Site-Selective Nitration of Aryl Germanes at Room Temperature

We report a site-selective ipso-nitration of aryl germanes in the presence of boronic esters, silanes, halogens, and additional functionalities. The protocol is characterized by operational simplicity, proceeds at room temperature, and is enabled by [Ru(bpy)(3)](PF6)(2)/blue light photocatalysis. Owing to the exquisite robustness of the [Ge] functionality, nitrations of alternative functional handles in the presence of the germane are also feasible, as showcased herein.

Automated summary

A site-selective ipso-nitration of aryl germanes is reported, which can also nitrate alternative functional handles in the presence of the germane.