4.7 Article

Improvement of Ni-CFRP interfacial properties using compound coupling agent treatment

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THIN-WALLED STRUCTURES
卷 195, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.tws.2023.111334

关键词

CFRP/Ni joints; Interfacial properties; Surface treatment; Strengthening mechanism

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This study investigates the surface modification of a nickel plate to improve the bonding strength with carbon fiber-reinforced plastics (CFRP). The results show that different surface modification methods, including sandblasting, coupling agent treatment, and compound coupling agent treatment, significantly enhance the bonding strength of CFRP/Ni joints. The research provides insights into improving the connection between nickel and CFRP, as well as other heterogeneous materials.
When nickel and carbon fiber-reinforced plastics (CFRP) are combined, poor surface wettability of nickel makes it difficult to obtain ideal interfacial properties, which limits its extensive application in the aerospace field. In this paper, the surface of the nickel plate was modified by sandblasting, coupling agent treatment, and compound coupling agent treatment, the results showed that the bonding strength of CFRP/Ni joints was increased by 19.6 %, 30.2 %, and 49.7 %, respectively, compared with the untreated joint. From the aspects of microstructure, surface wetting, and chemical bonding, the mechanism of strengthening nickel and CFRP bonding with the above surface modification methods were researched. Sandblasting treatment could form irregular pits on the surface of the nickel plate. These irregular pits effectively improved the surface roughness of nickel plate, but had little effect on the surface wettability. Coupling agent treatment has little effect on the surface roughness of the nickel plate, but greatly improvement on wettability with grafting the coupling agent molecule. Compound coupling agent treatment introduces -OH and -NH2 groups through plasma treatment to improve the grafting rate of coupling agent molecules on the surface of the nickel plate, achieving the purpose of strengthening the bonding of CFRP/Ni. This research is expected to provide research ideas for the connection of Ni and CFRP and other heterogeneous materials.

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