期刊
ORGANIC LETTERS
卷 25, 期 43, 页码 7836-7840出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c03078
关键词
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Modular synthesis of novel biphen-[n]-arenes with customizable heterocycle blocks, functional skeletons, binding sites, and topological structures was achieved through rational design and replacement of reaction modules, functional modules, and linking modules. The properties were characterized by various techniques and thoroughly studied.
Modular synthesis of novel biphen-[n]-arenes (n = 2-4) with customizable heterocycle blocks, functional skeletons, binding sites, and topological structures could be facilely achieved through the rational design and replacement of reaction modules (furan and thiophene), functional modules (substituted benzene, biphenyl, and naphthalene), and linking modules (methylene). These biphen-[n]-arenes were characterized by NMR, HRMS, and X-ray crystalline diffraction, complemented by DFT calculations. Their photophysical properties were thoroughly studied.
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