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3D Printed Graphene and Graphene/Polymer Composites for Multifunctional Applications

MATERIALS (2023)

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Article Materials Science, Multidisciplinary

Electromagnetic wave absorption properties of the FeSiAl/PLA and FeSiAl-MoS2-Graphene/PLA double-layer absorber formed by fused deposition modeling

Xicong Ye et al.

Summary: The FeSiAl/PLA and FeSiAl-MoS2-GR/PLA composite filaments were prepared through mechanical mixing and melt extrusion process, and double-layer absorbers were prepared using FDM 3D printing technology. The results demonstrate that the double-layer absorber made of FeSiAl/PLA and FeSiAl-MoS2-GR/PLA can significantly improve impedance matching and enhance electromagnetic wave absorption performance. The double-layer absorber achieves a minimum reflection loss (RLmin) of -52.50 dB at 17.76 GHz, with a FeSiAl/PLA layer thickness of 0.6 mm and a total thickness of 1.7 mm. The effective absorption bandwidth (EAB) of the double-layer absorber is 5.92 GHz (12.08 to 18 GHz) with layer thicknesses of 0.8 mm and 1.2 mm, respectively. This is 29.8% wider than the EAB (4.56 GHz) of the single-layer FeSiAl-MoS2-GR/PLA composite with the same thickness.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2023)

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Article Materials Science, Characterization & Testing

3D printing of graphene oxide/carbon nanotubes hydrogel circuits for multifunctional fire alarm and protection

Xiaohu Chen et al.

Summary: In this study, we developed a printable conductive sodium alginate/graphene/carbon nanotube (SGC) ink through the flexible design of circuit structure and direct inkjet 3D printing technology. Three-dimensional graphene-based flexible circuits with high resolution and multifunction were achieved. The addition of GO, SWCNT and Ca2+ greatly improved the conductivity and flame retardancy of SGC. The preliminary explorations in 3D printing of multifunctional SGC hydrogels with complex structures provide theoretical basis for their application in flexible circuits, fire protection, and artificial electronic skin.

POLYMER TESTING (2023)

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Article Materials Science, Multidisciplinary

3D printing of architectured graphene-based aerogels by cross-linking GO inks with adjustable viscoelasticity for energy storage devices

San-Can Han et al.

Summary: Functional graphene-based architectures with superior electrical conductivity and good mechanical strength were achieved through micro-extrusion printing using viscoelasticity-adjustable inks. The rheological behavior and specific strength of the printed graphene architectures were notably improved by strong cross-linking networks and reached values higher than conventional graphene aerogels. The 3D-printed graphene-based architectures also showed excellent electrochemical performance as micro-supercapacitors due to effective ion transportation.

RARE METALS (2023)

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Article Chemistry, Physical

The Effect of Few-Layer Graphene on the Complex of Hardness, Strength, and Thermo Physical Properties of Polymer Composite Materials Produced by Digital Light Processing (DLP) 3D Printing

Sergey Kidalov et al.

Summary: The effect of particles of few-layer graphene (FLG) synthesized by self-propagating high-temperature synthesis (SHS) on the complex of strength and thermo physical properties of polymer composite products obtained by digital light processing (DLP) 3D printing were studied. It was found that the thermophysical and strength parameters of polymers were improved by FLG modification compared to unmodified base resin. This improvement was attributed to the low defectiveness and homogeneous distribution of FLG in the polymer structure. The hardness could be increased by 120%, bending strength by 102%, Charpy impact strength by 205%, and thermal conductivity at 25 degrees C by 572% with a concentration of few-layer graphene not exceeding 2 wt.%.

MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Three-in-One Portable Electronic Sensory System Based on Low-Impedance Laser-Induced Graphene On-Skin Electrode Sensors for Electrophysiological Signal Monitoring

Quan Zhang et al.

Summary: This article introduces a wearable multimodal data acquisition unit that can accurately perceive important electrophysiological signals and display the acquired signals in real time through a mobile app, showing great potential in various applications.

ADVANCED MATERIALS INTERFACES (2023)

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Article Chemistry, Multidisciplinary

Laser-Induced Graphene Enabled Additive Manufacturing of Multifunctional 3D Architectures with Freeform Structures

Fu Liu et al.

Summary: 3D printing is an important strategy for constructing graphene smart structures with arbitrary shapes and complexities. A new laser-induced graphene-based additive manufacturing (LIG-AM) protocol was developed to form bulk 3D graphene with freeform structures without using additional binders, templates, and catalysts. This method enables the assembly of various types of graphene architectures and allows for control of processing efficiency and assembling resolution. By studying the properties, a LIG-AM enabled aircraft-wing section model was printed to demonstrate its shiftable process, hybridizable structure, and multifunctional performance.

ADVANCED SCIENCE (2023)

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Article Chemistry, Physical

High Zinc Utilization Aqueous Zinc Ion Batteries Enabled by 3D Printed Graphene Arrays

Buke Wu et al.

Summary: This study improves the reversibility and utilization of zinc anodes by using three-dimensional printed graphene arrays, overcoming the limitations of current two-dimensional geometric design of zinc anodes. The graphene array structures can accommodate the volume change during zinc deposition/dissolution process and protect the battery from short circuits.

ENERGY STORAGE MATERIALS (2023)

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Review Multidisciplinary Sciences

Stereolithography apparatus and digital light processing-based 3D bioprinting for tissue fabrication

Wanlu Li et al.

Summary: Three-dimensional (3D) bioprinting, particularly using stereolithography apparatus (SLA) and digital light processing (DLP)-based vat-polymerization techniques, is a promising approach in biomedical research for producing high-resolution and architecturally sophisticated structures. This review provides an overview of the factors that affect SLA- and DLP-based 3D bioprinting processes, as well as the advances in bioinks used in these techniques. Additionally, the biomedical applications of SLA and DLP-based bioprinting, primarily in regenerative medicine and tissue modeling engineering, are discussed.

ISCIENCE (2023)

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Article Chemistry, Multidisciplinary

Graphene Oxide Based Transparent Resins For Accurate 3D Printing of Conductive Materials

David Tilve-Martinez et al.

Summary: Digital Light Processing (DLP) technology enables fast and high-resolution 3D printing, but it is limited to transparent resins and not suitable for printing conductive materials. In this study, a UV transparent liquid crystal graphene oxide precursor is used to generate in situ conductive particles in a photopolymerizable resin. The resin can sustain high temperature for the thermal reduction of graphene oxide into electrically conductive reduced graphene oxide particles. This method reconciles the DLP technology with the manufacturing of 3D electrically conductive objects.

ADVANCED FUNCTIONAL MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Ultraprecise 3D Printed Graphene Aerogel Microlattices on Tape for Micro Sensors and E-Skin

Qian Chen et al.

Summary: 3D printed graphene aerogels with high printing resolution show improved sensing accuracy and device miniaturization. The research formulates printable graphene oxide inks and creates self-standing 3D graphene oxide aerogel microlattice with ultra-high printing resolution. The reduced graphene oxide aerogel is then utilized in target applications, such as micro sensors and robot e-skin, by being stuck onto adhesive tape.

ADVANCED FUNCTIONAL MATERIALS (2023)

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Article Chemistry, Physical

Electrochemically synthesized graphene/TEMPO-oxidized cellulose nanofibrils hydrogels: Highly conductive green inks for 3D printing of robust structured EMI shielding aerogels

Elnaz Erfanian et al.

Summary: We designed and synthesized bio-based, electrically conductive green inks for direct ink writing (DIW) of lightweight electronics and electromagnetic interference (EMI) shields. The inks incorporate cellulose and graphene oxide, without using hazardous chemicals. The ink composition and ratio significantly affect the printing fidelity, shape retention, and mechanical and electrical properties of the printed structures. For the optimized ink, a high EMI shielding effectiveness of 55.6 dB is achieved.

CARBON (2023)

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Article Chemistry, Physical

Design and additive manufacturing of optimized electrodes for energy storage applications

Mariana Desireé Reale Batista et al.

CARBON (2023)

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Review Engineering, Manufacturing

Review on 3D-printed graphene-reinforced composites for structural applications

Xiao You et al.

Summary: The reasonable design of macro-micro structure has a significant impact on the mechanical properties of structural composites, and the development of 3D printing provides an opportunity for the efficient and controllable construction of multi-dimensional lightweight and high-strength composites. Carbon-based nanomaterials, especially graphene, have attracted attention as nanofillers for structural composites due to their huge specific surface area and excellent mechanical properties. The application of graphene in 3D printing enables the fabrication of complex 3D objects with highly oriented distribution and the construction of a penetrating structural network.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2023)

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Article Chemistry, Physical

Graphene/carbonyl iron powder composite microspheres enhance electromagnetic absorption of 3D printing composites

Xicong Ye et al.

