4.8 Article

12-inch growth of uniform MoS2 monolayer for integrated circuit manufacture

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NATURE MATERIALS
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NATURE PORTFOLIO
DOI: 10.1038/s41563-023-01671-5

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This study reports an improved chemical vapor deposition synthesis method for growing large-area high-quality 2D semiconductor films with fast and non-toxic growth, which has the potential to reduce manufacturing costs.
Two-dimensional (2D) semiconductors, such as transition metal dichalcogenides, provide an opportunity for beyond-silicon exploration. However, the lab to fab transition of 2D semiconductors is still in its preliminary stages, and it has been challenging to meet manufacturing standards of stability and repeatability. Thus, there is a natural eagerness to grow wafer-level, high-quality films with industrially acceptable scalecost-performance metrics. Here we report an improved chemical vapour deposition synthesis method in which the controlled release of precursors and substrates predeposited with amorphous Al2O3 ensure the uniform synthesis of monolayer MoS2 as large as 12 inches while also enabling fast and non-toxic growth to reduce manufacturing costs. Transistor arrays were fabricated to further confirm the high quality of the film and its integrated circuit application potential. This work achieves the co-optimization of scale-cost-performance metrics and lays the foundation for advancing the integration of 2D semiconductors in industry-standard pilot lines.

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