4.8 Article

Theory predicts UV/vis-to-IR photonic down conversion mediated by excited state vibrational polaritons

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Multidisciplinary Sciences

Quantum dynamical effects of vibrational strong coupling in chemical reactivity

Lachlan P. Lindoy et al.

Summary: Recent experiments have shown that placing molecular systems inside infrared cavities can modify their ground state chemical reactivity, but the underlying theoretical explanation remains unclear. In this study, the authors employ an exact quantum dynamics approach to investigate a model of cavity-modified chemical reactions and find that quantum mechanical treatment is crucial in obtaining accurate predictions of reactivity alterations. They observe sizable changes in the rate constant, which are associated with quantum mechanical state splittings and resonances, suggesting that quantum light-matter interactions play a key role in understanding this phenomenon.

NATURE COMMUNICATIONS (2023)

Review Chemistry, Physical

Vibration-Cavity Polariton Chemistry and Dynamics

Adam D. Dunkelberger et al.

Summary: Molecular polaritons result from the coupling between light and matter, exhibiting unique optical properties and the ability to modify chemical and physical processes, including chemical reactivity and spectroscopy. Insights provided in this field may offer potential for systematically manipulating molecular polaritons in photonic and chemical applications.

ANNUAL REVIEW OF PHYSICAL CHEMISTRY (2022)

Article Physics, Multidisciplinary

Coupling function from bath density of states

S. Nemati et al.

Summary: This study presents a method to infer the coupling between an open quantum system and its bosonic environment by using the experimentally measurable density of states (DOS). It confirms the physical equivalence between the DOS of the well-known Debye model and choosing an Ohmic bath, and successfully determines the coupling parameters for materials such as gold, yttrium iron garnet (YIG), and iron. This method is important for accurately modeling the relaxation dynamics of materials, particularly for phonon-dominated spin damping in magnetic materials.
Article Multidisciplinary Sciences

Energy-efficient pathway for selectively exciting solute molecules to high vibrational states via solvent vibration-polariton pumping

Tao E. Li et al.

Summary: In an optical cavity, selectively exciting solute molecules by exciting the polariton of the solvent can significantly enhance the efficiency and selectivity of infrared photochemical reactions.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

Improving Enzyme Catalytic Efficiency by Co-operative Vibrational Strong Coupling of Water

Jyoti Lather et al.

Summary: In this study, the catalytic efficiency of an enzymatic reaction was enhanced by co-operative vibrational strong coupling of water and alpha-chymotrypsin. The selective strong coupling of specific vibrational modes resulted in a significant increase in the rate of enzymatic ester hydrolysis. Additionally, VSC was used as a spectroscopic tool to gain insights into the mechanism of the enzymatic reaction, suggesting potential applications in chemistry.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Chemistry, Multidisciplinary

Influence of Vibronic Coupling on Ultrafast Singlet Fission in a Linear Terrylenediimide Dimer

Jonathan D. Schultz et al.

Summary: Singlet fission is a photophysical process that can enhance the efficiency of solar cells, with recent experimental evidence suggesting a role for nuclear motions and vibronic coupling in supporting rapid and efficient singlet fission in organic chromophore assemblies. Observations of low-frequency coherent wavepacket transfer indicate a significant dependence of singlet fission on nonadiabatic coupling. These findings demonstrate how nonadiabatic mixing influences the complex potential energy landscape of ultrafast singlet fission.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Chemistry, Multidisciplinary

Chemistry under Vibrational Strong Coupling

Kalaivanan Nagarajan et al.

Summary: Manipulating chemistry and material properties using hybrid light-matter states has attracted considerable interest in the past decade. The strong coupling phenomenon occurs in the dark and does not require real photons to induce. Vibrational strong coupling offers exciting possibilities for molecular and material science.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays

Manuel Hertzog et al.

Summary: The addition of a gold nanorod array into a cavity containing pure organic molecules increases the total coupling strength by an order of magnitude and narrows the plasmon line width inside the cavity significantly. These results provide a step forward in exploring vibropolaritonic chemistry and may be utilized in plasmon based biosensors.

NANO LETTERS (2021)

Article Multidisciplinary Sciences

Cavity frequency-dependent theory for vibrational polariton chemistry

Xinyang Li et al.

