Aqueous Adsorption of Pharmaceutical Pollutants on Biochar: a Review on Physicochemical Characteristics, Classical Sorption Models, and Advancements in Machine Learning Techniques

Review Engineering, Environmental

Biopolymer - A sustainable and efficacious material system for effluent removal

Alsha Subash et al.

Summary: This review provides an in-depth perspective on the biosorption of various toxins by biopolymers and the possible interaction between the adsorbent and adsorbate.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Review Engineering, Environmental

Recent Trends in the Application of Silk-Based Composites for Remediation of Toxic Contaminants from Wastewater

Shruti Gupta et al.

Summary: The utilization of harmful chemicals has expanded dramatically due to rapid industrialization and urbanization, leading to serious threats to the environment. Conventional wastewater treatment techniques have limitations, while adsorption has emerged as an efficient method. Silk fibroin as an adsorbent offers excellent properties and can be functionalized for the removal of heavy metal ions, dyes, and oil-water separation.

JOURNAL OF POLYMERS AND THE ENVIRONMENT (2023)

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Review Computer Science, Artificial Intelligence

Neural network models for simulating adsorptive eviction of metal contaminants from effluent streams using natural materials (NMs)

Amrita Nighojkar et al.

Summary: With the rise in environmental-conscious research, natural materials (NMs) have been considered as an eco-sustainable solution for removing hazardous pollutants via adsorption. Artificial neural networks (ANN) have accelerated the adsorption propensity of adsorbents for metal ions in water, and this review evaluates their approaches in simulating the adsorption of different metal ions on NMs. The relative influence of process parameters on adsorption and future development in the field are also outlined.

NEURAL COMPUTING & APPLICATIONS (2023)

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Article Environmental Sciences

Universal machine-learning algorithm for predicting adsorption performance of organic molecules based on limited data set: Importance of feature description

Chaoyi Huang et al.

Summary: Adsorption of organic molecules can be effectively predicted using machine learning methods based on chemical structure, which can differentiate structural differences and provide relevant information for their interaction with adsorbents.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

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Article Chemistry, Multidisciplinary

Biodegradable silk-curcumin composite for sustained drug release and visual wound monitoring

N. Jaya Prakash et al.

Summary: The production of biodegradable dressing capable of sustained drug release, along with the monitoring of wound conditions, represents new heights of multifunctional platforms for wound care. The reported curcumin-loaded silk fibroin has shown sustained drug release over the time of 10 days through a non-Fickian diffusion process satisfying Korsmeyer-Peppas' model along with the visual monitoring of wound healing through notable color variation with pH as a biomarker. The superhydrophobic nature (water contact angle = 163.7) of the SF, along with the lipophilicity (CA = 0 (Blood)) and hygroscopic nature prevents wetting of wound surface, whereas the excess exudates from wounds are absorbed along with sufficient water and oxygen permeability. The pH responsiveness as a result of the keto-enol tautom-erism in curcumin was utilized for wound monitoring through visual indication enabling even ordinary people to detect the state of the wound. The in-situ biodegradation studies verified using cow-dung slurry, the degradability of the material with 25.3% weight loss within 30 days following first-order kinetics (R2 = 0.994), as a result of the attack of proteolytic enzymes on the amino acid units of SF, mitigating the concerns of medical wastes. (c) 2022 Elsevier Ltd. All rights reserved.

MATERIALS TODAY CHEMISTRY (2023)

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Review Engineering, Manufacturing

Breakthrough to the pragmatic evolution of direct ink writing: progression, challenges, and future

Komal Sandeep Pandya et al.

Summary: This paper focuses on the significance of the direct ink writing (DIW) process in the additive manufacturing industry, which enables the construction of 3D geometries using multifaceted materials. It emphasizes the influence of key process parameters, such as nozzle diameter, extrusion rate, nozzle substrate distance, extrusion pressure, and layer thickness, on ink rheology and flow. The paper also mentions the application of emerging technologies, such as machine learning, for controlling process parameters and improving ink rheology models.

PROGRESS IN ADDITIVE MANUFACTURING (2023)

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Review Chemistry, Multidisciplinary

Removal of pollutants from wastewater using alumina based nanomaterials: A review

Ramakrishna Mahesh et al.