Summary: The RGO-CIP composite microspheres were prepared using ethyl cellulose and epoxy resin. They effectively combined graphene (RGO) with carbonyl iron powder (CIP) to achieve multiple loss mechanisms and good electromagnetic absorption capability. The microspheres were used to prepare a 3D printed wire, which showed excellent electromagnetic properties. Heterogeneous interfaces formed on the surface and inside of the microspheres enhanced microwave reflections and scattering.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

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Article Materials Science, Composites

Preparation of carbon black/graphene nanosheets/PP composites with 3D separated conductive networks based on selective laser sintering

Hui Shen et al.

Summary: The main research goal of high-performance conductive polymer composites is to improve electrical conductivity and reduce the percolation threshold. In this study, polypropylene composite powders coated with carbon black (CB) and graphene nanosheets (GNSs) were prepared, and sintered using a selective laser sintering process to prepare polypropylene composites with three-dimensional separated conductive networks. The synergy between CB and GNSs was utilized to further improve the electrical conductivity of the composites.

POLYMER COMPOSITES (2023)

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Review Chemistry, Multidisciplinary

3D Printed Graphene-Based Metamaterials: Guesting Multi-Functionality in One Gain

Junjie Du et al.

Summary: This article reviews the latest developments and applications of 3D printed graphene-based metamaterials. It discusses the structure design and fabrication strategies of different types of metamaterials. It also explores the introduction of multi-functionality through 3D printed graphene-based materials.

SMALL (2023)

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Review Engineering, Manufacturing

Additive manufacturing by digital light processing: a review

Rajat Chaudhary et al.

Summary: Digital light processing (DLP), as an additive manufacturing technology, has shown potential in printing photopolymer, ceramic, and metal parts. It offers flexibility and efficiency, making it applicable in various fields such as dentistry, orthopedics, and smart materials.

PROGRESS IN ADDITIVE MANUFACTURING (2023)

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Article Nanoscience & Nanotechnology

Systematic Design of a Graphene Ink Formulation for Aerosol Jet Printing

Livio Gamba et al.

Summary: Aerosol jet printing is a noncontact, digital, additive manufacturing technique compatible with a wide variety of functional materials. In this study, a systematic approach to formulating a polymer-stabilized graphene ink is reported, considering the effect of solvent composition on dispersion, rheology, wetting, drying, and phase separation. The ink formulation achieved efficient ink atomization, controlled in-line drying, and high resolution and electrical conductivity, demonstrating its viability for fabricating functional electronic devices.

ACS APPLIED MATERIALS & INTERFACES (2023)

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Article Engineering, Environmental

Fabrication of three-dimensional printed hybrid graphene oxide/calcium alginate network by 3D printing technology with outstanding U(VI) recycling capacity in acidic solution

Fuxiang Song et al.

Summary: A 3D-printed graphene oxide (GO)/calcium alginate (CA) hybrid network (3D GO/CA) with excellent U(VI) adsorption performance was constructed using direct ink writing-based 3D printing technology and in situ calcium ion cross-linking technology. The 3D GO/CA exhibited a wide valid pH range (3-12) and excellent adsorption capacity for U(VI) in a strongly acidic solution. Furthermore, it showed a high adsorption kinetic reaction rate and stability even after reusing and soaking in strong acid solutions.

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Engineering, Multidisciplinary

Electrically assisted continuous vat photopolymerization 3D printing for fabricating high-performance ordered graphene/polymer composites

Guangming Zhang et al.

Summary: Electrically assisted continuous vat photopolymerization 3D printing technology has successfully achieved the continuous fabrication of ordered graphene/polymer composites, improving mechanical properties and electrical conductivity.

COMPOSITES PART B-ENGINEERING (2023)

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Article Nanoscience & Nanotechnology

Additive Manufacturing of Stretchable Polyurethane/Graphene/ Multiwalled Carbon Nanotube-Based Conducting Polymers for Strain Sensing

Fuxi Liu et al.

Summary: This study utilizes digital light processing (DLP) to prepare flexible sensors with pore structures by dispersing fillers in a light-sensitive resin. Results demonstrate that the 1.2 wt% MWCNTs-GN/TPU material exhibits excellent sensing performance, with higher sensitivity and suitability for human body. This method provides new ideas for rapid formation of flexible sensors.

ACS APPLIED NANO MATERIALS (2023)

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Article Materials Science, Composites

Temperature-insensitive stretchable conductors based on hierarchical double-layer graphene foams/PEDOT:PSS networks

Ying Wu et al.

Summary: In this study, a novel and facile approach was developed to achieve stable electrical conducting under stretching and temperature variation by incorporating a hierarchical wavy graphene foam (wGF) with a double-layer conductive framework formed by coating highly conductive poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) on interior graphene struts. The resulting composites exhibited exceptional resistance stabilities during stretching within a wide temperature range of -30-145 degrees C. The unique composite structure, including the macroscopic wavy structures, microscopic compacted conductive skeletons, and more ductile double-layer graphene/PEDOT:PSS frameworks, contributed to the excellent stretchable conducting properties and temperature-insensitive performances.

COMPOSITES SCIENCE AND TECHNOLOGY (2023)

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Article Engineering, Electrical & Electronic

Embedded Pressure Sensing Metamaterials Using TPU-Graphene Composites and Additive Manufacturing

Inigo Sanz-Pena et al.

Summary: This study aimed to develop wearable sensors with embedded pressure-sensing capabilities by utilizing additive manufacturing and graphene inks. Three different structural designs were created for different measuring ranges, and two graphene infusion processes were evaluated. The results showed that structural dimensions affected the measuring range, while the infusion process influenced the piezoresistive sensitivity and linear response of the sensors.

IEEE SENSORS JOURNAL (2023)

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Article Chemistry, Physical

Evaluation of Mechanical Properties and Filler Interaction in the Field of SLA Polymeric Additive Manufacturing

Petr Jirku et al.

Summary: The research is focused on the use of fillers in polymeric materials produced by SLA additive technology. The aim is to evaluate 3D printing parameters, mechanical properties, and the interaction of polymer matrix and fillers in composite materials using SEM analysis. It was found that the use of cotton flakes as filler had a positive effect on the mechanical properties under static and cyclic loading. The service life of materials with fillers increased significantly compared to pure resin.

MATERIALS (2023)

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Article Chemistry, Physical

3D graphene-based active electrodes with large areal capacitance by modified direct ink writing method

Ying Zhang et al.

Summary: The application of 3D printing technology in the field of energy storage is challenging but promising. This study successfully printed graphene-based conductive filaments and formed a poly-pyrrole film on the surface of the 3D frame. The 3D-printed open porous structure of the electrodes provided effective channels for ion transport and large ion accessible area for electrochemical reactions.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2023)

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Article Materials Science, Multidisciplinary

100 m min-1 Industrial-Scale Flexographic Printing of Graphene-Incorporated Conductive Ink

Nasiruddin Macadam et al.

Summary: The incorporation of graphene nanoplatelets (GPs) into conductive flexographic ink improves sheet-resistance and uniformity, as well as adhesion on paper and PET substrates. The GP-enhanced samples exhibit robust durability under 1000 cyclic bend-test, showing a minimal average variation in resistance. Statistically scalable results show that GP-incorporation offers a cost-performance advantage for flexographic printing of large-area conductive patterns.

ADVANCED ENGINEERING MATERIALS (2022)

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Article Materials Science, Multidisciplinary

3D Printed Reduced Graphene Oxide/Elastomer Resin Composite with Structural Modulated Sensitivity for Flexible Strain Sensor

Cheng Qian et al.

Summary: In this study, a high-performance flexible strain sensor was developed using a digital light processing-based 3D printing method. The sensor exhibited high sensitivity and mechanical stability, enabling it to monitor various human motions.

ADVANCED ENGINEERING MATERIALS (2022)

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Article Chemistry, Multidisciplinary

3D Printed Template-Directed Assembly of Multiscale Graphene Structures

Jingzhuo Zhou et al.

Summary: Using graphene as a model building block, the fabrication of multiscale structures with tailorable features spanning seven orders of magnitude in size is achieved by a 3D printed template-directed assembly method. The structures demonstrate extraordinary properties such as ultralow density, ultrahigh stiffness, and compressibility.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Dimensional Design and Core-Shell Engineering of Nanomaterials for Electromagnetic Wave Absorption

Zhengchen Wu et al.

