☆ 4.3 Review

Inorganic hydrogels: synthetic strategies, properties and applications

REVIEWS IN INORGANIC CHEMISTRY (2023)

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Article Chemistry, Physical

Hydrogels totally from inorganic nanosheets and water with mechanical robustness, self-healing, controlled lubrication and anti-corrosion

Yi Yang et al.

Summary: This study successfully integrates mechanical strength and self-recovery into a colloidal hydrogel system of aluminium hydroxide nanosheets. The hydrogel exhibits excellent elasticity and stiffness, as well as high self-healing efficiency. It also demonstrates good lubrication and anti-corrosion properties.

NANO RESEARCH (2023)

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Article Chemistry, Physical

Surface-Modified Silica Hydrogels for the Programmable Release of Bisphosphonate Anti-Osteoporosis Drugs: The Case of Etidronate

Fanouria-Eirini G. Alatzoglou et al.

Summary: Bisphosphonate drugs are effective for treating bone diseases, but they have drawbacks such as rapid excretion and limited bioavailability. This study presents novel silica-based hydrogels loaded with the osteoporosis drug etidronate for controlled drug release. Various methods were evaluated to control the release rate and concentration, including gel density, metal cations, and surface functionalization. This research contributes to the development of programmable drug-loaded gels for controlled release of osteoporosis drugs.

MATERIALS (2023)

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Review Chemistry, Inorganic & Nuclear

Interpenetrating polymer network hydrogels for removal of synthetic dyes: A comprehensive review

Moslem Ahmadian et al.

Summary: The treatment of wastewater containing synthetic dyes is crucial due to their potential risks to the environment and public health. Adsorption process using interpenetrating polymer networks (IPNs) and semi-IPNs hydrogels as adsorbents have gained attention for their stability, high swelling capacity, non-toxicity, biocompatibility, and biodegradability. This review examines the removal of synthetic dyes from aqueous media using semi-IPNs and IPNs hydrogels, discussing their preparation, adsorption capacities, and future perspectives.

COORDINATION CHEMISTRY REVIEWS (2023)

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Article Chemistry, Multidisciplinary

Self-assembled three-dimensional hydrogels based on graphene derivatives and cerium oxide nanoparticles: scaffolds for co-culture of oligodendrocytes and neurons derived from neural stem cells

Yurena Polo et al.

Summary: Three-dimensional hydrogels based on graphene derivatives and cerium oxide nanoparticles have been developed as potential supports for neural stem cell adhesion, migration, and differentiation. The properties of the hydrogels can be controlled by adjusting the amount of reducing agent and CeO2 nanoparticles. The presence of CeO2 nanoparticles promotes the differentiation of neural stem cells into neuronal, astroglial, and oligodendroglial lineage cells, making these hydrogels suitable for neuroregenerative cell therapies.

NANOSCALE (2023)

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Article Chemistry, Multidisciplinary

Mineral Hydrogel from Inorganic Salts: Biocompatible Synthesis, All-in-One Charge Storage, and Possible Implications in the Origin of Life

Bo Li et al.

Summary: This study introduces a novel hydrogel synthesized from water and inorganic salts, offering high ionic conductivity and energy density. The gel is biocompatible and sheds light on prebiotic evolution.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Review Polymer Science

A review of etching methods of MXene and applications of MXene conductive hydrogels

Can Zhou et al.

Summary: This paper reviews the etching methods, synthesis strategies and applications of MXene, and provides an outlook on its future development.

EUROPEAN POLYMER JOURNAL (2022)

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Article Chemistry, Inorganic & Nuclear

Silica Hydrogels as a Basis of Novel Soft Dosage Forms and Cosmetic Compositions

E. S. Dolinina et al.

Summary: The study demonstrates that colloid silica hydrogels can serve as a platform for the development of novel soft formulations and cosmetic compositions for topical drug delivery, with controlled release of drugs to enhance antioxidant effects.

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY (2022)

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Review Polymer Science

Silica Hydrogels as Entrapment Material for Microalgae

Sarah Vanessa Homburg et al.

Summary: Despite the potential of microalgae as a feedstock for various industries, their production processes are currently uneconomical due to slow growth rates, expensive media, problematic downstream processes, and low cell densities. Entrapment via immobilization in silica hydrogels offers a promising solution to these challenges, allowing continuous processes with protection against shear forces and contaminations. Efforts have been made to improve biocompatibility and, through various methods, enable the proliferation of entrapped microalgae cells. This review provides an overview of entrapment methods in silica hydrogels, specifically for sensitive microalgae.