Summary: Recent experiments show that coupling molecules inside an optical microcavity can control chemical reactivities, specifically through the mechanism of vibrational strong coupling. The modification of chemical reactivities in VSC polariton chemistry, dependent on photon frequency, can be explained by non-Markovian dynamics and the dynamic caging effect of the reaction coordinate. This study sheds light on the suppression of reaction rates for a specific cavity frequency, reminiscent of a solvent caging effect.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Excited-State Symmetry Breaking and the Laporte Rule

Zoltan Szakacs et al.

Summary: Excited-state symmetry breaking (ES-SB) is common in multibranched electron donor-acceptor (DA) molecules in polar environments. However, due to the lack of an unambiguous spectroscopic signature in the UV-vis region, electronic transient absorption (TA) has not been the preferred method for real-time observation of this phenomenon.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Chemistry, Physical

Analytic and numerical vibronic spectra from quasi-classical trajectory ensembles

Justin Provazza et al.

Summary: The truncated Wigner approximation is used to explore quantum dynamics in phase space for computing vibronic line shapes in monomer linear optical spectra. Analytic expressions for vibronic line shapes are derived for both equal and unequal frequency shifted harmonic oscillator models along with consideration of nonlinear responses to momentum fluctuations in classical trajectories. Numerical simulations are also conducted for an anharmonic shifted Morse potential model, revealing challenges in describing vibronic line shapes with large relative shifts in potentials.

JOURNAL OF CHEMICAL PHYSICS (2021)

Article Chemistry, Physical

Mode-Specific Chemistry through Vibrational Strong Coupling (or A Wish Come True)

Blake S. Simpkins et al.

Summary: Vibrational strong coupling presents new opportunities in chemical processes, but also faces obstacles such as lack of mechanism understanding, unconventional spectroscopic interpretations, and shortage of evidence. Overcoming these challenges is crucial for establishing the field of quantum optical chemistry.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Materials Science, Multidisciplinary

Strong coupling regime and hybrid quasinormal modes from a single plasmonic resonator coupled to a transition metal dichalcogenide monolayer

Chelsea Carlson et al.

Summary: This study presents a rigorous quasinormal mode approach to investigate the strong coupling behavior between a monolayer of MoSe2 and a single gold nanoparticle. The classical spectral mode splitting at the onset of strong coupling is quantified by computing the full three-dimensional hybrid quasinormal modes of the combined structure, allowing for accurate modeling of light-matter interactions without invoking traditional theories of strong coupling. Different spectral splittings are observed in the range of 80-110 meV, with no fitting parameters required for the material models.

PHYSICAL REVIEW B (2021)

Article Chemistry, Multidisciplinary

Modulation of Prins Cyclization by Vibrational Strong Coupling

Kenji Hirai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Multidisciplinary Sciences

Quantum biology revisited

Jianshu Cao et al.

SCIENCE ADVANCES (2020)

Article Chemistry, Physical

Polarized Fock States and the Dynamical Casimir Effect in Molecular Cavity Quantum Electrodynamics

Arkajit Mandal et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

Article Multidisciplinary Sciences

Intermolecular vibrations mediate ultrafast singlet fission

Hong-Guang Duan et al.

SCIENCE ADVANCES (2020)

Article Multidisciplinary Sciences

Tilting a ground-state reactivity landscape by vibrational strong coupling

A. Thomas et al.

SCIENCE (2019)

Article Nanoscience & Nanotechnology

Vibrational Strong Coupling with Surface Plasmons and the Presence of Surface Plasmon Stop Bands

Kishan S. Menghrajani et al.

ACS PHOTONICS (2019)

Article Chemistry, Multidisciplinary

Modification of Enzyme Activity by Vibrational Strong Coupling of Water

Robrecht M. A. Vergauwe et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Physics, Multidisciplinary

Purcell-Enhanced Spontaneous Emission of Molecular Vibrations

Bernd Metzger et al.

PHYSICAL REVIEW LETTERS (2019)

Article Nanoscience & Nanotechnology

Theory of Nanoscale Organic Cavities: The Essential Role of Vibration-Photon Dressed States

Felipe Herrera et al.

ACS PHOTONICS (2018)

Review Chemistry, Physical

Vibrational and Nonadiabatic Coherence in 2D Electronic Spectroscopy, the Jahn-Teller Effect, and Energy Transfer

David M. Jonas

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 69 (2018)

Article Optics

Light-matter interaction in the long-wavelength limit: no ground-state without dipole self-energy

Vasil Rokaj et al.

