4.7 Review

Recent advances on graphene and graphene oxide as extraction materials in solid-phase (micro)extraction

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Polyoxometalate/reduced graphene oxide composite stabilized on the inner wall of a stainless steel tube as a sorbent for solid-phase microextraction of some parabens followed by quantification via high-performance liquid chromatography

Marziyeh Kavian et al.

Summary: An affordable high-throughput microextraction strategy using poly-oxometalate/reduced graphene oxide (POM/rGO) composite was developed for the extraction of parabens from real samples. The method showed high extraction efficiency due to the uniform stabilization of POMs on rGO and the hydrophobic interactions between rGO and the target analytes. The method was validated and applied successfully for the analysis of parabens in cosmetic products without interference.

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Ultrasound-assisted one-step reduction and self-assembly of carbon dots-reduced graphene oxide: Mechanism investigation and solid phase microextraction of ultra-trace organochlorine pesticides

Shengrui Xu et al.

Summary: In this study, a carbon dots-reduction graphene oxide (CDs/RGO) composite was synthesized and utilized for the extraction and determination of ultra-trace organochlorine pesticides (OCPs). The CDs/RGO composite exhibited excellent morphology and chemical structures, and showed superior extraction capacities for OCPs. The proposed analytical method demonstrated high sensitivity and good linearity, enabling successful determination of ultra-trace OCPs in water samples.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Analytical

Efficient solid phase microextraction of organic pollutants based on graphene oxide/chitosan aerogel

Sheng Peng et al.

Summary: A novel stable chitosan cross-linked graphene oxide aerogel was reported as a coating for solid phase microextraction, showing high extraction performance towards hydrophobic pollutants and superior analytical capabilities for PAHs, with potential for wide application.

ANALYTICA CHIMICA ACTA (2022)

Article Chemistry, Analytical

GNP/Al-MOF nanocomposite as an efficient fiber coating of headspace solid-phase micro-extraction for the determination of organophosphorus pesticides in food samples

Ali Khodayari et al.

Summary: This study reports the synthesis and utilization of a high porous nanocomposite consisting of MIL-53(Al) metal-organic framework and graphene nanopowder as a fiber coating for headspace solid-phase micro-extraction of organophosphorus pesticides. The fabricated fiber showed good repeatability and enrichment factor under optimal conditions, making it suitable for micro-extraction of other pesticides.

MICROCHIMICA ACTA (2022)

Review Chemistry, Analytical

Development of aerogels in solid-phase extraction and microextraction

Min Sun et al.

Summary: Sample pretreatment is a crucial step in analyzing and detecting trace targets, and aerogels have shown great potential as extraction materials in sample preparation. This review provides a comprehensive overview of the classification, development, and application of aerogels in solid-phase extraction and solid-phase microextraction from 2010 to 2021. Different types of aerogels, including silica, carbon, organic, organic-inorganic hybridized, and metal-oxide aerogels, have been introduced in these techniques. They have demonstrated excellent adsorption performance and the ability to capture various analytes in environmental, biological, and food samples. The challenges and future prospects for the use of aerogels in sample preparation are also discussed.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2022)

Article Biochemical Research Methods

Determination of Organophosphorus Pesticides Using Solid-Phase Extraction Followed by Gas Chromatography-Mass Spectrometry

Peng Sun et al.

Summary: A method using graphene aerogel solid-phase extraction combined with gas chromatography-mass spectrometry was developed for determination of three organophosphorus pesticides. The method showed good linearity and accuracy in the analysis of target analytes.

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A magnetic solid phase extraction based on UiO-67@GO@Fe3O4 coupled with UPLC-MS/MS for the determination of nitroimidazoles and benzimidazoles in honey

Yan Xu et al.

Summary: A novel composite material was fabricated and utilized for simultaneous determination of nitroimidazoles and benzimidazoles in honey, achieving efficient analysis separation through optimized graphite oxide amount and analysis parameters. The method, characterized by its simplicity, speed, and environmental friendliness, can be used for detecting multiple compounds.

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Article Biochemical Research Methods

Headspace solid-phase-microextraction using a graphene aerogel for gas chromatography-tandem mass spectrometry quantification of polychlorinated naphthalenes in shrimp

Xinrui Wang et al.