POLYMERS (2022)

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Article Materials Science, Multidisciplinary

Silica hydrogel composites as a platform for soft drug formulations and cosmetic compositions

Elena V. Parfenyuk et al.

Summary: Silica hydrogels have potential applications in the development of new soft drug formulations and cosmetic products. In this study, hydrogel drug-silica composites were synthesized under different synthesis conditions and their mechanical properties, thixotropic behavior, and drug release kinetics were investigated. The results showed that the synthesis conditions significantly influenced the properties of the hydrogels.

MATERIALS CHEMISTRY AND PHYSICS (2022)

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Article Pharmacology & Pharmacy

Silica Hydrogels as Platform for Delivery of Hyaluronic Acid

Elena Parfenyuk et al.

Pharmaceutics (2022)

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Article Pharmacology & Pharmacy

Fibrous Clays in Dermopharmaceutical and Cosmetic Applications: Traditional and Emerging Perspectives

Lihua Cao et al.

Summary: Functionalization of natural clay minerals for high value-added pharmaceutical and cosmetic applications is receiving global research attention. Fibrous clays have unique structural characteristics and are widely used in the dermopharmaceutical and cosmetic fields to develop novel skin delivery systems for enhanced health effects. This review summarizes the applications, structural characteristics, and mechanisms of fibrous clays in therapeutic and cosmetic fields.

INTERNATIONAL JOURNAL OF PHARMACEUTICS (2022)

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Review Chemistry, Physical

A Brief Review: The Use of L-Ascorbic Acid as a Green Reducing Agent of Graphene Oxide

Mariano Palomba et al.

Summary: The reduced form of graphene oxide (r-GO) is a versatile 2D material with properties similar to graphene, making it useful for various technological applications. Important considerations in producing r-GO include the degree of reduction, dispersion stability, and the use of environmentally friendly and inexpensive reducing agents. L-ascorbic acid (L-aa) has been found to be a suitable green reducing agent for converting GO to r-GO, achieving comparable results to hydrazine. This review summarizes the latest literature on the reduction of GO by L-aa, focusing on liquid-phase and gel-phase reduction approaches, as well as reaction mechanisms and experimental parameters.

MATERIALS (2022)

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Proceedings Paper Energy & Fuels

Thermal Stability of Silica for Application in Thermal Energy Storage

Patrick Davenport et al.

Summary: Silica sand, as a candidate thermal energy storage medium, demonstrates stability and high energy storage density. The limited changes observed after thermal treatment indicate its suitability for solid particle thermal energy storage applications.

SOLARPACES 2020 - 26TH INTERNATIONAL CONFERENCE ON CONCENTRATING SOLAR POWER AND CHEMICAL ENERGY SYSTEMS (2022)

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Article Chemistry, Applied

Exploiting mesoporous silica nanoparticles as versatile drug carriers for several routes of administration

Rafael Miguel Sabio et al.

Summary: The use of mesoporous silica nanoparticles as drug delivery systems has increased significantly, but there is a lack of research on the main exposure routes. Understanding these administration routes can help in developing smarter nanoplatforms with interesting properties.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Chemistry, Physical

A high-strength self-healing nano-silica hydrogel with anisotropic differential conductivity

Xingyu Huang et al.

Summary: A transparent nano-silica hydrogel with excellent mechanical strength, self-healing properties and conductivity was prepared in this study, which can be applied in the field of nano conductive materials.

NANO RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Controllable Patterning of Porous MXene (Ti3C2) by Metal-Assisted Electro-Gelation Method

Tingting Tu et al.

Summary: The metal-assisted electro-gelation method proposed by the authors enables the direct generation of porous-structured MXene hydrogels with tunable features. These high-performance hydrogels with complex architectures show promising applications in energy and biochemical sensing fields, making the method a prospective technique for advanced fabrication of MXene-based devices.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Polymer Science

Biomedical Application, Patent Repository, Clinical Trial and Regulatory Updates on Hydrogel: An Extensive Review

Sradhanjali Mohapatra et al.

Summary: Hydrogels play a crucial role in biomedical applications, offering flexibility with their physical, mechanical properties and biocompatibility. The water-loving nature and swelling capacity of hydrogels make them attractive for drug delivery applications, potentially solving various related issues.