Summary: Increasing urbanization and industrialization has led to a high demand for clean potable water, thus nanotechnology is employed to remove pollutants, pathogens, and effluents from water. The use of alumina and its composites as nanomaterials presents a potential solution for water treatment due to their unique properties. Alumina can be coated on membranes and composites can be used to purify water by removing heavy metal ions, dyes, and microbes. This review focuses on the treatment of water using alumina composites, which can be extended to other applications like dye removal and desalination with modifications.

KOREAN JOURNAL OF CHEMICAL ENGINEERING (2023)

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Review Biochemistry & Molecular Biology

Emerging Strategies in Stimuli-Responsive Silk Architectures

Niranjana Jaya Prakash et al.

Summary: The development of implantable devices using biocompatible shape memory polymers offers a less invasive alternative to the insertion of large, impliable devices. Silk materials exhibit heterogeneity in their genetic structure and physical properties due to folding and unfolding processes, and possess stimuli-responsive properties. This article explores the stimuli-responsive nature of silk and its potential applications in biomedical devices.

MACROMOLECULAR BIOSCIENCE (2023)

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Article Environmental Sciences

Removal of Aqueous Cr(VI) by Tea Stalk Biochar Supported Nanoscale Zero-Valent Iron: Performance and Mechanism

Yujie Mao et al.

Summary: Biochar-supported nanoscale zero-valent iron (800nZVI/BC) was used to efficiently remove Cr(VI) from wastewater. The material exhibited a high adsorption capacity and stability, with over 99% Cr(VI) removed within 30 minutes at pH 2. The removal process followed the pseud-second-order kinetics and Langmuir's adsorption model. The mechanism involved reduction reactions and complex formation on the surface.

WATER AIR AND SOIL POLLUTION (2023)

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Article Environmental Sciences

Impregnation of Modified Magnetic Nanoparticles on Low-Cost Agro-Waste-Derived Biochar for Enhanced Removal of Pharmaceutically Active Compounds: Performance Evaluation and Optimization Using Response Surface Methodology

Arif Jamal Siddiqui et al.

Summary: In this study, a magnetic nanocomposite based on biochar, nanoscale zerovalent iron, and chitosan was fabricated for the removal of aspirin and carbamazepine. The nanocomposite was characterized and optimized using a response surface methodology. Under optimized conditions, the maximum removal efficiency of aspirin was observed to be 97.8%, while for carbamazepine, it was 89.32%. The isotherm models, kinetics models, and thermodynamic parameters confirmed the effectiveness and feasibility of the nanocomposite.

WATER (2023)

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Article Environmental Sciences

Effective degradation of chloramphenicol in wastewater by activated peroxymonosulfate with Fe-rich porous biochar derived from petrochemical sludge

Lina Qian et al.

Summary: Excess sludge in petroleum industry can be converted into biochar catalysts to reduce environmental risk and recover resources. In this study, activated sludge biochar (ASC) was produced from petrochemical sludge and its chloramphenicol (CAP) removal performance was evaluated. The results showed that ASC 800 exhibited the best CAP removal performance. The study confirmed that porous biochar derived from petrochemical sludge is effective for removing organic pollutants from wastewater.

CHEMOSPHERE (2023)

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Review Engineering, Environmental

Algal mediated intervention for the retrieval of emerging pollutants from aqueous media

Alok Kumar et al.

Summary: Water is essential for all sectors, with agriculture accounting for 70% of its use globally. Human activities from various industries have led to the release of contaminants into water systems, causing harm to the ecosystem and organisms. Algae-based methods, including biosorption, bioaccumulation, biotransformation, and biodegradation, show potential in efficiently removing organic pollutants. This paper provides detailed information on these processes, along with the genetic alteration of algal biomass, highlighting the advantages of genetic engineering and mutations for enhanced removal efficiency without secondary toxicity.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Agricultural Engineering

One-pot preparation of layered double oxides-engineered biochar for the sustained removal of tetracycline in water

Jiayi Tang et al.

Summary: In this study, a new composite adsorbent (BC-MA) was developed by impregnating bio-waste bagasse with magnesium-aluminum layered double oxides for the removal of tetracycline (TC). BC-MA exhibited a high adsorption capacity of 250.6 mg g(-1) due to its developed porous structure, large surface area, and reinforced functional groups. BC-MA showed excellent adsorption capacity in diverse water environments and sustainable regeneration ability. The adsorption process of TC by BC-MA was spontaneous and endothermic, and intraparticle diffusion was the rate-limiting stage. The proposed mechanisms involved pi-pi interactions, pore filling, complexation, and hydrogen bonding. These findings suggest that the synthesis of modified biochar from bagasse offers new opportunities for waste resource reuse and water pollution control.

