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Review
Chemistry, Applied
Kun Wang et al.
Summary: Li-metal batteries (LMBs) are attracting research attention again due to their high-energy requirements. Commercial carbonate electrolytes have unfavorable reactions with the Li-metal anode, leading to the formation of unstable solid electrolyte interphase (SEI) and Li dendrites. However, the incorporation of lithium nitrate (LiNO3) into commercial carbonate electrolytes can successfully stabilize the SEI and enable dendrite-free Li-metal anode, making LMBs practical.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Chemistry, Physical
Lei Xu et al.
Summary: An artificial protective interlayer of GO-BQ@LiTFSI (GBL) is designed to overcome the challenge of Li dendrite growth in Li metal batteries. The GBL interlayer is prepared by incorporating graphene-oxide sheets with a liquid organic eutectic mixture. The GBL interlayer promotes uniform nucleation of Li and regulates Li-ion flux, resulting in the formation of planar Li metal and high electrochemical stability.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Zhenglu Zhu et al.
Summary: Recruiting anions from electrolyte additives into the lithium ion solvation structure is a promising strategy for the construction of long-lifespan Li-metal batteries (LMBs). However, inadequate understanding of the anion-involved Li+ solvation hinders the finding of new anion additives. The effects of the newly-introduced NO3- anion on the Li+ solvation structure are investigated, showing that it reduces the electrostatic potential of the Li+ solvation cluster, especially for solvated solvents, thus improving electrolyte stability against the Li anode. The anion selection coefficient, based on the anion size to the binding energy toward Li+, is proposed as a new selection principle, leading to the discovery of the beneficial hexafluorosilicate anion for LMBs.
ADVANCED ENERGY MATERIALS
(2023)
Article
Energy & Fuels
Zhaohui Wu et al.
Summary: Controlling the nucleation and growth is essential for enabling long-life Li-metal batteries. Here, the authors report the growth of faceted single-crystalline Li seeds on a lithiophobic Fe/LiF composite substrate that enables dense Li deposition under fast-charging conditions. A cell using a 3 mAh cm(-2) LiNi0.8Co0.1Mn0.1O2 (LiNMC811) cathode, onefold excess of lithium and 3 g Ah(-1) electrolyte cycles at a 1 C rate for more than 130 cycles with 80% capacity retention, a 550% improvement over the baseline cells. These findings advance the understanding of lithium nucleation and pave the way for realizing high-energy, fast-charging Li-metal batteries.
Article
Chemistry, Multidisciplinary
Yucheng Wen et al.
Summary: By introducing NO3- into carbonate-based electrolytes through synthesizing targeted covalent organic frameworks, a reliable SEI for Li metal batteries is established, leading to significantly improved cycling and rate performance with capacity retention dramatically increased. This strategy presents a potential avenue for the application of COFs in building stable SEIs for high-energy-density LMBs.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Huadong Yuan et al.
Summary: This review presents a historical framework of important concepts and breakthroughs in enabling lithium metal anodes to be practically applied. It also discusses and summarizes the major contributions from different institutions, journals, authors, and highly cited papers. The goal of this review is to motivate more researchers to pave the way for high-energy lithium metal batteries in the future.
Article
Multidisciplinary Sciences
Yujing Liu et al.
Summary: In this study, self-assembled monolayers (SAMs) were utilized to control electrolyte degradation and solid-electrolyte interphase (SEI) formation in lithium metal batteries (LMBs), resulting in improved cycling performance and lifespan.
Article
Chemistry, Multidisciplinary
Li-Peng Hou et al.
Summary: This study proposes and validates the use of modified nitrate ions (NO3-) to improve the homogeneity of the solid electrolyte interphase (SEI) in lithium metal batteries. By forming isosorbide dinitrate (ISDN), the resonant structure of NO3- is broken and its reducibility is improved. Lithium-sulfur batteries with ISDN additives show improved cycling performance and specific energy.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Jun Zhao et al.
Summary: This study innovatively designed a mechanically interlocked network (MIN) as an interfacial layer to protect the Li anode, incorporating unique energy dissipation capability for surviving repeated volume variation. The results showed that the MIN-coated Li anode exhibited prolonged cycling life and good capacity retention.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Physical
Robert Usiskin et al.
Summary: Modern batteries are complex systems with high-density interfaces, and device performance is often determined by effects at these interfaces. Space charge layers at interfaces can modify charge transport, transfer, and storage properties. Practical interfaces exhibit additional complex phenomena like passivation layer formation, current constriction, and partial blocking of mobile species. Specific interfacial issues related to mass storage modes are discussed, with a focus on solid-state batteries.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Chong Yan et al.
Summary: Research on solid electrolyte interphase (SEI) formation should focus on its nucleation and growth mechanism, especially the establishment of isothermal electrochemical crystallization theory to explain the process.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Zilong Zhuang et al.
Summary: This study successfully prepared ultrathin graphitic carbon nitride nanosheets for use on lithium metal anodes, forming an artificial solid electrolyte interface (SEI) to suppress lithium dendrite growth and enhance the affinity of electrodes with electrolytes.
