期刊
ORGANIC LETTERS
卷 25, 期 28, 页码 5262-5267出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c01786
关键词
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The developed methodology demonstrates an efficient Rh(III)-catalyzed oxidative C-H/C-H cross-coupling reaction between acyclic enamides and heteroarenes. This reaction offers advantages of excellent regio- and stereoselectivity, good compatibility with various functional groups, and a broad range of substrates. Mechanistically, Rh(III)-catalyzed β-C(sp(2))-H activation of acyclic enamides is proposed as the crucial step.
The developed methodology describes an efficient Rh(III)-catalyzedoxidative C-H/C-H cross-coupling between acyclic enamidesand heteroarenes. This cross dehydrogenative coupling (CDC) reactionoffers advantages, including excellent regioselectivity and stereoselectivity,good functional group compatibility, and a broad substrate scope.Mechanistically, Rh(III)-catalyzed & beta;-C(sp(2))-H activation of acyclic enamides is proposed to be the criticalstep.
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