BIORESOURCE TECHNOLOGY (2023)

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Article Environmental Sciences

Laboratory Studies into Tetracycline Removal from Aqueous Solutions by Beads of Calcium-Iron Oxide Nanoparticles

Layla Abdulkareem Mokif et al.

Summary: Calcium extraction from chicken bone wastes was utilized for preparing a novel sorbent for tetracycline removal. The sorbent was formed by immobilizing calcium-iron oxide nanoparticles as sodium alginate beads. Batch testing showed a removal efficiency greater than 95%, with ideal conditions including a contact time of 3 h, beads mass of one gram per 50 mL, and pH value of 7 for the stock solution. The permeable reactive barrier can effectively control pollutant migration, with the barrier longevity increasing with thicker beds for low inlet concentrations and water flow rates. The Thomas-BDST expression provided the best model for simulating the continuous experiments.

WATER AIR AND SOIL POLLUTION (2023)

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Article Environmental Sciences

Mg-Fe-LDH for Aquatic Selenium Treatment: Adsorption, RSM Modeling, and Machine Learning Neural Network

Ahmed I. A. Ibrahim et al.

Summary: This study investigated the removal efficiency of aqueous selenite, selenate, and selenocyanate species using Mg-Fe-LDH nanomaterial adsorbent. The experimental results showed higher removal for selenite and selenate species compared to selenocyanate species. The modeling results demonstrated that the BPANN method exhibited higher accuracy in predicting selenium species removal compared to the RSM technique.

WATER AIR AND SOIL POLLUTION (2023)

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Review Physics, Applied

Sludge-derived biochar: Physicochemical characteristics for environmental remediation

Neelaambhigai Mayilswamy et al.

Summary: It is predicted that the global production of fecal wastes will reach a very high level by 2030. Handling and exposure to human and animal fecal matter are closely linked to various health issues, and sludge treatment accounts for a significant portion of operational expenditure. Carbonization of sludges to generate biochar adsorbents or catalysts can reduce sludge processing costs and provide effective solutions for contaminant removal.

APPLIED PHYSICS REVIEWS (2023)

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Review Engineering, Environmental

Functionalized polymeric architectures (FPAs) for uranium recovery from oceans: A review on adsorptive approaches, models and spectrophotometry for understanding the interaction mechanism

Amrita Nighojkar et al.

Summary: Uranium, the prime source of nuclear power production, can be extracted from seawater using functionalized polymeric architectures (FPAs). This review analyzes the uranium extraction ability and binding mechanisms of FPAs in real and artificial seawater matrix. The study demonstrates the efficacy of FPAs in sequestering uranium from seawater and highlights the need for further research on complex uranium adsorption behavior in dynamic conditions.

JOURNAL OF HAZARDOUS MATERIALS ADVANCES (2023)

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Review Environmental Sciences

A review on algal biosorbents for heavy metal remediation with different adsorption isotherm models

Alok Kumar et al.

Summary: Biosorbent composites derived from biotic species can be used for the exclusion of toxicants from various sources. The use of composites increases adsorption capacity, as demonstrated by higher levels of copper and nickel adsorption. Algae-based biosorbents have also shown potential for efficient removal of heavy metals. This article provides detailed information on heavy metals, biosorbents, estimation techniques, removal methods, and health effects. It also highlights the importance of biosorbent recovery and reuse in line with sustainable development goals.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

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Article Engineering, Environmental

Insights into the adsorption of pharmaceuticals and personal care products (PPCPs) on biochar and activated carbon with the aid of machine learning

Xinzhe Zhu et al.

Summary: This study utilized machine learning to build adsorption prediction models for biochar's capability in removing recalcitrant organic contaminants (PPCPs), demonstrating that detailed biochar properties obtained from advanced techniques contribute to more accurate predictions. Surface carbon functionalities and pore diameter of adsorbents play crucial roles in predicting the adsorption capacity of PPCPs.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Review Engineering, Environmental

Application of MXenes for water treatment and energy-efficient desalination: A review

Fuhar Dixit et al.

