4.8 Article

Multifunctional Zn-N4 Catalysts for the Coupling of CO2 with Epoxides into Cyclic Carbonates

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

Biomimetic asymmetric catalysis

Xiao Xiao et al.

Summary: Enzymes are essential for biological transformations and have attracted great attention for their structures and functions. Biomimetic chemistry has rapidly developed in response to the demand for bioactive molecules and efficient synthesis. Biomimetic asymmetric catalysis, inspired by enzymes, has been recognized as one of the most promising strategies for producing valuable chiral compounds. This review summarizes the evolution of biomimetic asymmetric catalysis in terms of biomimetic design, catalyst development, and catalytic transformations, providing insights into bridging the gap between bio-catalysis and chemical synthesis.

SCIENCE CHINA-CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

[HDBU]Br@P-DD as Porous Organic Polymer-Supported Ionic Liquid Catalysts for Chemical Fixation of CO2 into Cyclic Carbonates

Huadeng Li et al.

Summary: In this study, a series of porous organic polymer-supported ionic liquids catalysts were successfully synthesized through a one-pot four-component reaction. The as-prepared catalysts exhibited versatile hierarchical porosity and excellent thermostability. These catalysts showed outstanding catalytic performance in the cycloaddition reaction of epoxides with CO2, providing a promising method for the synthesis of cyclic carbonates.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

Article Chemistry, Multidisciplinary

Theoretical and experimental investigations of the enantioselective epoxidation of olefins catalyzed by manganese complexes

Jin Lin et al.

Summary: The enantioselective epoxidation of olefin by Mn-II(R,R-PMCP)(OTf)(2), H2O2 and H2SO4 was studied using DFT calculations and experiments. Theoretical results suggest that [Mn-V(O)(R,R-PMCP)(SO4)](+) species acts as the active species for the olefin epoxidation, which is formed with the assistance of H2SO4. Mn-III-persulfate also plays a role in this system but does not directly promote the olefin epoxidation, instead transforming into Mn-V(O) species.

CHINESE CHEMICAL LETTERS (2022)

Review Chemistry, Multidisciplinary

Porous organic polymers for CO2 capture, separation and conversion

Kyung Seob Song et al.

Summary: This review provides key insights into the structure-property relationships governing the separation, capture and conversion of CO2 using porous organic polymers (POPs). Recent advances in the field, with a focus on engineering the pore environment, are also highlighted.

CHEMICAL SOCIETY REVIEWS (2022)

Review Chemistry, Multidisciplinary

Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity

Guan-Wen Yang et al.

Summary: Organoboron catalysts play a significant role in chemical transformations. This study summarizes recent advances in developing organoboron catalysts that combine high efficiency and easy preparation through modular design, optimizing the catalysts for various chemical reactions.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Article Chemistry, Physical

C3-symmetric zinc complexes as sustainable catalysts for transforming carbon dioxide into mono- and multi-cyclic carbonates

Kanagaraj Naveen et al.

Summary: This study introduces a new single-step preparation method for synthesizing C-3-symmetric zinc complexes as efficient bifunctional catalysts for coupling CO2 with epoxides. The catalyst displayed high catalytic activity, selectivity, and recyclability, making it a promising option for green transformations.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

Tolerant Bimetallic Macrocyclic [OSSO]-Type Zinc Complexes for Efficient CO2 Fixation into Cyclic Carbonates

Junwu Chen et al.

Summary: A new type of sustainable bimetallic zinc complexes has been developed for the chemical fixation of carbon dioxide into cyclic carbonates. The catalyst showed excellent performance with high stability to moisture and oxygen, resistance to impurities, and good recyclability. The catalytic mechanism involves a Lewis acidic zinc center and a nucleophilic halide counterion from the cocatalyst.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Nanoscience & Nanotechnology

Synthesis of Bifunctional Porphyrin Polymers for Catalytic Conversion of Dilute CO2 to Cyclic Carbonates

Lina Liu et al.

Summary: The synthesis of bifunctional polymers incorporating porphyrin-Zn as Lewis acid sites and Br- as nucleophiles for the cycloaddition of dilute CO2 with epoxides has been reported. Optimized bifunctional polymer shows high catalytic activity and can efficiently catalyze the reaction even under ambient conditions. This bifunctional polymer demonstrates great potential for industrial-scale production in the field of CO2 conversion.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

Efficient Aliphatic C-H Oxidation and C=C Epoxidation Catalyzed by Porous Organic Polymer-Supported Single-Site Manganese Catalysts

Bingyang Wang et al.

Summary: This study successfully developed bioinspired manganese catalysts using porous organic polymers (POPs) as scaffolds, which showed high reactivity in oxidation reactions and could be easily recycled and reused. The single-site nature of the catalyst prevented oxidative degradation during the reaction, making it a promising approach for selective oxidation reactions.

ACS CATALYSIS (2021)

Review Chemistry, Physical

Synthesis of metalloporphyrin-based porous organic polymers and their functionalization for conversion of CO2 into cyclic carbonates: recent advances, opportunities and challenges

Rongchang Luo et al.