Article
Multidisciplinary Sciences
Miran Gaberscek
Summary: Electrochemical impedance spectroscopy is a crucial technique for understanding Li-based battery processes, with untapped potential for comprehending battery storage mechanisms. While traditionally considered as a supplementary tool, the application of EIS should be enhanced through improved experimental design and advanced data analysis techniques.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Sichen Gu et al.
Summary: By adding rubidium nitrate additive coordinated with 18-crown-6 crown ether to the carbonate electrolyte, the stability of lithium metal anodes can be improved, leading to higher Coulombic efficiency and better battery performance.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Lin Fu et al.
Summary: The concept of salt-in-metal is proposed in this study, where a Li/LiNO3 composite foil is constructed to embed LiNO3 into the bulk structure of metallic Li. This helps in achieving a stable solid electrolyte interphase (SEI) and regulating the nucleation and growth processes of Li, reducing dendritic Li growth. This approach results in stable cycling and high capacity retention for rechargeable batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Nan Piao et al.
Summary: By introducing lithium nitrate (LiNO3) and fluoroethylene carbonate (FEC) into commercial 1 M LiPF6/EC-DMC electrolytes, an inorganic-enhanced LiF-Li3N SEI was designed to improve the Li plating/stripping Coulombic efficiency to 99.6% in 100 cycles. This strategy enabled a lithium metal anode cell to achieve an average CE of 99.7% and a capacity retention of 90.8% after 150 cycles, demonstrating high performance in commercial carbonate electrolytes.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Yi-Hong Tan et al.
Summary: Electrolyte engineering with fluorinated additives has the potential to enhance cycling stability and safety of high-energy Li-metal batteries. The electrolyte developed in this study utilizing a porous lithium fluoride strategy demonstrated nonflammability and high electrochemical performance, leading to stable cycling of Li-metal anodes even at high current densities. This new electrolyte engineering strategy offers promise for stable and safe Li-metal batteries.
ADVANCED MATERIALS
(2021)
Review
Nanoscience & Nanotechnology
Xin He et al.
Summary: This paper discusses the limitations of rechargeable Li metal batteries and the requirements for an ideal passivation layer, focusing on the reactions at the Li metal-liquid electrolyte interface that are crucial for preventing Li consumption and delaying electrolyte decomposition.
NATURE REVIEWS MATERIALS
(2021)
Review
Electrochemistry
Xiang Li et al.
Summary: This review provides an overview of the impact and applications of nitrates in lithium batteries, focusing on their roles in the solid-electrolyte interphase and cathode-electrolyte interphase, as well as strategies for regulating solvation behavior.
Review
Materials Science, Multidisciplinary
Xin Wang et al.
Summary: The practical application of lithium metal batteries is limited by safety problems and low Coulombic efficiency, but graphene-based materials have shown promise in solving these issues. Various protection strategies using GBMs are summarized and challenges and solutions for future development are discussed.
NEW CARBON MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Birger Horstmann et al.
Summary: Despite the approaching performance limits of lithium-ion intercalation batteries, research is intensifying on next-generation battery technologies, with a focus on the use of lithium metal anode. However, the poor morphological stability and Coulombic efficiency of the lithium metal anode in liquid electrolytes present challenges for reversible cycling. Experimental and theoretical insights are being used to explore pathways for stable cycling of two-dimensional lithium metal and improvements in understanding lithium metal nucleation and deposition on the nanoscale. Recent advances in electrolytes and SEI design show potential for stable cycling and mitigation of morphological instabilities.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Engineering, Environmental
Xin-Yang Yue et al.
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Chemistry, Multidisciplinary
Ying Huang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Multidisciplinary Sciences
Huadong Yuan et al.
Article
Chemistry, Physical
Jingyi Wu et al.
Article
Chemistry, Multidisciplinary
Wei-Wei Wang et al.
Review
Chemistry, Physical
Xiangwen Gao et al.
Article
Chemistry, Multidisciplinary
Jiale Fu et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Multidisciplinary Sciences
Qing Zhao et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2020)
Article
Materials Science, Multidisciplinary
Yu-Xing Yao et al.
Article
Chemistry, Physical
Xin-Yang Yue et al.
Article
Nanoscience & Nanotechnology
Meina Lei et al.
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Physical
Feilong Qiu et al.
ADVANCED ENERGY MATERIALS
(2019)
Article
Chemistry, Physical
Ke Chen et al.
ENERGY STORAGE MATERIALS
(2019)
Article
Multidisciplinary Sciences
Qiuwei Shi et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2018)
Article
Chemistry, Multidisciplinary
Chong Yan et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2018)
Article
Energy & Fuels
Xiao Liang et al.
Article
Chemistry, Physical
Stefan Grimme et al.
JOURNAL OF CHEMICAL PHYSICS
(2010)
Article
Electrochemistry
Qian Sun et al.
ELECTROCHEMICAL AND SOLID STATE LETTERS
(2007)
Article
Chemistry, Physical
J Torres et al.
JOURNAL OF PHYSICAL CHEMISTRY B
(2003)