GELS (2021)

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Article Chemistry, Applied

Optimized supercapacitive performance of graphene-hydrogel by porous texture controlling

Hong Yi Fu et al.

JOURNAL OF POROUS MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Robust and easily retrievable Pd/Ti3C2Tx⊂graphene hydrogels for efficient catalytic hydrogenation of nitroaromatic compounds

Xiuqiang Xie et al.

CHINESE CHEMICAL LETTERS (2020)

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Article Chemistry, Multidisciplinary

Highly Stable 3D Ti3C2Tx MXene-Based Foam Architectures toward High-Performance Terahertz Radiation Shielding

Zehui Lin et al.

ACS NANO (2020)

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Review Agriculture, Multidisciplinary

Natural biopolymer-based hydrogels for use in food and agriculture

Miri Klein et al.

JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE (2020)

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Review Pharmacology & Pharmacy

Hydrogel-Based Active Substance Release Systems for Cosmetology and Dermatology Application: A Review

Martyna Zagorska-Dziok et al.

PHARMACEUTICS (2020)

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Review Chemistry, Multidisciplinary

Recent Trends in Morphology-Controlled Synthesis and Application of Mesoporous Silica Nanoparticles

Nabanita Pal et al.

NANOMATERIALS (2020)

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Article Multidisciplinary Sciences

A mechanically adaptive hydrogel with a reconfigurable network consisting entirely of inorganic nanosheets and water

Koki Sano et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

Effect of sol-gel synthesis conditions on the physical properties of silica hydrogels

Ekaterina S. Dolinina et al.

MENDELEEV COMMUNICATIONS (2020)

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Article Polymer Science

Tetraethyl Orthosilicate-Based Hydrogels for Drug Delivery-Effects of Their Nanoparticulate Structure on Release Properties

Bogdan A. Serban et al.

GELS (2020)

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Review Chemistry, Physical

Functional biobased hydrogels for the removal of aqueous hazardous pollutants: current status, challenges, and future perspectives

Chirag Batukbhai Godiya et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Design and characterization of spring water hydrogels with natural inorganic excipients

Fatima Garcia-Villen et al.

APPLIED CLAY SCIENCE (2020)

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Review Materials Science, Multidisciplinary

Functional Conductive Hydrogels for Bioelectronics

Fanfan Fu et al.

ACS MATERIALS LETTERS (2020)

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Review Chemistry, Multidisciplinary

MXene hydrogels: fundamentals and applications

Yi-Zhou Zhang et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Processable dispersions of photocatalytically active nanosheets derived from titanium diboride: self assembly into hydrogels and paper-like macrostructures

Asha Liza James et al.

NANOSCALE (2020)

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Review Multidisciplinary Sciences

Commercial hydrogels for biomedical applications

S. H. Aswathy et al.

HELIYON (2020)

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Disturbance-Promoted Unconventional and Rapid Fabrication of Self-Healable Noble Metal Gels for (Photo-)Electrocatalysis

Ran Du et al.

MATTER (2020)

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Article Chemistry, Multidisciplinary

Fast Gelation of Ti3C2Tx MXene Initiated by Metal Ions

Yaqian Deng et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Ti3C2Tx-Based Three-Dimensional Hydrogel by a Graphene Oxide-Assisted Self-Convergence Process for Enhanced Photoredox Catalysis

Yan Chen et al.

ACS NANO (2019)

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Article Chemistry, Physical

Fast self-healing and rebuildable polyphosphate-based metallo-gels with mixed ionic-electronic conductivity

Euzebio Skovroinski et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Article Materials Science, Biomaterials

Evaluation of biomimetically synthesized mesoporous silica nanoparticles as drug carriers: Structure, wettability, degradation, biocompatibility and brain distribution

Heran Li et al.

MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS (2019)

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Review Chemistry, Physical

Carbon-based hydrogels: synthesis and their recent energy applications

Jayakumar Anjali et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Review Chemistry, Multidisciplinary

Conductive Hydrogels as Smart Materials for Flexible Electronic Devices

Qinfeng Rong et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Review Pharmacology & Pharmacy

Clay minerals: Properties and applications to dermocosmetic products and perspectives of natural raw materials for therapeutic purposes-A review

Jemima Daniela Dias Moraes et al.

INTERNATIONAL JOURNAL OF PHARMACEUTICS (2017)

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Article Chemistry, Physical

One-step synthesis of highly reduced graphene hydrogels for high power supercapacitor applications

Harish Banda et al.