Summary: Electromagnetic wave absorption materials with core-shell structures can enhance performance through interfacial polarization, conduction networks, magnetic coupling, and magnetic-dielectric synergy. This review outlines the recent advances in low-dimensional core-shell electromagnetic wave absorption materials and discusses notable examples. Key information regarding dimensional design, structural engineering, performance, and structure-function relationship is comprehensively summarized.

ADVANCED MATERIALS (2022)

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Article Materials Science, Ceramics

Dual gradient direct ink writing of functional geopolymer-based carbonyl-iron/graphene composites for adjustable broadband microwave absorption

Zheng Li et al.

Summary: This research successfully fabricated functional gradient materials using additive manufacturing technology and improved wave absorption performance, providing a strategy for manufacturing wave absorption devices.

CERAMICS INTERNATIONAL (2022)

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Article Engineering, Environmental

A flexible dual parameter sensor with hierarchical porous structure for fully decoupled pressure-temperature sensing

Yiming Yin et al.

Summary: A flexible pressure-temperature dual parameter sensor with a hierarchical porous structure has been developed to simultaneously sense pressure and temperature with high sensitivity. The sensor demonstrates negligible mutual interference between pressure and temperature signals in dual parameter mode, thanks to reduced temperature-induced resistance change by surface coating of graphene. This sensor shows promising applications in healthcare monitoring, prosthesis, and human-machine interaction systems.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Manufacturing

Graphene Oxide-loaded magnetic nanoparticles within 3D hydrogel form High-performance scaffolds for bone regeneration and tumour treatment

Yan Li et al.

Summary: The study successfully prepared a novel magnetic hydrogel composite scaffold using additive manufacturing technology, demonstrating good molding properties and strong hydrogen bonding. The scaffolds support bone cell differentiation in vitro and exhibit promising anti-tumour characteristics in vivo.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2022)

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Article Materials Science, Biomaterials

Modified graphene oxide nanoplates reinforced 3D printed multifunctional scaffold for bone tissue engineering

Akriti Sharma et al.

Summary: This study developed a novel approach to fabricate mechanically customized 3D printed scaffolds with modified nanosheets reinforcement. The designed scaffold showed stem cell responsive, integrative, and pro-regenerative multi functionalities, making it a potential treatment alternative for bone tissue regeneration.

BIOMATERIALS ADVANCES (2022)

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Article Materials Science, Multidisciplinary

Carbon fibre-graphene composite polylactic acid (PLA) material for COVID shield frameKohlenstofffaser-Graphen-Polylactid (PLA)-Verbundwerkstoff als COVID-Schutzrahmen

E. P. Mohammed Basheer et al.

Summary: This research focuses on the challenges in developing carbon fiber and graphene reinforced composite polylactic acid material. By using a screw extrusion process, a continuous composite polylactic acid wire containing 1 wt.% carbon fiber particles, 1 wt.% graphene, and 98 wt.% polylactic acid pellets is successfully produced. The dispersion of carbon fiber and graphene in the polylactic acid material is confirmed through electron microscope analysis and their presence in the material is further confirmed through x-ray diffraction. The mechanical test samples show that the strength of the composite polylactic acid material is 31 MPa, while the 3D printed composite material has a strength of 63 MPa. A commercial product, an autoclavable COVID-19 face shield, is developed using the composite polylactic acid material through Fused Filament Fabrication 3D printing.

MATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK (2022)

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Article Chemistry, Physical

Fabrication of PLA/PCL/Graphene Nanoplatelet (GNP) Electrically Conductive Circuit Using the Fused Filament Fabrication (FFF) 3D Printing Technique

Nour-Alhoda Masarra et al.

Summary: This study fabricated electrically conductive composites using the fused filament fabrication (FFF) technique and compared their properties with injection-molded samples. The results showed that the 3D-printed samples with graphene exhibited semiconductor behavior, while the injection-molded samples were insulators. The printing raster angles also influenced the electrical conductivity results. Moreover, an increase in the graphene content increased the Young's modulus of the composites.

MATERIALS (2022)

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Article Chemistry, Multidisciplinary

A highly accurate flexible sensor system for human blood pressure and heart rate monitoring based on graphene/sponge

Fan Zhang et al.

Summary: This work presents a flexible sensing system for human health monitoring, which exhibits high accuracy and repeatability and allows for real-time continuous detection of parameters such as human pulse waveform, blood pressure, and heart rate.

RSC ADVANCES (2022)

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Article Nanoscience & Nanotechnology

Silver-modified graphene oxide nanosheets for antibacterial performance of bone scaffold

Zhiheng Yu et al.

Summary: In this study, Ag@GO nanohybrids were constructed by in situ growing silver nanoparticles on graphene oxide (GO) and then introduced into a polymer scaffold. The antibacterial scaffold exhibited robust antibacterial performance and good cytocompatibility. This work developed an efficient antibacterial material for bone repair scaffold.

AIP ADVANCES (2022)

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Article Chemistry, Multidisciplinary

Beyond Skin Pressure Sensing: 3D Printed Laminated Graphene Pressure Sensing Material Combines Extremely Low Detection Limits with Wide Detection Range

Kunli Cao et al.

Summary: The development of robotic skins capable of handling complex external pressure environments is highly desired, but remains a major challenge due to the lack of pressure sensing materials that can combine extremely low detection limits and wide detection ranges. Inspired by the synergistic strategy of dual mechanoreceptors in human skin, laminated graphene pressure sensing materials have been designed and 3D printed to achieve a low detection limit and wide detection range, showing great potential for applications such as electronic skin and human-machine interfaces.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Analytical

Electrochemical (Bio)Sensors Enabled by Fused Deposition Modeling-Based 3D Printing: A Guide to Selecting Designs, Printing Parameters, and Post-Treatment Protocols

Jessica Santos Stefano et al.

Summary: 3D printing technology has great potential in electroanalysis, allowing for quick and flexible production of various shapes and sizes of electrochemical systems and electrodes. Care must be taken when using FDM 3D printers to ensure quality and sealing.

ANALYTICAL CHEMISTRY (2022)

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Article Multidisciplinary Sciences

Design and evaluation of 3D-printed auxetic structures coated by CWPU/graphene as strain sensor

Hyeong Yeol Choi et al.

Summary: Recently, a strain sensor with elasticity has been studied for monitoring humans or robots. Four types of 3D-printed auxetic lattice structures using thermoplastic polyurethane as raw material were characterized, and then coated with graphene to create flexible and stable strain sensors. These fabricated structures have excellent strength, flexibility, and electrical conductivity, making them suitable for strain sensors that can detect a constant change in resistance at a given strain.

SCIENTIFIC REPORTS (2022)

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Article Chemistry, Multidisciplinary

Pristine graphene-ink for 3D-printed flexible solid-state supercapacitor

Satendra Kumar et al.

Summary: This study demonstrates the fabrication of a 3D-printed planar supercapacitor using graphene ink, without the need for high-temperature processing or functional additives. The resulting supercapacitor exhibits excellent specific capacitance and energy density, surpassing previous carbon-based supercapacitors fabricated using 3D or inkjet printing. The flexibility and robustness of 3D-printed devices are also achieved, allowing for customizable shapes.

CARBON LETTERS (2022)

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Article Nanoscience & Nanotechnology

Controlling surface porosity of graphene-based printed aerogels

Binghan Zhou et al.

Summary: The surface porosity of graphene-based aerogels plays a crucial role in applications involving mass transfer. Through experiments and simulations, it is found that high shear stress during the fabrication process leads to a non-porous surface, while crosslinking of the sheets results in a porous surface. Controlling the surface porosity of printed graphene-oxide aerogels (GOA) can be achieved by regulating the crosslinking agents and shear stress. The study demonstrates the performance advantages of GOA with porous surface in dye adsorption, highlighting the importance of surface porosity in specific applications.

NPJ 2D MATERIALS AND APPLICATIONS (2022)

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Article Materials Science, Composites

Non-Destructive and Destructive Testing to Analyse the Effects of Processing Parameters on the Tensile and Flexural Properties of FFF-Printed Graphene-Enhanced PLA

Javaid Butt et al.

Summary: This study investigates the effects of four different parameters on FFF printing capabilities and evaluates the characteristics of printed PLA through various testing methods. The results highlight the importance of non-destructive testing methods in assessing material properties.

JOURNAL OF COMPOSITES SCIENCE (2022)

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Article Chemistry, Physical

3D-printed graphene polylactic acid devices resistant to SARS-CoV-2 Sunlight-mediated sterilization of additive manufactured objects :

Flavio De Maio et al.