Summary: MXenes are a new type of 2D material gaining attention for their use in environmental, chemical, and medical applications. They exhibit high performance and efficiency in water treatment, wastewater treatment, and desalination applications, outperforming conventional materials in various fields.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Review Environmental Sciences

Impact, disease outbreak and the eco-hazards associated with pharmaceutical residues: a Critical review

A. H. Khan et al.

Summary: Pharmaceutical residues pose a threat to public health and ecological balance, requiring dedicated treatment at the source. These residues have the potential to cause disease outbreaks and eco-toxicological impacts on aquatic organisms.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2022)

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Review Environmental Sciences

Adsorptive Removal of Endocrine-Disrupting Chemicals from Aqueous Solutions: a Review

Kayode Adesina Adegoke et al.

Summary: Endocrine-disrupting chemicals (EDCs) are pollutants that have adverse effects on water quality even at low concentrations. These pollutants enter the human system through contaminated air, water, and food, and can disrupt the endocrine systems of humans and wildlife. To improve water quality and protect the ecosystem, it is important to develop effective and cost-efficient removal techniques for EDCs.

WATER AIR AND SOIL POLLUTION (2022)

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Article Environmental Sciences

Application of machine learning in predicting the adsorption capacity of organic compounds onto biochar and resin

Ying Zhao et al.

Summary: In this study, the Kriging and polyparameter linear free energy relationship model were used to predict the adsorption capacity of organic pollutants by biochar and resin. The results showed that the Kriging-LFER model had better accuracy and predictive performance compared to the published NN-LFER model. Local sensitivity analysis and uncertainty analysis methods were also applied to evaluate the influence of variables and analyze data uncertainty. The study highlights the significance of the Kriging-LFER model in understanding parameter importance, reducing experimental efforts, and evaluating pollutant fate.

ENVIRONMENTAL RESEARCH (2022)

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Article Engineering, Environmental

Nano-fluoro dispersion functionalized superhydrophobic degummed & waste silk fabric for sustained recovery of petroleum oils & organic solvents from wastewater

Prakash M. Gore et al.

Summary: In this study, superwettable and chemically stable waste silk fabric and degummed silk were used for treatment of oily wastewater and oil/solvent recovery. The silk functionalized with a nano-fluoro dispersion showed superhydrophobic and oleophilic properties, demonstrating high filtration efficiencies and permeation flux for oil-water separation. The functionalized silk also exhibited excellent stability in acidic and alkaline mediums, along with thermal stability. The results indicate that nano-fluoro dispersion functionalized silk can be successfully employed for effective oil/solvent-water filtration and treatment of oily wastewater.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Green & Sustainable Science & Technology

Fabrication of Biochar Materials from Biowaste Coffee Grounds and Assessment of Its Adsorbent Efficiency for Remediation of Water-Soluble Pharmaceuticals

Vuyokazi Zungu et al.

Summary: This study successfully produced biochar from biowaste coffee grounds through pyrolysis and found that it has a strong adsorption capacity for pharmaceuticals in water. These results indicate that biochar can serve as an effective adsorbent to enhance the removal of emerging contaminants from wastewater.

SUSTAINABILITY (2022)

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Article Chemistry, Multidisciplinary

Experimental design, machine learning approaches for the optimization and modeling of caffeine adsorption

N. Taoufik et al.

Summary: This study comparatively investigated the sorption of caffeine on fresh and calcined Cu-Al layered double hydroxide, developing reliable models through data mining methods. Various characterization techniques were used to analyze the characteristics of HDL, revealing its structural and functional features. The proposed machine learning models proved to be reliable computer methods for monitoring and simulating the adsorption of pollutants by Cu-Al-LDH from aqueous solutions.

MATERIALS TODAY CHEMISTRY (2022)

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Article Environmental Sciences

Machine learning-assisted evaluation of potential biochars for pharmaceutical removal from water

Xiaocui Yang et al.

Summary: A data-driven machine learning tool was developed to predict the max adsorption capacity of pharmaceutical compounds on biochars, and K-nearest neighbors (KNN) was found to be the most optimal algorithm. Modified biochars can enhance adsorption capacity and surface area values.

