期刊
MATERIALS
卷 16, 期 21, 页码 -出版社
MDPI
DOI: 10.3390/ma16216874
关键词
synthesis; application; titanium sub-oxides; Magneli phase
Magneli phase titanium oxides, also known as titanium sub-oxides, are electrically conducting ceramic materials with attractive properties such as electrical conductivity, corrosion resistance and optical properties. The synthesis of nanostructured titanium sub-oxides has been making progress and they have potential applications in conducting materials, fuel cells, coatings, and electronic and optoelectronic devices.
Magneli phase titanium oxides, also called titanium sub-oxides (TinO2n-1, 4 < n < 9), are a series of electrically conducting ceramic materials. The synthesis and applications of these materials have recently attracted tremendous attention because of their applications in a number of existing and emerging areas. Titanium sub-oxides are generally synthesized through the reduction of titanium dioxide using hydrogen, carbon, metals or metal hydrides as reduction agents. More recently, the synthesis of nanostructured titanium sub-oxides has been making progress through optimizing thermal reduction processes or using new titanium-containing precursors. Titanium sub-oxides have attractive properties such as electrical conductivity, corrosion resistance and optical properties. Titanium sub-oxides have played important roles in a number of areas such as conducting materials, fuel cells and organic degradation. Titanium sub-oxides also show promising applications in batteries, solar energy, coatings and electronic and optoelectronic devices. Titanium sub-oxides are expected to become more important materials in the future. In this review, the recent progress in the synthesis methods and applications of titanium sub-oxides in the existing and emerging areas are reviewed.
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