Summary: Additive manufacturing has played a crucial role in the COVID-19 global emergency by enabling rapid production of medical devices and personal protective equipment. By incorporating graphene nanoplatelets, 3D-printed devices that can be sterilized using near-infrared light have been developed. This method effectively kills SARS-CoV-2 viral particles on the surface of 3D-printed PLA-G, and PLA-G material is highly biocompatible, making it suitable for producing sterilizable personal protective equipment and everyday objects.

CARBON (2022)

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Article Engineering, Multidisciplinary

3D printing stretchable core-shell laser scribed graphene conductive network for self-powered wearable devices

Qiushi Li et al.

Summary: In this study, a graphene-based flexible electronic device called LSGCN is demonstrated, which is fabricated using 3D printing and double-side laser scribing graphene techniques. LSGCN shows good stretchability and stability, making it suitable for applications in bio-energy harvesting and self-powered sensing devices.

COMPOSITES PART B-ENGINEERING (2022)

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Article Materials Science, Composites

Mechanical and functional properties of polyamide/graphene nanocomposite prepared by chemicals free-approach and selective laser sintering

Qingshi Meng et al.

COMPOSITES COMMUNICATIONS (2022)

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Article Nanoscience & Nanotechnology

Direct ink printing reduced graphene oxide/KCu7S4 electrodes for high-performance supercapacitors

Yanliang Zhao et al.

Summary: In this study, a novel method using two-dimensional lamellar graphene oxide and nano-rod KCu7S4 to prepare ink suitable for 3D printing is proposed. The printed rGO/KCu7S4 electrode shows excellent capacitance performance and cycle stability.

ADVANCED COMPOSITES AND HYBRID MATERIALS (2022)

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Article Chemistry, Physical

High-Performance All-solid-state microsupercapacitors from 3D printing Structure-engineered Graphene-Carbon sphere electrodes

Yan Zhang et al.

Summary: This article introduces a method to prevent graphene aggregation by modifying the structure of the graphene electrode, and successfully validates this method through experiments. The MSCs prepared using this method have good electrochemical performance and mechanical flexibility.

APPLIED SURFACE SCIENCE (2022)

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Article Dentistry, Oral Surgery & Medicine

Development of 3D printed dental resin nanocomposite with graphene nanoplatelets enhanced mechanical properties and induced drug-free antimicrobial activity

Sultan Aati et al.

Summary: This study introduced the feasibility of developing a 3D printed resin-based composition modified with graphene nanoplatelets (GNPs) to improve properties. Mechanical, physical, biological, and antimicrobial aspects were analyzed to evaluate the effectiveness of the modified material.

DENTAL MATERIALS (2022)

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Article Chemistry, Physical

Direct ink writing (DIW) of graphene aerogel composite electrode for vanadium redox flow battery

Qiang Li et al.

Summary: This paper presents a reduced graphene oxide/Super-P aerogel composite electrode with controllable porous structure based on direct ink writing (DIW), which shows promising potential in vanadium redox flow battery (VRFB). The optimized electrode exhibits superior discharge capacity and energy efficiency due to its high conductivity, high specific area, and reasonable hierarchical porous structure.

JOURNAL OF POWER SOURCES (2022)

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Review Materials Science, Multidisciplinary

Graphene-based wearable temperature sensors: A review

Anindya Nag et al.

Summary: This paper presents a comprehensive review on the use of graphene for developing wearable temperature sensors. Flexible temperature sensors using various polymers and nanomaterials have been fabricated and widely used to detect temperature over a wide range in biomedical and industrial applications. Graphene, with its exceptional electrical, mechanical, and thermal properties, has been extensively employed for the development of wearable temperature sensors. The paper highlights significant works and suggests possible remedial steps to address the challenges in the current literature.

MATERIALS & DESIGN (2022)

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Article Materials Science, Multidisciplinary

Magnetic-field-assisted DLP stereolithography for controlled production of highly aligned 3D printed polymer-Fe3O4@graphene nanocomposites

Hammad Younes et al.

Summary: This paper demonstrates the printing of nanocomposites using the DLP method with aligned magnetic Fe3O4@graphene fillers, showing significant improvement in mechanical properties. The results indicate that 0 alignment provides better mechanical properties compared to 90 alignment for filler concentrations of 0.4, 0.8, and 1.6 wt.%.

MATERIALS RESEARCH BULLETIN (2022)

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Article Engineering, Environmental

3D printed polylactic acid/graphene nanocomposites with tailored multifunctionality towards superior thermal management and high-efficient electromagnetic interference shielding

Shaohong Shi et al.

Summary: This study presents a promising multifunctional filament by incorporating graphene nanosheets (GNs) into a polylactic matrix using a solution-blending method. The resulting nanocomposites exhibit improved thermal conductivity and electromagnetic interference shielding. By utilizing 3D printing technology, ideal parts with arbitrary structures and exceptional performance, such as heat sinks and shielding modules, were successfully constructed. This innovative study enriches printable materials and shows promising potential for next-generation functional parts.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Three-Dimensional Printed MoS2/Graphene Aerogel Electrodes for Hydrogen Evolution Reactions

Swetha Chandrasekaran et al.

ACS MATERIALS AU (2022)

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Article Chemistry, Physical

A simple and effective host for sodium metal anode: a 3D-printed high pyrrolic-N doped graphene microlattice aerogel

Haoyuan Yang et al.

Summary: In this study, a three-dimensional printed nitrogen-doped graphene aerogel microlattice host was developed to achieve uniform sodium nucleation and deposition, thus addressing safety issues caused by sodium dendrite formation in rechargeable sodium metal batteries. The optimized architecture and nitrogen doping technology of the microlattice enable low nucleation overpotentials, long cycle life, and high coulombic efficiency.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Materials Science, Multidisciplinary

Direct ink writing of a graphene/CNT/silicone composite strain sensor with a near-zero temperature coefficient of resistance

Wei-Bin Zhu et al.

Summary: In this study, highly stretchable GCE fibres were successfully prepared, which exhibit a near-zero TCR, highest sensitivity, wide working range, and excellent electrical stability, demonstrating outstanding sensing performance and response stability.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

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Article Chemistry, Physical

3D printing of resilient, lightweight and conductive MXene/reduced graphene oxide architectures for broadband electromagnetic interference shielding

Yang Dai et al.

Summary: In this study, lightweight, resilient, and conductive MXene-based scaffolds were successfully 3D printed using a direct ink writing technique, demonstrating the impact of structural design flexibility on optimizing comprehensive performance. The printed MXene/RGO scaffolds showed high electrical conductivity and broadband tunable electromagnetic interference shielding effectiveness, as well as excellent reversible compressibility and cyclic fatigue resistance.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Polymer Science

Graphene-polyamide-6 composite for additive manufacture of multifunctional electromagnetic interference shielding components

Kok Peng Marcian Lee et al.

Summary: The addition of graphene enhances the properties of polyamide-6 composite materials, while maintaining processability even at high graphene concentrations. SEM imaging shows the alignment of graphene in printed materials, and the inclusion of graphene improves the dielectric properties and EMI SE of the materials in compression molded and ME test specimens.

JOURNAL OF APPLIED POLYMER SCIENCE (2021)

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Review Chemistry, Multidisciplinary

3D Printed Flexible Strain Sensors: From Printing to Devices and Signals

Haodong Liu et al.

Summary: The revolutionary advancements in flexible electronics offer great potential for wearable devices and electronic skin, with flexible strain sensors serving as essential components in integrated electronic systems. 3D printing technology is preferred for manufacturing flexible strain sensors due to its cost-effectiveness, accuracy, and efficiency. Various printing methods, such as DLP, FDM, and DIW, are discussed in this study, along with the sensing mechanisms of the printed sensors and suggestions for future research directions.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

3D printing of graphene oxide composites with well controlled alignment

Yue Qian et al.

Summary: The study introduces a universal strategy for large-scale alignment of graphene oxide without the need for modification. By laminating, scrolling, and 3D printing, graphene oxide nanosheets are aligned in the filament axial direction, resulting in improved mechanical properties of the composite materials.

CARBON (2021)

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Article Engineering, Multidisciplinary

Recent progress and multifunctional applications of 3D printed graphene nanocomposites

Deepalekshmi Ponnamma et al.

Summary: This review comprehensively analyzes the incorporation of graphene and its derivatives into polymer matrices for enhanced 3D printed structures. Factors such as printing method selection, dispersion of graphene, and interfacial interactions play a key role in the final performance, while graphene-based nanocomposites show limitless potential for multifunctional applications in 3D printing.