ENVIRONMENTAL RESEARCH (2022)

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Article Environmental Sciences

Adsorption of Zn(II) on Pristine and SPLP/TCLP Leached Rice Straw Biochar: an Interplay of Precipitation and Ion Exchange

Akanksha Bhardwaj et al.

Summary: The inorganic mineral content in biochar affects the adsorption of Zn(II) metal ions. Washing has an influence on the metal ion adsorption of mineral rich rice straw biochar. The adsorption of Zn(II) by different biochars is influenced by pH, dose, and leaching extent.

WATER AIR AND SOIL POLLUTION (2022)

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Article Environmental Sciences

Cladophora Algae Modified with CuO Nanoparticles for Tetracycline Removal from Aqueous Solutions

Mohammed Sadeq Salman et al.

Summary: In this study, modified algae with nano copper oxide were used as adsorption media to remove tetracycline from aqueous solutions. The optimum condition for removal was found to be at pH 7, a contact time of 240 min, a dosage of 5 g/L, an initial concentration of 25 mg/L, and a temperature of 45 degrees C. Thermodynamic and kinetic models indicated that the adsorption process was endothermic and followed a second-order kinetic model. The Langmuir model fitted the study well, suggesting homogeneous adsorption sites. Based on the experimental results and removal efficiency, the modified algae with nano copper oxide biomass was suitable for tetracycline removal.

WATER AIR AND SOIL POLLUTION (2022)

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Article Biotechnology & Applied Microbiology

Removal of Tetracycline from aqueous solution using composite adsorbent of ZnAl layered double hydroxide and bagasse biochar

Le Phuong Hoang et al.

Summary: In this study, a composite adsorbent of biochar derived from bagasse and ZnAl-layered double hydroxide was synthesized by the in-situ growth method. The adsorbent exhibited good adsorption performance for tetracycline, with a maximum adsorption capacity of 41.98 mg/g. The prepared biochar and composite adsorbent were characterized and their adsorption properties were investigated.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2022)

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Article Engineering, Environmental

Efficient adsorptive removal of ciprofloxacin and carbamazepine using modified pinewood biochar-A kinetic, mechanistic study

Yongtao Xue et al.

Summary: This study utilized modified biochar for the immobilization of CuO to efficiently adsorb and degrade pharmaceutical compounds in polluted waters. The modified biochar exhibited a larger surface area and more functional groups, which facilitated the adsorption and degradation reactions. Response surface methodology was used to study the effects of different operating parameters on the degradation efficiency. This research provides valuable insights into the fabrication and application of sustainable and green materials for the removal of emerging wastewater contaminants.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Engineering, Environmental

Biochar production techniques utilizing biomass waste-derived materials and environmental applications-A review

Farah Amalina et al.

Summary: This article comprehensively evaluates and presents the preparation, properties, and environmental applications of biochar. The type of biomass and process parameters influence the production and properties of biochar. Biochar finds wide applications in soil remediation, carbon sequestration, waste composting, water and wastewater treatment, among others.

JOURNAL OF HAZARDOUS MATERIALS ADVANCES (2022)

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Review Polymer Science

Engineering properties of Teflon derived blends and composites: a review

Sarang S. Shindalkar et al.

Summary: This review focuses on the tribological performance of polytetrafluoroethylene (PTFE, commonly known as Teflon) derived blends and composites at different grades, and details the optimized casting process and rational design principles. The desired wear rate and excellent thermal conductivity of actual Teflon components are demonstrated through bird's eye view, and the engineering properties of Teflon for future prospects and applications as emerging high-performance thermoplastics are revealed.

POLYMER-PLASTICS TECHNOLOGY AND MATERIALS (2022)

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Article Engineering, Environmental

Continuous adsorption studies of pharmaceuticals in multicomponent mixtures by agroforestry biochar

Anton Puga et al.

Summary: This study investigated the adsorption of a multicomponent mixture of active pharmaceutical compounds using a biochar fixed-bed column. The research found that eucalyptus biochar was the most effective option for removing the pollutants. The study also revealed the adsorption mechanism and its correlation with the chosen biochars. Additionally, the multicomponent system showed synergistic behavior for one compound and antagonist behavior for the other two.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Environmental Sciences

Impacts of temperatures and phosphoric-acid modification to the physicochemical properties of biochar for excellent sulfadiazine adsorption

Xue-Yu Zeng et al.

