Catalytic Selective Oxidation of β-O-4 Bond in Phenethoxybenzene as a Lignin Model Using (TBA)5[PMo10V2O40] Nanocatalyst: Optimization of Operational Conditions

The catalytic oxidation of phenethoxybenzene as a lignin model compound with a beta-O-4 bond was conducted using the Keggin-type polyoxometalate nanocatalyst (TBA)(5)[PMo10V2O40]. The optimization of the process's operational conditions was carried out using response surface methodology. The statistically significant variables in the process were determined using a fractional factorial design. Based on this selection, a central circumscribed composite experimental design was used to maximize the phenethoxybenzene conversion, varying temperature, reaction time, and catalyst load. The optimal conditions that maximized the phenethoxybenzene conversion were 137 degrees C, 3.5 h, and 200 mg of catalyst. In addition, under the optimized conditions, the Kraft lignin catalytic depolymerization was carried out to validate the effectiveness of the process. The depolymerization degree was assessed by gel permeation chromatography from which a significant decrease in the molar mass distribution Mw from 7.34 kDa to 1.97 kDa and a reduction in the polydispersity index PDI from 6 to 3 were observed. Furthermore, the successful cleavage of the beta-O-4 bond in the Kraft lignin was verified by gas chromatography-mass spectrometry analysis of the reaction products. These results offer a sustainable alternative to efficiently converting lignin into valuable products.

Automated summary

The catalytic oxidation of a lignin model compound using a polyoxometalate nanocatalyst was optimized to achieve a high conversion rate. The optimized conditions allowed for the successful depolymerization of Kraft lignin, resulting in a decrease in molar mass distribution and polydispersity index, as well as the cleavage of the beta-O-4 bond. These findings offer a sustainable alternative for converting lignin into valuable products.