期刊
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
卷 206, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.sab.2023.106725
关键词
Laser-induced breakdown spectroscopy; Plasma chemistry; Laser-ablation atomic absorption spectroscopy; Plume-gas interaction; Yttrium; Absorption spectroscopy; Plasma diagnostics
类别
The absolute atomized mass of a laser-induced yttrium plasma was measured under various noble and oxidizing cover gases using high resolution atomic-absorption spectroscopy mapping. The maximum spatial extent of the plasma decreased with the molar mass of the cover gas. Time-resolved masses measured under oxidizing atmospheres showed continuous net loss from the first measured delay. Plasmas under helium and argon atmospheres also exhibited net loss of atomized yttrium beyond 4 mu s, due to an unknown mechanism.
The absolute atomized mass of the neutral and first-ion reservoirs of a laser-induced yttrium plasma were measured with high resolution atomic-absorption spectroscopy mapping at various delays and under different noble and oxidizing cover gases. The maximum spatial extent of the plasma was inversely dependent on the molar mass of the cover gas. Time-resolved masses measured under oxidizing atmospheres showed continuous net loss from even the first measured delay (2 mu s). Though their total masses were stable at early delays, plasmas under helium and argon atmospheres also showed net loss of atomized yttrium from an unknown mechanism beyond 4 mu s. The measured total atomized masses during the early stable period under the noble atmospheres were approximately equal (similar to 30 ng) but higher than the masses measured under oxidizing atmospheres.
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