Engineered Polymer Architectures for Thermo-Responsive Desiccants in Dehumidification Applications

Humidity control is relevant to many processes in buildings and manufacturing and is responsible for over 600 million tons of CO2 annually. As such, desiccants that can efficiently remove moisture from air can greatly reduce emissions. A new class of desiccant materials, thermo-responsive desiccants, has been of increased interest in the literature. These materials are generally based on thermo-responsive polymers and exhibit a temperature-dependent isotherm, an attribute that is small in traditional desiccants. In this work, seven key parameters needed to create an effective thermo-responsive polymer desiccant are identified using a combination of modeling and experimental data. It is found that more thermo-responsiveness is not necessarily better for energy efficiency, and that an optimal, medium value is desired. Additionally, polymer composition and architecture play key roles in adjusting the seven key parameters. Finally, based on findings from both modeling and experimental work, guidelines on synthesizing future thermo-responsive polymer desiccants are presented.

Automated summary

Humidity control is important in buildings and manufacturing processes, contributing to over 600 million tons of annual CO2 emissions. Thermo-responsive desiccants, which are based on polymers with temperature-dependent isotherms, have gained attention due to their potential for efficient moisture removal. This study identifies seven key parameters for effective thermo-responsive polymer desiccants through modeling and experimental data. It is found that an optimal, moderate level of thermo-responsiveness is desired for energy efficiency, and polymer composition and architecture play crucial roles in adjusting these parameters. Guidelines for synthesizing future thermo-responsive polymer desiccants are proposed based on the findings.