Polymeric Biocomposite Based on Thermoplastic Polyurethane (TPU) and Protein and Elastomeric Waste Mixture

Polymeric biocomposites based on TPU/recycled TPUW/mixed leather and SBR rubber waste unmodified/modified with polydimethylsiloxane/PE-g-MA in different percentages were made via the mixing technique on a Plasti-Corder Brabender mixer with an internal capacity of 350 cm(3). The waste, which came from the shoe industry, was cryogenically ground with the help of a cryogenic cyclone mill at micrometric sizes and different speeds. For the tests, standard plates of 150 x 150 x 2 mm were obtained in a laboratory-scale hydraulic press via the method of compression between its plates, with well-established parameters. The biocomposites were tested physico-mechanically and rheologically (MFI) according to the standards in force on polymer-specific equipment, also via FT-IR spectroscopy and microscopy, as well as via differential scanning calorimetry-DSC. Following the tests carried out, according to the standard for use in the footwear industry, at least two samples present optimal values (of interest) suitable for use in the footwear industry by injection or pressing in forming moulds.

Automated summary

Polymeric biocomposites based on TPU/recycled TPUW/mixed leather and SBR rubber waste unmodified/modified with polydimethylsiloxane/PE-g-MA in different percentages were prepared via mixing technique. The waste was cryogenically ground to micrometric sizes and different speeds. Standard plates were obtained through compression method using a laboratory-scale hydraulic press. Physico-mechanical and rheological tests were conducted on the biocomposites, along with FT-IR spectroscopy, microscopy, and DSC. According to the footwear industry standards, at least two samples showed optimal values suitable for injection or pressing in forming molds.