COMPOSITES PART B-ENGINEERING (2021)

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Article Materials Science, Composites

Highly stretchable graphene/polydimethylsiloxane composite lattices with tailored structure for strain-tolerant EMI shielding performance

Zhenyu Wang et al.

Summary: The study presents a highly stretchable and conductive graphene/polydimethylsiloxane lattice fabricated through 3D printing technique, with excellent stretchability, tunable EMI shielding effectiveness, and durability for next-generation flexible and stretchable electronics.

COMPOSITES SCIENCE AND TECHNOLOGY (2021)

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Review Engineering, Multidisciplinary

3D printing for polymer/particle-based processing: A review

Weiheng Xu et al.

Summary: The 3D printing technology, also known as additive manufacturing, has great potential in manufacturing but requires further research to develop new mechanisms for multi-material manufacturing. Materials with unique properties, such as particles, can find broad applications in various fields. This review provides an overview of different 3D printing mechanisms and summarizes the processing parameters, advantages, disadvantages, and future challenges.

COMPOSITES PART B-ENGINEERING (2021)

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Article Engineering, Multidisciplinary

Wavy graphene foam reinforced elastomeric composites for large-strain stretchable conductors

Lei Wang et al.

Summary: A novel wavy graphene foam (wGF)/thermoplastic polyurethane (TPU) composite with excellent flexibility, stretchability, and electrical conductivity has been fabricated. The composite demonstrates great potential as large-strain stretchable conductors, with stable electrical performances under different deformation conditions, making it suitable for real-world applications. The synergic effects of the wavy structure extension and the reshaping of highly compacted graphene frameworks during stretching contribute to the stable conductive performances of the material.

COMPOSITES PART B-ENGINEERING (2021)

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Article Engineering, Biomedical

3D-printed cryomilled poly(ε-caprolactone)/graphene composite scaffolds for bone tissue regeneration

Daniela Dias et al.

Summary: This study successfully manufactured composite scaffolds based on PCL and FLG for the first time using cryomilling and FDM techniques. The functionalized FLG showed slight changes in scaffold microstructure, enhanced compressive modulus, and good cell viability and proliferation for SaOs-2 cells. These new FLG/PCL scaffolds demonstrated suitable morphological, thermal, mechanical, and biological properties for bone tissue regeneration.

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS (2021)

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Article Materials Science, Multidisciplinary

Poly ether ether ketone and its composite powder prepared by thermally induced phase separation for high temperature selective laser sintering

Yuan Wang et al.

Summary: In this study, novel neat PEEK and PEEK/CNT composite powders suitable for SLS application were produced using the TIPS method. The composite powder showed increased crystallinity compared to neat PEEK powder, and single layer films were successfully built using HT-SLS. DMA analysis indicated that the addition of 0.1% CNT improved the mechanical properties of PEEK.

MATERIALS & DESIGN (2021)

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Article Pharmacology & Pharmacy

Selective Laser Sintering of Solid Oral Dosage Forms with Copovidone and Paracetamol Using a CO2 Laser

Yanis A. Gueche et al.

Summary: This study assesses the suitability of CO2 laser for selective laser sintering of solid oral dosage forms containing copovidone and paracetamol, proving the feasibility of this method. Physicochemical characterization of powders and evaluation of sintered SODFs properties were conducted, demonstrating the applicability of CO2 laser SLS printer for producing SODFs.

PHARMACEUTICS (2021)

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Article Materials Science, Multidisciplinary

Mechanical anisotropy of graphene nanocomposites induced by graphene alignment during stereolithography 3D printing

Kalaimani Markandan et al.

Summary: The presence of aligned graphene platelets in stereolithographically 3D-printed graphene-PMMA nanocomposites was experimentally confirmed for the first time using polarized light microscopy. The alignment was weak, with anisotropy values only around 10% - 30% and the optimal graphene concentration for maximum anisotropy was found to be 0.02wt%-0.05wt%. Beyond 0.2wt%, graphene agglomeration prevented 3D printing altogether.

JOURNAL OF MATERIALS RESEARCH (2021)

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Article Engineering, Multidisciplinary

Highly flexible, thermally stable, and static dissipative nanocomposite with reduced functionalized graphene oxide processed through 3D printing

Binbin Guo et al.

Summary: This study developed a reduced functionalized graphene oxide/acrylate nanocomposite through 3D printing technology with flexibility, thermal stability, and static dissipation capacity. A highly efficient ultrasonication method was used to prepare functionalized graphene oxide, increasing its dispersion and stability in acrylate solution for SLA 3D printing. The nanocomposite exhibited impressive electrical conductivity and static dissipative properties, showing potential for smart electronics applications.

COMPOSITES PART B-ENGINEERING (2021)

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Article Materials Science, Multidisciplinary

Study on 3D printed graphene/carbon fiber multi-scale reinforced PLA composites

Li Liang et al.

Summary: Mechanical and interfacial properties of 3D-printed PLA were significantly enhanced by blending with CF and GO, along with a PBS toughening agent. The resulting composite showed improved strength and modulus compared to pure PLA and CF/PLA.

MATERIALS LETTERS (2021)

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Review Materials Science, Multidisciplinary

Structural and functional applications of 3D-printed graphene-based architectures

Xiao You et al.

Summary: Based on the potential of graphene-based composites in various applications, the assembly and three-dimensional configuration of graphene nanosheets is crucial for optimizing their properties, with 3D printing technology standing out for its efficient construction process. The interconnected graphene conductive network and lightweight structural regulation enable the integration of structure and function, and understanding ink properties, structural regulation, and application prospects is important for the development of printed graphene-based architecture. A summary and outlook highlight the application challenges and future development of 3D-printed graphene-based architecture.

JOURNAL OF MATERIALS SCIENCE (2021)

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Article Nanoscience & Nanotechnology

Stereolithography (SLA) 3D printing of carbon fiber-graphene oxide (CF-GO) reinforced polymer lattices

Ran Xiao et al.

Summary: A novel carbon fiber-graphene oxide (CF-GO) polymer composite resin, along with mild annealing postprocess, significantly enhances the compression strength of stereolithography (SLA)-printed oct-truss (OCT) lattices. The study demonstrates that incorporating a suitable amount of CF-GO, combined with annealing treatment, can increase the mechanical properties of polymer OCT lattices by nearly 10 times.

NANOTECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Highly Thermally Conductive 3D Printed Graphene Filled Polymer Composites for Scalable Thermal Management Applications

Haichang Guo et al.

Summary: The combination of 3D printing and 2D materials such as graphene enables infinite possibilities for hierarchically aligned structure programming, resulting in enhanced thermal conductivity in composite materials.

ACS NANO (2021)

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Article Materials Science, Composites

Facile fabrication of lightweight porous FDM-Printed polyethylene/graphene nanocomposites with enhanced interfacial strength for electromagnetic interference shielding

Jingjing Jing et al.

Summary: The development of diverse, lightweight and high-performance electromagnetic interference (EMI) shielding materials is urgent but challenging. Utilizing a combination of FDM 3D printing, ball milling and microwave (MW) irradiation technology, a promising lightweight EMI shielding material with porous and complex geometry structure was successfully fabricated, achieving prominent EMI shielding effectiveness in the range of 8.2-12.4 GHz.

COMPOSITES SCIENCE AND TECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Universal Alignment of Graphene Oxide in Suspensions and Fibers

Yul Hui Shim et al.

Summary: Research showed that there is a universal shear threshold for the best alignment of graphene oxide particles under shear conditions, leading to a significant enhancement in the mechanical properties of graphene fibers without the need for chemical modification.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Additive Manufacturing of 3D Aerogels and Porous Scaffolds: A Review

Halil Tetik et al.

Summary: Aerogels are highly porous structures produced by replacing the liquid solvent of a gel with air, without causing a collapse in the solid network. Additive manufacturing (AM) has been used to fabricate 3D aerogels with customized geometries specific to their applications, showing great promise in various fields such as tissue engineering, electrochemical energy storage, controlled drug delivery, sensing, and soft robotics. Postprinting processes are addressed to achieve desired properties like porosity and mechanical strength through drying and postdrying treatments.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Engineering, Manufacturing

Boosting piezoelectric performance with a new selective laser sintering 3D printable PVDF/graphene nanocomposite

Shiping Song et al.

Summary: Piezoelectric materials, with unique mechanical energy-harvesting capabilities, face challenges in achieving ideal performance when fabricated into low-dimensional products. SLS 3D printing offers a solution to amplify piezoelectric output, emphasizing the importance of novel materials in enhancing performance for energy harvesting applications.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2021)

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Article Materials Science, Multidisciplinary

A Fully 3D-Printed Wearable Piezoresistive Strain and Tactile Sensing Array for Robot Hand

Zhen Pei et al.

