4.6 Article

Biochar Production and Demineralization Characteristics of Food Waste for Fuel Conversion

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MOLECULES
卷 28, 期 16, 页码 -

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MDPI
DOI: 10.3390/molecules28166114

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food waste; pyrolysis; biochar; saltwater quality

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The pyrolysis of food waste has high economic potential, producing gas, bio-oil, and biochar. In South Korea, biochar production from food waste is prohibited due to dioxin generation caused by chloride ions from high salt content. This study evaluates the water quality and the use of food waste-based biochar as a solid refuse fuel. The results show that biochar can be efficiently generated while meeting emission standards for chloride ions, dissolved VOCs, ash, and carbon at 300 degrees C pyrolysis temperature.
The pyrolysis of food waste has high economic potential and produces several value-added products, such as gas, bio-oil, and biochar. In South Korea, biochar production from food waste is prohibited, because dioxins are generated during combustion caused by the chloride ions arising from the high salt content. This study is the first to examine the water quality and the applicability of food waste-based biochar as solid refuse fuel (SRF) based on a demineralization process. The calorific value increased after demineralization due to the removal of ionic substances and the high carbon content. The chloride ion removal rate after demineralization increased with the increasing pyrolysis temperature. A proximate analysis of biochar indicated that the volatile matter decreased, while ash and fixed carbon increased, with increasing pyrolysis temperature. At 300 degrees C pyrolysis temperature, all domestic bio-SRF standards were met. The organic matter concentration in water decreased with increasing carbonization temperature, and the concentrations of soluble harmful substances, such as volatile organic compounds (VOCs), were within the standards or non-detectable. These results suggest that biochar can be efficiently generated from food waste while meeting the emission standards for chloride ions, dissolved VOCs, ash, and carbon.

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