期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 316, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.seppur.2023.123846
关键词
Water pollution treatment; Enteromorpha prolifera biochar; CoFe2O4; Wide pH range; Peroxymonosulfate activation
In this study, a heterogeneous catalyst, CFO@EPBC, was developed and used for the degradation of lomefloxacin hydrochloride (LMH) by activating peroxymonosulfate (PMS). The CFO@EPBC showed remarkable catalytic ability with higher degradation rates compared to other catalysts, indicating synergistic interaction between EPBC and CoFe2O4. Moreover, CFO@EPBC demonstrated potential application for treating LMH in different types of water matrixes.
Heterogeneous catalysts with high-activity and wide pH tolerance are urgently needed for water pollutant degradation. In this work, CoFe2O4-loaded biochar prepared from the marine biomass Enteromorpha prolifera (CFO@EPBC) was successfully developed as an efficient heterogeneous catalyst for the degradation of lomefloxacin hydrochloride (LMH) by activating peroxymonosulfate (PMS). The crystalline structure, porous structure and surface chemistry of CFO@EPBC were characterized. The catalytic performance of CFO@EPBC activated PMS for the decomposition of LMH was estimated, and the reusability, stability and applicability of CFO@EPBC were also evaluated. The results showed that CFO@EPBC displayed 35.2-, 3.7- and 6.6-times degradation rates (kobs) towards LMH than that of EPBC, CoFe2O4 and EPBC + CoFe2O4, respectively, demonstrating remarkable synergistic interaction between EPBC and CoFe2O4. More importantly, excellent catalytic ability of the CFO@EPBC/PMS system for LMH degradation under a wide initial pH range (3-11) was observed due to a suitable pH(zpc) of catalysts. Also, CFO@EPBC showed a good application prospect for treating LMH in different types of water matrixes (river water and seawater). Reactive oxygen species (SO4-, center dot OH, center dot O-2(-) and O-1(2)) produced marked effects during the degradation process, while the radical process played a dominant role. This study also demonstrates a typical case for turning trash into treasure using Enteromorpha prolifera, providing a new idea for the value-added transformation of other similar bio-wastes.
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