Summary: The developed 3D-printed wearable strain and tactile sensing array integrates flexible strain and pressure sensors with porous structures, providing a wide linear measurement range and continuous pressure monitoring ability for robotic perception.

ADVANCED MATERIALS TECHNOLOGIES (2021)

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Review Chemistry, Multidisciplinary

Three-dimensional printing of graphene-based materials for energy storage and conversion

Yanqiu Jiang et al.

Summary: Developing high-performance energy storage and conversion devices relies on the use of good materials and rational design of assembly structure. Graphene-based materials are extensively used for ESC applications due to their superior properties, with 3D printing techniques bringing revolutionary improvements in structure control and design capabilities. Studying 3D-printed graphene materials and their design philosophy can provide new concepts for material design and future research opportunities in high-performance ESC devices.

SUSMAT (2021)

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Article Engineering, Electrical & Electronic

All-Printed MXene-Graphene Nanosheet-Based Bimodal Sensors for Simultaneous Strain and Temperature Sensing

Mortaza Saeidi-Javash et al.

Summary: The aerosol jet printed bimodal sensor using graphene and Ti3C2Tx MXene nanoinks can detect strain and monitor temperature simultaneously, expanding sensing capability with improved spatial resolution and competitive thermopower output. The sensor exhibits excellent stability and flexibility, making it suitable for a broad range of applications with potential for multifunctional devices.

ACS APPLIED ELECTRONIC MATERIALS (2021)

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Review Engineering, Multidisciplinary

A review on the fused deposition modeling (FDM) 3D printing: Filament processing, materials, and printing parameters

Ruben Bayu Kristiawan et al.

Summary: This study reviews the progress on factors affecting the results of 3D printing in FDM process, emphasizing the significance of relationships between parameters in determining printing outcomes.

OPEN ENGINEERING (2021)

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Review Materials Science, Multidisciplinary

Direct ink writing of energy materials

S. Tagliaferri et al.

Summary: This review discusses the application of 3D printing technology in sustainable energy device fabrication, focusing on the growth of extrusion-based 3D printing in manufacturing batteries, supercapacitors, and catalytic systems. The critical role of ink formulation and rheological characteristics on the functional performance of printed devices is emphasized, along with a review of strategies for obtaining printable inks from energy materials and the challenges and opportunities for future development.

MATERIALS ADVANCES (2021)

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Article Chemistry, Physical

3D printed carbon aerogel microlattices for customizable supercapacitors with high areal capacitance

Shijia Yuan et al.

Summary: This study presents a method to design carbon aerogel microlattices using 3D printing technology, achieving high areal capacitance. Through the use of appropriate materials and processing methods, ideal capacitance performance was achieved under high mass loading and large thickness.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Polymer Science

3D-Printed thermoplastic polyurethane/graphene composite with porous segregated structure: Toward ultralow percolation threshold and great strain sensitivity

Shuxiang Mei et al.

Summary: The study successfully fabricated a highly sensitive and stable strain sensor with low-percolation threshold and large deformation capacity, providing important guidance for the manufacture of high-performance strain sensors.

JOURNAL OF APPLIED POLYMER SCIENCE (2021)

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Article Chemistry, Multidisciplinary

3D-Printed Structure Boosts the Kinetics and Intrinsic Capacitance of Pseudocapacitive Graphene Aerogels

Bin Yao et al.

ADVANCED MATERIALS (2020)

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Article Engineering, Manufacturing

Enhanced mechanical properties of 3D printed graphene-polymer composite lattices at very low graphene concentrations

Kalaimani Markandan et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2020)

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Article Engineering, Multidisciplinary

Multifunctional performance of carbon nanotubes and graphene nanoplatelets reinforced PEEK composites enabled via FFF additive manufacturing

M. F. Arif et al.

COMPOSITES PART B-ENGINEERING (2020)

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Article Nanoscience & Nanotechnology

3D Printing of Highly Sensitive and Large-Measurement-Range Flexible Pressure Sensors with a Positive Piezoresistive Effect

Zhenhua Tang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Physical

Liquid crystalline 3D printing for superstrong graphene microlattices with high density

Fang Wang et al.

CARBON (2020)

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Review Chemistry, Multidisciplinary

Photopolymerizable Biomaterials and Light-Based 3D Printing Strategies for Biomedical Applications

Claire Yu et al.

CHEMICAL REVIEWS (2020)

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Article Polymer Science

Comparative Studies on Polyurethane Composites Filled with Polyaniline and Graphene for DLP-Type 3D Printing

Hyeonseo Joo et al.

POLYMERS (2020)

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Article Engineering, Multidisciplinary

Exfoliated graphene/thermoplastic elastomer nanocomposites with improved wear properties for 3D printing

Hyerin Jeon et al.

COMPOSITES PART B-ENGINEERING (2020)

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Article Chemistry, Multidisciplinary

Electroactive 3D Printed Scaffolds Based on Percolated Composites of Polycaprolactone with Thermally Reduced Graphene Oxide for Antibacterial and Tissue Engineering Applications

Carolina Angulo-Pineda et al.

NANOMATERIALS (2020)

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Article Engineering, Chemical

Fused Deposition Modeling 3D Printing of Novel Poly(vinyl alcohol)/Graphene Nanocomposite with Enhanced Mechanical and Electromagnetic Interference Shielding Properties

Lu Yang et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Multidisciplinary Sciences

3D printing of conducting polymers

Hyunwoo Yuk et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Analytical

The Fabrication of Micro Beam from Photopolymer by Digital Light Processing 3D Printing Technology

Ishak Ertugrul

MICROMACHINES (2020)

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Article Engineering, Manufacturing

Laterally compressed graphene foam/acrylonitrile butadiene styrene composites for electromagnetic interference shielding

Lei Wang et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2020)

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Article Materials Science, Composites

In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing

Yuval Shmueli et al.

COMPOSITES SCIENCE AND TECHNOLOGY (2020)

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Article Engineering, Electrical & Electronic

Printed Temperature Sensor Based on PEDOT: PSS-Graphene Oxide Composite

Mahesh Soni et al.

IEEE SENSORS JOURNAL (2020)

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Article Engineering, Chemical

Preparation of Highly Efficient Electromagnetic Interference Shielding Polylactic Acid/Graphene Nanocomposites for Fused Deposition Modeling Three-Dimensional Printing

Shaohong Shi et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Nanoscience & Nanotechnology

On the Effect of Ultralow Loading of Microwave-Assisted Bifunctionalized Graphene Oxide in Stereolithographic 3D-Printed Nanocomposites

Edgar-Homero Ramirez-Soria et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Physical

Multimaterial 3D-printing of graphene/Li0.35Zn0.3Fe2.35O4 and graphene/carbonyl iron composites with superior microwave absorption properties and adjustable bandwidth

Yuxin Zuo et al.

CARBON (2020)

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Article Chemistry, Physical

3D printing of Fe3O4 functionalized graphene-polymer (FGP) microarchitectures

Muhammad Wajahat et al.

CARBON (2020)

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Article Materials Science, Multidisciplinary

3D printed high-performance flexible strain sensors based on carbon nanotube and graphene nanoplatelet filled polymer composites

Dong Xiang et al.

JOURNAL OF MATERIALS SCIENCE (2020)

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Article Engineering, Environmental

Facile and scalable fabrication of highly thermal conductive polyethylene/graphene nanocomposites by combining solid-state shear milling and FDM 3D-printing aligning methods

Jingjing Jing et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Nanoscience & Nanotechnology

Poly(ionic liquid)-Stabilized Graphene Nanoinks for Scalable 3D Printing of Graphene Aerogels

Tuan Sang Tran et al.

ACS APPLIED NANO MATERIALS (2020)

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Review Engineering, Multidisciplinary

A critical review on the fused deposition modeling of thermoplastic polymer composites

Pavan Kumar Penumakala et al.

COMPOSITES PART B-ENGINEERING (2020)

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Article Materials Science, Characterization & Testing

Comparative study of geometric properties of unreinforced PLA and PLA-Graphene composite materials applied to additive manufacturing using FFF technology

E. Garcia et al.

POLYMER TESTING (2020)

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Review Materials Science, Multidisciplinary

Engineering materials with light: recent progress in digital light processing based 3D printing

Zhi Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Article Chemistry, Physical

3D printed rGO/CNT microlattice aerogel for a dendrite-free sodium metal anode

Jin Yan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Proceedings Paper Materials Science, Multidisciplinary

Effect on infill density on mechanical properties of PETG part fabricated by fused deposition modelling

R. Srinivasan et al.

MATERIALS TODAY-PROCEEDINGS (2020)

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Proceedings Paper Materials Science, Multidisciplinary

Vapor smoothing process for surface finishing of FDM replicas

Jasgurpreet Singh Chohan et al.

