Boosting reversible charging of Li-ion batteries at low temperatures by a synergy of propylene carbonate-based electrolyte and defective graphite

[37] Kohs, W.; Santner, H. J.; Hofer, F.; Schr & ouml;ttner, H.; Doninger, J.; Barsukov, I.; Buqa, H.; Albering, J. H.; M & ouml;ller, K. C.; Besenhard, J. O. et al. A study on electrolyte interactions with graphite anodes exhibiting structures with various amounts of rhombohedral phase. J. Power Sources 2003 , 119-121 , 528-537. [38] Fan, H. M.; Liu, X. W.; Luo, L. B.; Zhong, F. P.; Cao, Y. L. All climate high-voltage commercial lithium-ion batteries based on propylene carbonate electrolytes. ACS Appl. Mater. Interfaces 2022 , 14 , 574-580. [39] Sun, H. COMPASS: An ab initio force-field optimized for condensed-phase applications-Overview with details on alkane and benzene compounds. J. Phys. Chem. B 1998 , 102 , 7338-7364. [40] Sun, H.; Ren, P.; Fried, J. R. The COMPASS force field: Parameterization and validation for phosphazenes. Comput. Theor. Polym. Sci. 1998 , 8 , 229-246. [41] Sun, H.; Jin, Z.; Yang, C. W.; Akkermans, R. L. C.; Robertson, S. H.; Spenley, N. A.; Miller, S.; Todd, S. M. COMPASS II: Extended coverage for polymer and drug-like molecule databases. J. Mol. Model. 2016 , 22 , 47. [42] Sodeyama, K.; Yamada, Y.; Aikawa, K.; Yamada, A.; Tateyama, Y. Sacrificial anion reduction mechanism for electrochemical stability improvement in highly concentrated Li-salt electrolyte. J. Phys. Chem. C 2014 , 118 , 14091-14097. [43] Xu, H.; Gao, J.; Jiang, D. L. Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts. Nat. Chem. 2015 , 7 , 905-912. Xu, H.; Tao, S. S.; Jiang, D. L. Proton conduction in crystalline and porous covalent organic frameworks. Nat. Mater. 2016 , 15 , 722-726. [44] [45] Jin, E. Q.; Asada, M.; Xu, Q.; Dalapati, S.; Addicoat, M. A.; Brady, M. A.; Xu, H.; Nakamura, T.; Heine, T.; Chen, Q. H. et al. Two

Automated summary

The article discusses the interactions between different structures of graphite anodes and electrolytes. The results show that the interaction between the electrolyte and graphite anode is influenced by the content of rhombohedral phase in the graphite.