Effect of sodium dodecyl sulfate surfactant on the surface properties of electroless NiP-TiO2-ZrO2 composite coatings on magnesium AZ91D substrate

This research incorporated nano TiO2 and ZrO2 particles into the NiP electroless bath to produce NiP-TiO2-ZrO2 composite deposits on magnesium AZ91D substrates. The impact of sodium dodecyl sulfate (SDS) (anionic surfactant) was utilized for deposition to minimize the agglomeration and clustering of particles in the electroless bath. Surface properties such as atomic force microscopy, energy dispersive X-Ray analysis, scanning electron microscopy, and X-ray diffraction are used to evaluate the surface morphologies of coating, surface roughness, elementary composition, and crystalline structure of the deposits. Furthermore, the impact of SDS surfactant on the corrosion properties of deposits was also studied using potentiodynamic polarization in a 5 wt% NaCl solution. The overall results reveal that incorporating anionic surfactant SDS at the optimum concentration of 1.5 g/L (CMC value) improved wettability, deposition rate, and surface roughness compared to the deposits developed without surfactant. The proposed mechanism is that the molecules of SDS surfactant could come into contact with the surface of NiP-TiO2-ZrO2 com-posite coating in the bath, increasing nanoparticle dispersion and resulting in a uniform coating. Furthermore, the electrochemical results show improved corrosion protection efficiency (PE%) of NiP-TiO2-ZrO2 composite coatings by increasing the concentration of SDS surfactant, achieving X87.9% at (1.5 g/L) CMC value.& COPY; 2023 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

This research introduced nano TiO2 and ZrO2 particles to the NiP electroless bath to create NiP-TiO2-ZrO2 composite deposits on magnesium AZ91D substrates. The addition of sodium dodecyl sulfate (SDS) as an anionic surfactant minimized particle agglomeration and improved the surface properties of the deposits. The study also explored the impact of SDS surfactant on the corrosion properties of the coatings. The overall findings reveal that incorporating SDS surfactant at the optimum concentration enhanced wettability, deposition rate, and corrosion protection efficiency of the composite coatings.