MATERIALS TODAY-PROCEEDINGS (2020)

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Article Materials Science, Textiles

Characterization of Electrical Heating of Graphene/PLA Honeycomb Structure Composite Manufactured by CFDM 3D Printer

Hyelim Kim et al.

FASHION AND TEXTILES (2020)

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Article Chemistry, Multidisciplinary

A robust 3D printed multilayer conductive graphene/polycaprolactone composite electrode

Chong-Yong Lee et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

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Article Materials Science, Multidisciplinary

Conformational Phase Map of Two-Dimensional Macromolecular Graphene Oxide in Solution

Ya Wang et al.

MATTER (2020)

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Article Chemistry, Physical

Three-dimensional printing of a tunable graphene-based elastomer for strain sensors with ultrahigh sensitivity

Kai Huang et al.

CARBON (2019)

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Article Engineering, Electrical & Electronic

Direct Ink Writing of Flexible Electronics on Paper Substrate with Graphene/Polypyrrole/Carbon Black Ink

Yiming Chen et al.

JOURNAL OF ELECTRONIC MATERIALS (2019)

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Article Materials Science, Multidisciplinary

Ultra-broadband metamaterial absorber with graphene composites fabricated by 3D printing

Lixian Yin et al.

MATERIALS LETTERS (2019)

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Article Nanoscience & Nanotechnology

3D printed graphene/polydimethylsiloxane composite for stretchable strain sensor with tunable sensitivity

Zhenyu Wang et al.

NANOTECHNOLOGY (2019)

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Article Chemistry, Multidisciplinary

Thermally Conductive Reduced Graphene Oxide Thin Films for Extreme Temperature Sensors

Yuqing Zeng et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Nanoscience & Nanotechnology

Graphene-Reinforced Biodegradable Resin Composites for Stereolithographic 3D Printing of Bone Structure Scaffolds

Zuying Feng et al.

JOURNAL OF NANOMATERIALS (2019)

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Article Chemistry, Multidisciplinary

Selective Laser Sintering Fabricated Thermoplastic Polyurethane/Graphene Cellular Structures with Tailorable Properties and High Strain Sensitivity

Alfredo Ronca et al.

APPLIED SCIENCES-BASEL (2019)

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Article Chemistry, Multidisciplinary

PLA/Graphene/MWCNT Composites with Improved Electrical and Thermal Properties Suitable for FDM 3D Printing Applications

Evgeni Ivanov et al.

APPLIED SCIENCES-BASEL (2019)

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Article Materials Science, Multidisciplinary

3D printing of hybrid MoS2-graphene aerogels as highly porous electrode materials for sodium ion battery anodes

Emery Brown et al.

MATERIALS & DESIGN (2019)

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Article Polymer Science

Influence of post-condensation on the crystallization kinetics of PA12: From virgin to reused powder

F. Paolucci et al.

POLYMER (2019)

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Article Nanoscience & Nanotechnology

Stereolithographic 3D Printing-Based Hierarchically Cellular Lattices for High-Performance Quasi-Solid Supercapacitor

Jianzhe Xue et al.

NANO-MICRO LETTERS (2019)

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Article Nanoscience & Nanotechnology

Preserving Fine Structure Details and Dramatically Enhancing Electron Transfer Rates in Graphene 3D-Printed Electrodes via Thermal Annealing: Toward Nitroaromatic Explosives Sensing

Filip Novotny et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

3D printing of free-standing and flexible nitrogen doped graphene/polyaniline electrode for electrochemical energy storage

Fuguo Zhou et al.

CHEMICAL PHYSICS LETTERS (2019)

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Review Engineering, Manufacturing

Additive manufacturing high performance graphene-based composites: A review

Yan Li et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2019)

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Article Engineering, Chemical

GO-modified flexible polymer nanocomposites fabricated via 3D stereolithography

Chi Him Alpha Tsang et al.

FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING (2019)

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Article Materials Science, Multidisciplinary

A versatile PDMS submicrobead/graphene oxide nanocomposite ink for the direct ink writing of wearable micron-scale tactile sensors

Ge Shi et al.

APPLIED MATERIALS TODAY (2019)

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Article Nanoscience & Nanotechnology

3D Printing of Covalent Functionalized Graphene Oxide Nanocomposite via Stereolithography

Jerome O. Palaganas et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

3D electrohydrodynamic printing of highly aligned dual-core graphene composite matrices

Baolin Wang et al.

CARBON (2019)

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Article Engineering, Multidisciplinary

Two-step approach based on selective laser sintering for high performance carbon black/polyamide 12 composite with 3D segregated conductive network

Rui Hong et al.

COMPOSITES PART B-ENGINEERING (2019)

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Article Nanoscience & Nanotechnology

3D-Printed Graphene/Polydimethylsiloxane Composites for Stretchable and Strain-Insensitive Temperature Sensors

Zhenyu Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

Improvement of Surface Roughness and Hydrophobicity in PETG Parts Manufactured via Fused Deposition Modeling (FDM): An Application in 3D Printed Self-Cleaning Parts

Juan M. Barrios et al.

MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Laser-Induced Graphene: From Discovery to Translation

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Article Materials Science, Multidisciplinary

Flexible Pressure Sensors with Wide Linearity Range and High Sensitivity Based on Selective Laser Sintering 3D Printing

Tong Zhang et al.

ADVANCED MATERIALS TECHNOLOGIES (2019)

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Article Engineering, Multidisciplinary

Digital light processing 3D printing of graphene/carbonyl iron/polymethyl methacrylate nanocomposites for efficient microwave absorption

Yuxin Zuo et al.

COMPOSITES PART B-ENGINEERING (2019)

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Article Chemistry, Physical

Highly conductive, mechanically strong graphene monolith assembled by three-dimensional printing of large graphene oxide

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JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Extrusion-based 3D printing of food pastes: Correlating rheological properties with printing behaviour

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INNOVATIVE FOOD SCIENCE & EMERGING TECHNOLOGIES (2019)

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Efficient 3D Printed Pseudocapacitive Electrodes with Ultrahigh MnO2 Loading

Bin Yao et al.

JOULE (2019)

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Review Nanoscience & Nanotechnology

Ink-based 3D printing technologies for graphene-based materials: a review

Jingfeng Wang et al.

ADVANCED COMPOSITES AND HYBRID MATERIALS (2019)

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Article Chemistry, Physical

3D printed graphene/nickel electrodes for high areal capacitance electrochemical storage

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JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Duplex printing of all-in-one integrated electronic devices for temperature monitoring

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JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Nanoscience & Nanotechnology

Recent advances on 3D printing graphene-based composites

Haichang Guo et al.

NANO MATERIALS SCIENCE (2019)

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Shape-driven arrest of coffee stain effect drives the fabrication of carbon-nanotube-graphene-oxide inks for printing embedded structures and temperature sensors

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NANOSCALE (2019)

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Article Chemistry, Multidisciplinary

3D graphene-containing structures for tissue engineering

J. Li et al.

MATERIALS TODAY CHEMISTRY (2019)

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Review Chemistry, Physical

Surface Modification of 3D Printed PLA Objects by Fused Deposition Modeling: A Review

Eda Hazal Baran et al.

COLLOIDS AND INTERFACES (2019)

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Review Engineering, Electrical & Electronic

Recent Progress of Direct Ink Writing of Electronic Components for Advanced Wearable Devices

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ACS APPLIED ELECTRONIC MATERIALS (2019)

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Three-Dimensional Printing of Polyaniline/Reduced Graphene Oxide Composite for High-Performance Planar Supercapacitor

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Generalized 3D Printing of Graphene-Based Mixed-Dimensional Hybrid Aerogels

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ACS NANO (2018)

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Laser-Induced Graphene by Multiple Lasing: Toward Electronics on Cloth, Paper, and Food

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ACS NANO (2018)

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Article Chemistry, Multidisciplinary

An Ultralight Graphene Honeycomb Sandwich for Stretchable Light-Emitting Displays

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Direct 3D Printing of Ultralight Graphene Oxide Aerogel Microlattices

Yanqiu Jiang et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Novel Materials for 3D Printing by Photopolymerization

Michael Layani et al.

