期刊
MATERIALS
卷 16, 期 15, 页码 -出版社
MDPI
DOI: 10.3390/ma16155425
关键词
hydrogen storage; absorption; desorption isotherms; LaNi(4 4)A(l0 3)F(e0 3) alloy; numerical model; thermodynamic functions
In this article, the experimental measurements of the absorption/desorption P-C-T isotherms of hydrogen in the LaNi4.4Fe0.3Al0.3 alloy at different temperatures and constant hydrogen pressure have been studied using a numerical model. The mathematical equations of this model contain parameters derived from the experimental data and the profiles of these parameters during the absorption/desorption process are studied. The evolution of thermodynamic functions with pressure, such as entropy, Gibbs free energy (G), and internal energy, are determined from the experimental data.
In this article, the experimental measurements of the absorption/desorption P-C-T isotherms of hydrogen in the LaNi4.4Fe0.3Al0.3 alloy at different temperatures and constant hydrogen pressure have been studied using a numerical model. The mathematics equations of this model contain parameters, such as the two terms, n(& alpha;) and n(& beta;,) representing the numbers of hydrogen atoms per site; N-m & alpha; and N-m & beta; are the receptor sites' densities, and the energetic parameters are P-& alpha; and P-& beta;. All these parameters are derived by numerically adjusting the experimental data. The profiles of these parameters during the absorption/desorption process are studied as a function of temperature. Thereafter, we examined the evolution of the internal energy versus temperature, which typically ranges between 138 and 181 kJmol(-1) for the absorption process and between 140 and 179 kJmol(-1) for the desorption process. The evolution of thermodynamic functions with pressure, for example, entropy, Gibbs free energy (G), and internal energy, are determined from the experimental data of the hydrogen absorption and desorption isotherms of the LaNi(4.4)A(l0.3)F(e0.3) alloy.
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