4.7 Article

Effect of Si content on the oxidation behavior of CoCrWSi coatings at 900 °C

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SURFACE & COATINGS TECHNOLOGY
卷 467, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2023.129729

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CoCrWSi coatings; High-velocity oxygen fuel; Oxidation behavior; Si content; Internal oxidation

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CoCrWSi coatings with different Si contents were prepared and their high-temperature oxidation resistance at 900°C in air was studied. Characterization of oxide scales was done through microscopy and diffraction techniques. The results showed that the oxidation resistance of the coatings increased with increasing Si content, and the beneficial effects of Si content on oxidation resistance were explained in terms of Si depletion and prevention of outward diffusion of Cr atoms.
In this study, CoCrWSi coatings with different Si contents were prepared via high-velocity oxygen fuel spraying, and the effect of Si content on their high-temperature oxidation resistance in air was studied at 900 & DEG;C. The microstructures and chemical compositions of oxide scales were characterized through scanning electron mi-croscopy, electron probe microanalysis, and X-ray diffraction. The results revealed that the oxidation resistance of the produced CoCrWSi coatings gradually increased with increasing Si content. Moreover, the beneficial ef-fects of Si content on the oxidation resistance were discussed in terms of Si depletion. The addition of Si pre-vented the outward diffusion of Cr atoms, and inhibited internal oxidation, while the depth of internal oxidation varied significantly with the oxidation time.

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