ADVANCED MATERIALS (2018)

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Extrusion-Based 3D Printing of Hierarchically Porous Advanced Battery Electrodes

Steven D. Lacey et al.

ADVANCED MATERIALS (2018)

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Anisotropy of graphene scaffolds assembled by three-dimensional printing

Kai Huang et al.

CARBON (2018)

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Electrical and thermal conductivities of MWCNT/polymer composites fabricated by selective laser sintering

Shangqin Yuan et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2018)

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High-strength epoxy nanocomposites for 3D printing

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COMPOSITES SCIENCE AND TECHNOLOGY (2018)

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High temperature rheological behavior and sintering kinetics of CF/PEEK composites during selective laser sintering

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Highly stretchable carbon aerogels

Fan Guo et al.

NATURE COMMUNICATIONS (2018)

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Development of 3D-Printed Embedded Temperature Sensor for Both Terrestrial and Aquatic Environmental Monitoring Robots

Memoon Sajid et al.

3D PRINTING AND ADDITIVE MANUFACTURING (2018)

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Review Chemistry, Physical

Recent advancements in supercapacitor technology

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NANO ENERGY (2018)

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Direct ink writing of organic and carbon aerogels

Swetha Chandrasekaran et al.

MATERIALS HORIZONS (2018)

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3D Printing Fiber Electrodes for an All-Fiber Integrated Electronic Device via Hybridization of an Asymmetric Supercapacitor and a Temperature Sensor

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ADVANCED SCIENCE (2018)

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3D-Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li-CO2 Batteries

Yun Qiao et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Architectured Leaf-Inspired Ni0.33Co0.66S2/Graphene Aerogels via 3D Printing for High-Performance Energy Storage

Xingwei Tang et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Fabrication of ABS/Graphene Oxide Composite Filament for Fused Filament Fabrication (FFF) 3D Printing

C. Aumnate et al.

ADVANCES IN MATERIALS SCIENCE AND ENGINEERING (2018)

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Article Chemistry, Physical

Plastic Metal-Free Electric Motor by 3D Printing of Graphene-Polyamide Powder

Al C. de Leon et al.

ACS APPLIED ENERGY MATERIALS (2018)

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Article Materials Science, Multidisciplinary

Development of novel highly conductive 3D printable hybrid polymer-graphene composites

Velram Balaji Mohan et al.

MATERIALS TODAY COMMUNICATIONS (2018)

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3D-Printed Multidrug-Eluting Stent from Graphene-Nanoplatelet-Doped Biodegradable Polymer Composite

Santosh K. Misra et al.

ADVANCED HEALTHCARE MATERIALS (2017)

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Article Multidisciplinary Sciences

Linking Rheology and Printability for Dense and Strong Ceramics by Direct Ink Writing

Amin M'Barki et al.

SCIENTIFIC REPORTS (2017)

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3D printing of CNT-and graphene-based conductive polymer nanocomposites by fused deposition modeling

K. Gnanasekaran et al.

APPLIED MATERIALS TODAY (2017)

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Article Engineering, Multidisciplinary

Study of graphene oxide-based 3D printable composites: Effect of the in situ reduction

Annalisa Chiappone et al.

COMPOSITES PART B-ENGINEERING (2017)

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Article Chemistry, Multidisciplinary

Graphene-Paper Pressure Sensor for Detecting Human Motions

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ACS NANO (2017)

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Review Materials Science, Multidisciplinary

Fundamentals and applications of 3D printing for novel materials

Jian-Yuan Lee et al.

APPLIED MATERIALS TODAY (2017)

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3D bioprinted graphene oxide-incorporated matrix for promoting chondrogenic differentiation of human bone marrow mesenchymal stem cells

Xuan Zhou et al.

CARBON (2017)

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High-Strength Stereolithographic 3D Printed Nanocomposites: Graphene Oxide Metastability

Jill Z. Manapat et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

Ultralight Graphene Foam/Conductive Polymer Composites for Exceptional Electromagnetic Interference Shielding

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ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

UV Cross-Linkable Graphene/Poly(trimethylene Carbonate) Composites for 3D Printing of Electrically Conductive Scaffolds

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ACS Applied Materials & Interfaces (2016)

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Article Nanoscience & Nanotechnology

Fabrication of Highly Stretchable Conductors Based on 3D Printed Porous Poly(dimethylsiloxane) and Conductive Carbon Nanotubes/Graphene Network

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ACS APPLIED MATERIALS & INTERFACES (2016)

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Graphene Oxide-Based Electrode Inks for 3D-Printed Lithium-Ion Batteries

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ADVANCED MATERIALS (2016)

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Review Biotechnology & Applied Microbiology

3D bioprinting for engineering complex tissues

Christian Mandrycky et al.

BIOTECHNOLOGY ADVANCES (2016)

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Three-dimensional multi-recognition flexible wearable sensor via graphene aerogel printing

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CHEMICAL COMMUNICATIONS (2016)

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Review Chemistry, Multidisciplinary

3D-printing technologies for electrochemical applications

Adriano Ambrosi et al.

CHEMICAL SOCIETY REVIEWS (2016)

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Fused deposition modelling with ABS-graphene nanocomposites

Sithiprumnea Dul et al.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2016)

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Supercapacitors Based on Three-Dimensional Hierarchical Graphene Aerogels with Periodic Macropores

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NANO LETTERS (2016)

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3D Printing of Graphene Aerogels

Qiangqiang Zhang et al.

SMALL (2016)

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Fabrication of highly conductive graphene flexible circuits by 3D printing

Di Zhang et al.

SYNTHETIC METALS (2016)

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Article Chemistry, Physical

An ultra-sensitive and rapid response speed graphene pressure sensors for electronic skin and health monitoring

Zheng Lou et al.

NANO ENERGY (2016)

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Article Chemistry, Multidisciplinary

Three-Dimensional Printing of High-Content Graphene Scaffolds for Electronic and Biomedical Applications

Adam E. Jakus et al.

ACS NANO (2015)

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Mechanically Tough Large-Area Hierarchical Porous Graphene Films for High-Performance Flexible Supercapacitor Applications

Zhiyuan Xiong et al.

ADVANCED MATERIALS (2015)

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Printing in Three Dimensions with Graphene

Esther Garcia-Tunon et al.

ADVANCED MATERIALS (2015)

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Graphene fiber: a new trend in carbon fibers

Zhen Xu et al.

MATERIALS TODAY (2015)

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3D stereolithography printing of graphene oxide reinforced complex architectures

Dong Lin et al.

NANOTECHNOLOGY (2015)

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Highly compressible 3D periodic graphene aerogel microlattices

Cheng Zhu et al.

NATURE COMMUNICATIONS (2015)

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Review Physics, Applied

Review of selective laser melting: Materials and applications

C. Y. Yap et al.

APPLIED PHYSICS REVIEWS (2015)

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3D Printing of Reduced Graphene Oxide Nanowires

Jung Hyun Kim et al.

ADVANCED MATERIALS (2015)

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The rheological behaviour of concentrated dispersions of graphene oxide

Cristina Valles et al.

JOURNAL OF MATERIALS SCIENCE (2014)

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A decade of graphene research: production, applications and outlook

Edward P. Randviir et al.

MATERIALS TODAY (2014)

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Deposition direction-dependent failure criteria for fused deposition modeling polycarbonate

Nevin Hill et al.

RAPID PROTOTYPING JOURNAL (2014)

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Graphene oxide dispersions: tuning rheology to enable fabrication

Sina Naficy et al.

MATERIALS HORIZONS (2014)

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3D Printing of Free Standing Liquid Metal Microstructures

Collin Ladd et al.

ADVANCED MATERIALS (2013)

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Article Chemistry, Multidisciplinary

Multifunctional, Ultra-Flyweight, Synergistically Assembled Carbon Aerogels

Haiyan Sun et al.

ADVANCED MATERIALS (2013)

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3D Printing of Interdigitated Li-Ion Microbattery Architectures

Ke Sun et al.

ADVANCED MATERIALS (2013)

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Graphene based piezoresistive pressure sensor

Shou-En Zhu et al.

APPLIED PHYSICS LETTERS (2013)

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Review Engineering, Biomedical

A review on stereolithography and its applications in biomedical engineering

Ferry P. W. Melchels et al.

BIOMATERIALS (2010)

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Review Multidisciplinary Sciences

Graphene: Status and Prospects

A. K. Geim

SCIENCE (2009)

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Direct ink writing of 3D functional materials

Jennifer A. Lewis

ADVANCED FUNCTIONAL MATERIALS (2006)

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Colloidal inks for directed assembly of 3-D periodic structures

JE Smay et al.

LANGMUIR (2002)

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