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS (2018)

Review Optics

Light Interaction with Photonic and Plasmonic Resonances

Philippe Lalanne et al.

LASER & PHOTONICS REVIEWS (2018)

Review Chemistry, Multidisciplinary

Polariton chemistry: controlling molecular dynamics with optical cavities

Raphael F. Ribeiro et al.

CHEMICAL SCIENCE (2018)

Article Nanoscience & Nanotechnology

Plasmonic Cavity Coupling

James T. Hugall et al.

ACS PHOTONICS (2018)

Article Chemistry, Physical

Effect of high-frequency modes on singlet fission dynamics

Yuta Fujihashi et al.

JOURNAL OF CHEMICAL PHYSICS (2017)

Article Chemistry, Physical

The Primary Photochemistry of Vision Occurs at the Molecular Speed Limit

Philip J. M. Johnson et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2017)

Article Multidisciplinary Sciences

Atoms and molecules in cavities, from weak to strong coupling in quantum-electrodynamics (QED) chemistry

Johannes Flick et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2017)

Article Optics

Absorption and photoluminescence in organic cavity QED

Felipe Herrera et al.

PHYSICAL REVIEW A (2017)

Review Chemistry, Multidisciplinary

Hybrid Light-Matter States in a Molecular and Material Science Perspective

Thomas W. Ebbesen

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Article Chemistry, Multidisciplinary

Ground-State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field

Anoop Thomas et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Physical

Two-dimensional infrared spectroscopy of vibrational polaritons of molecules in an optical cavity

Prasoon Saurabh et al.

JOURNAL OF CHEMICAL PHYSICS (2016)

Article Multidisciplinary Sciences

Modified relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons

A. D. Dunkelberger et al.

NATURE COMMUNICATIONS (2016)

Article Optics

Raman scattering with strongly coupled vibron-polaritons

Artem Strashko et al.

PHYSICAL REVIEW A (2016)

Article Chemistry, Physical

Liquid-Phase Vibrational Strong Coupling

Jino George et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Article Chemistry, Multidisciplinary

Local vibrational coherences drive the primary photochemistry of vision

Philip J. M. Johnson et al.

NATURE CHEMISTRY (2015)

Article Chemistry, Physical

Resolving the ambiguity in the relation between Stokes shift and Huang-Rhys parameter

Mathijs de Jong et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

Article Multidisciplinary Sciences

Coherent coupling of molecular resonators with a microcavity mode

A. Shalabney et al.

NATURE COMMUNICATIONS (2015)

Review Physics, Multidisciplinary

Strong coupling between surface plasmon polaritons and emitters: a review

P. Torma et al.

REPORTS ON PROGRESS IN PHYSICS (2015)

Article Chemistry, Multidisciplinary

Vibronic coherence in oxygenic photosynthesis

Franklin D. Fuller et al.

NATURE CHEMISTRY (2014)

Article Chemistry, Physical

Computing vibrational spectra from ab initio molecular dynamics

Martin Thomas et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

Article Multidisciplinary Sciences

Electronic resonance with anticorrelated pigment vibrations drives photosynthetic energy transfer outside the adiabatic framework

Vivek Tiwari et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2013)

Article Chemistry, Physical

Vibronic Enhancement of Exciton Sizes and Energy Transport in Photosynthetic Complexes

Jordan M. Womick et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2011)

Article Physics, Multidisciplinary

Phase space representation of quantum dynamics

Anatoli Polkovnikov

ANNALS OF PHYSICS (2010)

Article Materials Science, Multidisciplinary

Controlling the dynamics of a coupled atom-cavity system by pure dephasing

A. Auffeves et al.

PHYSICAL REVIEW B (2010)

Article Education, Scientific Disciplines

Wigner functions and Weyl transforms for pedestrians

William B. Case

AMERICAN JOURNAL OF PHYSICS (2008)

Review Optics

Photon confinement in photonic crystal nanocavities

Philippe Lalanne et al.

LASER & PHOTONICS REVIEWS (2008)

Article Chemistry, Multidisciplinary

Quantum chemical calculation of vibrational spectra of large molecules - Raman and IR spectra for buckminsterfullerene

J Neugebauer et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2002)