JOURNAL OF POWER SOURCES (2017)

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Article Chemistry, Applied

Understanding the hydrothermal, thermal, mechanical and hydrolytic stability of mesoporous KIT-6: A comprehensive study

Rupak Kishor et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2017)

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Article Materials Science, Biomaterials

The physics and chemistry of silica-in-silicates nanocomposite hydrogels and their phycocompatibility

Nada Ben Ahmed et al.

JOURNAL OF MATERIALS CHEMISTRY B (2017)

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Smart, programmable and responsive injectable hydrogels for controlled release of cargo osteoporosis drugs

Konstantinos E. Papathanasiou et al.

SCIENTIFIC REPORTS (2017)

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Comprehensive study on graphene hydrogels and aerogels synthesis and their ability of gold nanoparticles adsorption

Izabela Kondratowicz et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2017)

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A Controlled Antibiotic Release System for the Development of Single-Application Otitis Externa Therapeutics

Bogdan A. Serban et al.

GELS (2017)

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Article Materials Science, Ceramics

Microstructure and transport properties of biocompatible silica hydrogels

Mercedes Perullini et al.

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY (2016)

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Reversible Assembly of Graphitic Carbon Nitride 3D Network for Highly Selective Dyes Absorption and Regeneration

Yuye Zhang et al.

ACS NANO (2016)

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Review Chemistry, Inorganic & Nuclear

Synthesis, functionalization, and applications of morphology-controllable silica-based nanostructures: A review

Bin Sun et al.

PROGRESS IN SOLID STATE CHEMISTRY (2016)

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Article Chemistry, Multidisciplinary

Investigation of the Antibacterial Effect of Mesoporous Magnesium Carbonate

Ken Welch et al.

ACS OMEGA (2016)

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Article Chemistry, Physical

Self-assembled three-dimensional graphene-based materials for dye adsorption and catalysis

Xueping Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Article Multidisciplinary Sciences

Enhanced transcription and translation in clay hydrogel and implications for early life evolution

Dayong Yang et al.

SCIENTIFIC REPORTS (2013)

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Article Chemistry, Physical

Three-dimensional graphene-based aerogels prepared by a self-assembly process and its excellent catalytic and absorbing performance

Tao Wu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Article Chemistry, Physical

Silicon alkoxide cross-linked silica nanoparticle gels for encapsulation of bacterial biocatalysts

Baris R. Mutlu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Article Chemistry, Physical

The performance of a silica-based mixed gel electrolyte in lead acid batteries

Ke Pan et al.

JOURNAL OF POWER SOURCES (2012)

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Article Chemistry, Physical

Preparation of Highly Conductive Graphene Hydrogels for Fabricating Supercapacitors with High Rate Capability

Li Zhang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2011)

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Article Chemistry, Physical

On the Gelation of Graphene Oxide

Hua Bai et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2011)

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Effect of synthesis conditions on the microstructure of TEOS derived silica hydrogels synthesized by the alcohol-free sol-gel route

Mercedes Perullini et al.

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY (2011)

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In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures

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NANOSCALE (2011)

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High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide

Sheng Kai-xuan et al.

NEW CARBON MATERIALS (2011)

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Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process

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ACS NANO (2010)

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Article Chemistry, Physical

Self-Assembly of Reduced Graphene Oxide into Three-Dimensional Architecture by Divalent Ion Linkage

Xu Jiang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

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Article Chemistry, Physical

Structural and rheological evolution of silica nanoparticle gels

X. J. Cao et al.

SOFT MATTER (2010)

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Article Chemistry, Multidisciplinary

Hydrogels and Aerogels from Noble Metal Nanoparticles

Nadja C. Bigall et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

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Article Chemistry, Physical

Cyanogel coordination polymers as precursors to transition metal alloys and intermetallics - from traditional heating to microwave processing

Martina Vondrova et al.

CHEMISTRY OF MATERIALS (2007)

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Review Chemistry, Multidisciplinary

Hydrous non-crystalline phosphates: Structure, function and a new white pigment

Renato Rosseto et al.

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY (2006)

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Ionic transport in aluminum polyphosphate hydrogels

Luiz G. Mendes et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2006)

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Advances in gelled-electrolyte technology for valve-regulated lead-acid batteries

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JOURNAL OF POWER SOURCES (2002)

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