Summary: This review discusses the recent advances in the design and synthesis of metalloporphyrin-based POPs for CO2 catalysis, focusing on the conversion of CO2 into cyclic carbonates and the diverse synthetic strategies for preparing these materials with different functionalities and compositions. The exploration of single/multi-active-site synergistic catalytic models provides theoretical guidance for multifunctionalization of metalloporphyrin-based POPs, while also highlighting key opportunities and challenges in the field for future research and industrial applications.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Recent developments in organocatalysed transformations of epoxides and carbon dioxide into cyclic carbonates

Liping Guo et al.

Summary: This review focuses on the rapidly evolving field of organocatalysed cyclic carbonate synthesis, covering mechanisms, catalyst systems, key parameters, and future challenges. The importance of green metrics and catalyst requirements are highlighted throughout the article.

GREEN CHEMISTRY (2021)

Article Chemistry, Physical

Rational Design of Bioinspired Catalysts for Selective Oxidations

Laia Vicens et al.

ACS CATALYSIS (2020)

Article Chemistry, Multidisciplinary

Design of Novel Poly(ionic liquids) for the Conversion of CO2 to Cyclic Carbonates under Mild Conditions without Solvent

Hongbing Song et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Physical

Cyclic carbonate for highly stable cycling of high voltage lithium metal batteries

Chi-Cheung Su et al.

ENERGY STORAGE MATERIALS (2019)

Article Chemistry, Physical

Synthesis of Porous Polymeric Catalysts for the Conversion of Carbon Dioxide

Kuan Huang et al.

ACS CATALYSIS (2018)

Review Chemistry, Multidisciplinary

Efficient, selective and sustainable catalysis of carbon dioxide

Qing-Wen Song et al.

GREEN CHEMISTRY (2017)

Review Chemistry, Multidisciplinary

Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

Konstantin P. Bryliakov

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

Proton-Promoted and Anion-Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts

Chengxia Miao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Sandwich electrode designed for high performance lithium-ion battery

Chunsong Zhao et al.

NANOSCALE (2016)

Article Chemistry, Physical

Cr(salophen) Complex Catalyzed Cyclic Carbonate Synthesis at Ambient Temperature And Pressure

Jose A. Castro-Osma et al.

ACS CATALYSIS (2016)

Article Chemistry, Multidisciplinary

Cyclic Carbonate: A Recyclable Medium for Zero Discharge Tanning

Murali Sathish et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2016)

Review Chemistry, Multidisciplinary

Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Organocatalysts

Mirza Cokoja et al.

CHEMSUSCHEM (2015)

Review Chemistry, Multidisciplinary

Sustainable conversion of carbon dioxide: the advent of organocatalysis

Giulia Fiorani et al.

GREEN CHEMISTRY (2015)

Review Chemistry, Multidisciplinary

Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings

James W. Comerford et al.

GREEN CHEMISTRY (2015)

Review Multidisciplinary Sciences

Using carbon dioxide as a building block in organic synthesis

Qiang Liu et al.

NATURE COMMUNICATIONS (2015)

Review Chemistry, Physical

Recent Advances in the Catalytic Preparation of Cyclic Organic Carbonates

Carmen Martin et al.

ACS CATALYSIS (2015)

Article Chemistry, Multidisciplinary

Carbon Dioxide as a Protecting Group: Highly Efficient and Selective Catalytic Access to Cyclic cis-Diol Scaffolds

Victor Laserna et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Physical

MnII complexes with tetradentate N4 ligands: Highly efficient catalysts for the epoxidation of olefins with H2O2

Songjie Yu et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2012)

Article Multidisciplinary Sciences

The urgency of the development of CO2 capture from ambient air

Klaus S. Lackner et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)

Article Chemistry, Physical

Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2

Paolo P. Pescarmona et al.

CATALYSIS SCIENCE & TECHNOLOGY (2012)

Review Chemistry, Multidisciplinary

Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

Mirza Cokoja et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Review Chemistry, Multidisciplinary

Salen-Complex-Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides

Antonello Decortes et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Review Chemistry, Multidisciplinary

Organic Carbonates as Solvents in Synthesis and Catalysis

Benjamin Schaeffner et al.

CHEMICAL REVIEWS (2010)

Article Chemistry, Multidisciplinary

A Series of Peroxomanganese(III) Complexes Supported by Tetradentate Aminopyridyl Ligands: Detailed Spectroscopic and Computational Studies

Robert A. Geiger et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Applied

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels

Gabriele Centi et al.

CATALYSIS TODAY (2009)

Article Chemistry, Multidisciplinary

CO2 cycloaddition reactions catalyzed by an ionic liquid grafted onto a highly cross-linked polymer matrix

Ye Xie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Article Chemistry, Organic

Chemical fixation of CO2 with highly efficient ZnCl2/[BMIm]Br catalyst system

FW Li et al.

TETRAHEDRON LETTERS (2004)

Article Chemistry, Multidisciplinary

Efficient epoxidation of electron-deficient olefins with a cationic manganese complex

A Murphy et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Article Chemistry, Multidisciplinary

A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2

MC White et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)