期刊
PETROLEUM CHEMISTRY
卷 63, 期 6, 页码 655-662出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544123040072
关键词
hydrogenation; furfural; mesoporous aluminosilicates; ruthenium; nickel
The paper investigates the performance of ruthenium and nickel catalysts supported on aluminum-modified SBA-15 mesoporous silicate in aqueous-phase furfural hydrogenation. Increasing the reaction temperature and hydrogen pressure enhances the selectivity towards methyltetrahydrofuran. The ruthenium catalyst shows higher activity than the nickel catalyst under 250°C and 5 MPa H2 conditions.
The paper describes synthesis of ruthenium and nickel catalysts supported on aluminum-modified SBA-15 (Santa Barbara Amorphous-15) mesoporous silicate, designated as Al-SBA-15, with a Si/Al ratio of 20. The catalysts were investigated in aqueous-phase hydrogenation of furfural, a valuable product obtained from lignocellulosic biomass. Elevating the reaction temperature from 200 to 250 & DEG;C and the hydrogen pressure from 3 to 5 MPa enhanced the selectivity towards methyltetrahydrofuran (MTHF). The ruthenium catalyst outperformed its nickel counterpart in terms of activity in aqueous-phase furfural hydrogenation (250 & DEG;C, 5 MPa H2).
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