Summary: This study investigated the properties of phosphoric acid-modified biochars (PABCs) prepared at different pyrolysis temperatures. PABCs prepared at higher temperatures had a higher proportion of micropores and showed improved adsorption capacity and rate for sulfadiazine (SDZ). The enhancement in adsorption was attributed to the confinement effect of hydrophobic cavities from the microporous structure and the pi-pi electron-donor-acceptor interaction. PABCs exhibited stable adsorption capacities at a wide pH range or high concentrations of coexisting ions.

BIOCHAR (2022)

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Article Engineering, Environmental

Application of data-driven machine learning to predict propranolol and trimethoprim removal using a managed aquifer recharge system

Muhammad Yaqub et al.

Summary: Experimental and data-driven modeling techniques, including multilayer perceptron and gene expression programming, were used to predict the removal of pharmaceutical products from reclaimed water through a managed aquifer recharge system. The gene expression programming models showed higher accuracy than the multilayer perceptron models, indicating their potential for better predictions and mathematical relationships in future studies. Data-driven machine learning models can effectively predict pharmaceutical product removal and reduce experimental workload.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Environmental Sciences

Prediction of Polycyclic Aromatic Hydrocarbons (PAHs) Removal from Wastewater Treatment Sludge Using Machine Learning Methods

Burcu Caglar Gencosman et al.

Summary: This study focused on predicting the removal efficiency of PAHs from wastewater treatment sludges using machine learning methods. Various classification and machine learning methods were proposed, with RF and k-NN showing the best performance with high prediction accuracies. RF outperformed other methods in predicting removal efficiencies on multi-class imbalanced datasets, providing cost-effective and efficient prediction results.

WATER AIR AND SOIL POLLUTION (2021)

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Article Engineering, Environmental

Forecasting the multicomponent adsorption of nimesulide and paracetamol through artificial neural network

P. S. Pauletto et al.

Summary: This study evaluated the adsorption of nimesulide and paracetamol on activated carbon using artificial neural network (ANN) models. Results showed that nimesulide had a higher affinity for the active sites of the AC compared to paracetamol, and in binary adsorption, nimesulide molecules competed with paracetamol molecules for adsorption sites. The optimal ANN model successfully predicted the adsorption of both nimesulide and paracetamol.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Three-dimensional mass transport modeling of pharmaceuticals adsorption inside ZnAl/biochar composite

Jaime Moreno-Perez et al.

Summary: The 3D-PVSDM model was used to predict adsorption of acetaminophen, ketoprofen, and ibuprofen in a ZnAl/biochar composite, showing that surface diffusion flux was the primary transport mechanism. Therefore, pore volume diffusion could be neglected, and a simplified 3D-SDM model could accurately simulate the mass transport.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

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Article Engineering, Environmental

Forecasting effluent and performance of wastewater treatment plant using different machine learning techniques

Mustafa El-Rawy et al.

Summary: This study introduces two methods for predicting and forecasting the removal efficiency of pollutants in wastewater treatment plants: traditional feed-forward, deep feed-forward backpropagation, and deep cascade-forward backpropagation networks; and deep learning time series forecasting with a long short-term memory network. The results show that the DCB network has the highest accuracy and is recommended for evaluating and predicting WWTP performance.

JOURNAL OF WATER PROCESS ENGINEERING (2021)

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Article Engineering, Environmental

Enhanced norfloxacin degradation by iron and nitrogen co-doped biochar: Revealing the radical and nonradical co-dominant mechanism of persulfate activation

Mufan Xi et al.

Summary: The study introduced a novel method using iron and nitrogen co-doped biochar material for the removal of antibiotics in water, showing significant degradation efficiency. Under optimal conditions, rapid degradation of antibiotics was achieved with potential for sustainable reuse through multiple cycles.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Environmental Sciences

Application of adsorption process for effective removal of emerging contaminants from water and wastewater

B. Senthil Rathi et al.

Summary: Emerging pollutants in the marine ecosystem are becoming a growing concern, as traditional wastewater treatment plants are not able to completely remove these contaminants, leading to the need for cost-effective additional water treatment methods. Adsorption is a successful method for contaminant removal globally, due to its low cost, high performance, and simple design.