Summary: A headspace solid-phase microextraction (HS-SPME) method combined with gas chromatography-tandem mass spectrometry was developed and validated for the analysis of polychlorinated naphthalenes (PCNs) in shrimp. The method utilized a graphene aerogel as the SPME fiber coating, which exhibited good performance in terms of sorption/desorption for PCNs. The optimized method showed excellent linearity, low limits of detection, and satisfactory recoveries. Compared with previous methods, this developed method is simpler, more sensitive, and environmentally friendly.

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Article Chemistry, Analytical

Semi-automated solid-phase extraction of polycyclic aromatic hydrocarbons based on stainless steel meshes coated with metal-organic framework/graphene oxide

Abbas Abdar et al.

Summary: In this study, a Cu-based metal-organic framework/graphene oxide (Cu-MOF/GO) nanocomposite was coated on a stainless steel mesh (SSM) to create a sorbent for the semi-automated solid-phase extraction (SPE) of polycyclic aromatic hydrocarbons (PAHs) from water samples. The extracted PAHs were then analyzed using gas chromatography-flame ionization detection (GC-FID). The optimized method demonstrated good linearity, low limits of detection, and quantification, and was successfully applied to real water samples with high accuracy and reproducibility.

MICROCHEMICAL JOURNAL (2022)

Review Chemistry, Analytical

Preparation of ionic covalent organic frameworks and their applications in solid-phase extraction

Mingxia Sun et al.

Summary: Ionic covalent organic frameworks (iCOFs) possess dual properties of COFs and ions, and have various excellent properties and potential applications. This paper reviews the preparation methods of iCOFs, their applications in solid-phase extraction, and discusses the extraction mechanisms. Task-specific iCOFs can be developed through the design and synthesis of ionic monomers or post-modification.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2022)

Article Chemistry, Analytical

Facile one-step synthesis of graphene oxide/polyhedral oligomeric silsesquioxane composite-coated fiber for high-efficiency solid-phase microextraction of polycyclic musks

Shuangchen Jiang et al.

Summary: Efficient synthesis strategy was developed to fabricate high-performance GO/POSS composite-coated fiber via ultra-fast UV polymerization, which exhibited superior extraction performance for PCMs in comparison to commercial fibers and other fibers.

ANALYTICA CHIMICA ACTA (2022)

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Environmental health and risk assessment metrics with special mention to biotransfer, bioaccumulation and biomagnification of environmental pollutants

Rishikesh Chormare et al.

Summary: This comprehensive review discusses the sources, toxicity, impact, and fate of different environmental pollutants, as well as the tools and models used to assess their risks to the environment and human health.

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Preparation and application of graphene oxide functionalized melamine-formaldehyde aerogel coated solid-phase microextraction tube

Sun Min et al.

Summary: GO/MF aerogels are promising due to the enhanced extraction efficiency of MF aerogels towards PAHs, achieved through increased adsorption sites and pi-pi interaction with PAHs.

CHINESE JOURNAL OF CHROMATOGRAPHY (2022)

Article Chemistry, Analytical

Determination of organophosphorus pesticides based on graphene oxide aerogel solid phase extraction column

Hou Xiudan et al.

Summary: A graphene oxide aerogel was successfully synthesized and applied for the extraction of residual organophosphorus pesticides in food. The optimal conditions for extraction efficiency were investigated, leading to improved recovery rates. The developed method showed promising results for the detection of organophosphorus pesticides in real samples.

CHINESE JOURNAL OF CHROMATOGRAPHY (2022)

Article Chemistry, Analytical

Covalent organic framework-graphene oxide composite: A superior adsorption material for solid phase microextraction of bisphenol A

Wei Gao et al.

Summary: Novel COF-GO composite materials were synthesized and tested for ultra-trace level SPME of BPA. The extraction efficiency of TpBD-GO-2 was significantly higher than TpBD and GO, leading to improved detection and quantification limits for BPA analysis.

TALANTA (2021)

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Electrochemically controlled solid phase microextraction based on a conductive polyaniline-graphene oxide nanocomposite for extraction of tetracyclines in milk and water

Hassan Sereshti et al.

Summary: A method using electrochemically controlled solid phase microextraction with a modified electrode was developed for the extraction of tetracycline antibiotics. The method proved to be a simple, fast, cost-effective, sensitive, and efficient procedure for extracting antibiotics in complex matrices.

JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE (2021)

Review Biochemical Research Methods

In-tube solid-phase microextraction: Current trends and future perspectives

Hiroyuki Kataoka

Summary: IT-SPME is an effective sample preparation technique using an open tubular capillary column as an extraction device, useful for micro-concentration, automated sample cleanup, and rapid online analysis. It is typically combined with high-performance liquid chromatography and utilizes online column switching technology for automated processing. Various improvements have been made to enhance extraction efficiency, and IT-SPME methods are widely used in environmental, food, and bioanalysis fields.

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Preparation and Application of β-Cyclodextrin Functionalised Graphene Oxide-Grafted Silica Sorbents for Solid-Phase Extraction (SPE) of Polycyclic Aromatic Hydrocarbons from Fried Food Using a Box-Behnken Design

Na Wang et al.

Summary: The new synthesized beta-CD@GO/SiO2 sorbent showed better extraction selectivity for PAHs in fried food extracts and satisfactory analysis results were obtained through optimization with RSM method.

FOOD ANALYTICAL METHODS (2021)

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Lipidomics phenotyping of clam (Corbicula fluminea) through graphene/ fibrous silica nanohybrids based solid-phase extraction and HILIC-MS analysis

Gongshuai Song et al.

Summary: The G/KCC-1 SPE and HILIC-MS method proved to be accurate and efficient in selectively extracting and phenotyping phospholipids in clam. The method showed good performance in terms of linearity, sensitivity, and precision.

FOOD CHEMISTRY (2021)

Article Chemistry, Analytical

Boron nitride modified reduced graphene oxide as solid-phase microextraction coating material for the extraction of seven polycyclic aromatic hydrocarbons from water and soil samples

Hongda Li et al.

Summary: A novel hexagonal boron nitride modified reduced graphene oxide material was synthesized for the solid-phase microextraction of polycyclic aromatic hydrocarbons from water and soil samples. The method showed good adsorption performance, linear response range, and relative recoveries for the analytes in both types of samples under optimal conditions.

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Porous material-based sorbent coatings in solid-phase microextraction technique: Recent trends and future perspectives

Karolina Delinska et al.

Summary: The use of porous materials as sorbents in sample preparation techniques, particularly in the development of novel fibers for Solid-phase microextraction (SPME), has recently attracted scientific attention. The selection of a robust sorbent is crucial for successful utilization of SPME under variable conditions. Understanding the nature of newly developed porous SPME coatings and the impact of their structures on analytical parameters is essential for their successful use as potential sorption media for specific purposes.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2021)

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Solid-Phase Microextraction of Phthalate Esters from Aqueous Media by Functionalized Carbon Nanotubes (Graphene Oxide Nanoribbons) and Determination by GC-FID

Maryam Kazemi et al.

Summary: Multiwalled carbon nanotubes were used to obtain graphene oxide nanoribbons (GONRs) through hydrothermal treatment, which were further characterized and used as sorbent phase for headspace solid-phase microextraction of phthalate esters (PEs). The newly fabricated GONR-coated SPME fiber showed excellent analytical performance in quantification of PEs with broad linear ranges, low detection limits, and good stability. The method demonstrated high extraction yield for PE analytes from aqueous solutions, suggesting its potential for precise and accurate evaluation and determination of PEs in environmental water samples.

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In-site and solvent-free exfoliation of porous graphene oxide from pencil lead fiber for solid-phase microextraction of cadmium ion before GF-AAS determination

Yuan Yang et al.

Summary: The graphene oxide-functionalized pencil lead fiber was prepared via one-step dielectric barrier discharge microplasma treatment, showing high efficiency and low cost for toxic metal ion extraction. The novel fiber with abundant oxygen-containing functional groups on the surface exhibited enhanced extraction efficiency and sensitivity for cadmium ions, with a detection limit of 0.005 ug/L. The SPME method had a sensitivity enhancement factor of 25 and demonstrated successful application in various water samples with spike recoveries from 94 to 105%.

MICROCHIMICA ACTA (2021)

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Yiyuan Zhou et al.

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Graphene oxide-functionalized mesoporous silica for online in-tube solid-phase microextraction of polycyclic aromatic hydrocarbons from honey and detection by high performance liquid chromatography-diode array detector

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