期刊
MONATSHEFTE FUR CHEMIE
卷 147, 期 11, 页码 1951-1961出版社
SPRINGER WIEN
DOI: 10.1007/s00706-016-1699-5
关键词
1,2,3-Triazoles; Cu-Co/ZSM-5; Bimetallic nanocatalyst; Organosilicon; Click reaction; Ultrasonic irradiation
资金
- University of Tabriz
- Iranian Nanotechnology Initiative
A new efficient procedure for preparation of 1,2,3-triazole derivatives by 1,3-dipolar cycloaddition of benzyl halides, sodium azide, and propargyl alcohol over Cu-Co/ZSM-5 bimetallic nanocatalyst in aqueous media under conventional heating and ultrasonic irradiation was developed. The maximum activity of the catalyst was reported under ultrasonic irradiation with a noticeable reduction in the reaction time. The generated products were utilized as substrates for the synthesis of a series of new 1,2,3-triazole derivatives containing organosilylvinyl substituent and bulky organosilicon groups using (RSiMe2)(3)CLi (R = Me, Ph).
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