ENVIRONMENTAL POLLUTION (2021)

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Article Engineering, Environmental

Use of a large dataset to develop new models for estimating the sorption of active pharmaceutical ingredients in soils and sediments

Jun Li et al.

Summary: The study investigated the sorption behavior of APIs in soils and sediments and developed new models using machine learning methods to estimate sorption coefficients. The random forest-based model performed best, accurately predicting sorption coefficients and aiding in assessing the sorption behavior of untested molecules and landscape-level risk assessments.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Review Environmental Sciences

Review of organic and inorganic pollutants removal by biochar and biochar-based composites

Liping Liang et al.

Summary: This article reviewed the application of biochar (BC) and BC-based composite materials in water treatment, including preparation methods, properties, pollutant removal efficiency, and adsorption mechanisms. BC and BC-based composite materials show good performance in removing inorganic and organic pollutants, but also face potential risks such as stability and biological toxicity.

BIOCHAR (2021)

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Article Environmental Sciences

Removal of sodium diclofenac from aqueous solutions by rice hull biochar

Judilyn Q. Filipinas et al.

Summary: This study successfully removed sodium diclofenac from aqueous solutions using rice hull biochar as an adsorbent, and identified factors affecting the removal efficiency. The Langmuir isotherm best fitted the experimental data, and the pseudo second-order model showed high correlation coefficients.

BIOCHAR (2021)

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Article Environmental Sciences

Adsorption of pharmaceuticals from aqueous solutions using biochar derived from cotton gin waste and guayule bagasse

Marlene C. Ndoun et al.

Summary: Biochars produced from cotton gin waste and guayule bagasse were characterized and explored as effective adsorbents for pharmaceutical removal from water. The adsorption mechanism involved hydrophobic partitioning, hydrogen bonding, and electron donor-acceptor interactions, with pH and specific surface area of biochar playing significant roles in adsorption efficiency. Adsorption of pharmaceutical compounds was found to be influenced by pH and contact time, indicating the potential of biochars for successful water treatment.

BIOCHAR (2021)

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Article Engineering, Chemical

Chemical modification of a polysaccharide from Artemisia vulgaris engenders a supersorbent for the removal of Cd2+ from spiked high-hardness groundwater

Muhammad Farid-ul-Haq et al.

Summary: The research on developing novel and chemically modified-natural materials for uptake of toxic heavy metal ions from aqueous environment is currently a hot topic. Mucilage from Artemisia vulgaris seeds were chemically modified and found to have a high sorption capacity for Cd2+ ions. Experimental data suggested that the sorption process is feasible, spontaneous, and exothermic.

DESALINATION AND WATER TREATMENT (2021)

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Review Chemistry, Applied

Ecotoxicity, Occurrence, and Removal of Pharmaceuticals and Illicit Drugs from Aquatic Systems

Harsh Mohan et al.

Summary: The pollutants from legal pharmaceuticals and illicit drugs are causing adverse effects on the environment, and have become a concern due to their toxicity and lack of biodegradability. Recent studies have confirmed the presence of these residues in drinking water, surface water, and groundwater, with wastewater treatment plants considered hotspots for pharmaceutical residue removal.

BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY (2021)

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Article Agricultural Engineering

ZnCl2 modified biochar derived from aerobic granular sludge for developed microporosity and enhanced adsorption to tetracycline

Lilong Yan et al.

BIORESOURCE TECHNOLOGY (2020)

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Review Environmental Sciences

Catalytic ozonation for water and wastewater treatment: Recent advances and perspective

Jianlong Wang et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Article Engineering, Environmental

Oxidative degradation of tetracycline using persulfate activated by N and Cu codoped biochar

Quanfa Zhong et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Review Environmental Sciences

Progressive trends in heavy metal ions and dyes adsorption using silk fibroin composites

Shivani Rastogi et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2020)

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Article Engineering, Environmental

Innovative spherical biochar for pharmaceutical removal from water: Insight into adsorption mechanism

Hai Nguyen Tran et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Engineering, Environmental

Photocatalytic degradation of gemifloxacin antibiotic using Zn-Co-LDH@biochar nanocomposite

Peyman Gholami et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Environmental Sciences

Fabrication of sustainable manganese ferrite modified biochar from vinasse for enhanced adsorption of fluoroquinolone antibiotics: Effects and mechanisms

Yujia Xiang et al.

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