☆ 4.6 Review

Chemistry of Carbon-Substituted Derivatives of Cobalt Bis(dicarbollide)(1-) Ion and Recent Progress in Boron Substitution

MOLECULES (2023)

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Aqueous solubilization of hydrophobic compounds by inorganic nano-ions: An unconventional mechanism

Ioanna Chazapi et al.

Summary: The study found that COSANs act as efficient aqueous solubilizers of medium-chain alcohols in their monomeric state. Unlike surfactants, COSANs dissolve through a bi-dimensional anisotropic growth of COSAN/butanol co-assemblies. Additionally, COSANs/2-butanol co-assemblies can efficiently solubilize more hydrophobic compounds, offering new opportunities in many applied fields.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

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Article Chemistry, Multidisciplinary

Biomimetic Photodegradation of Glyphosate in Carborane-Functionalized Nanoconfined Spaces

Lei Gan et al.

Summary: The removal of organophosphorus (OP) herbicides from water has been studied using various methods such as adsorptive removal, chemical oxidation, electrooxidation, enzymatic degradation, and photodegradation. In this study, a Zr-based metal-organic framework (mCB-MOF-2) was used for the adsorption and photodegradation of the OP herbicide glyphosate (GP). The mCB-MOF-2 demonstrated a high adsorption capacity for GP and selectively converted it to non-toxic sarcosine and orthophosphate under UV-vis light irradiation. These findings suggest that mCB-MOF-2 is a promising material for removing OP herbicides from water.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

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Article Chemistry, Multidisciplinary

Metallacarborane Cluster Anions of the Cobalt Bisdicarbollide-Type as Chaotropic Carriers for Transmembrane and Intracellular Delivery of Cationic Peptides

Yao Chen et al.

Summary: Cobalt bisdicarbollides (COSANs) are used as selective and efficient molecular carriers to transport hydrophilic oligopeptides through membranes. They can permeate lipid bilayer membranes without causing membrane damage. COSANs transport arginine-rich and lysine-rich peptides effectively, but cannot transport small molecules or anionic cargos. The transportation mechanism is a molecular carrier mechanism, and living cell experiments show that a fluorescent peptide cargo can be delivered into the cytosol.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

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Review Chemistry, Medicinal

Next generation of boron neutron capture therapy (BNCT) agents for cancer treatment

Paolo Coghi et al.

Summary: Boron neutron capture therapy (BNCT) is a promising treatment method in cancer therapy. The currently used boron compounds, l-boronophenylalanine (BPA) and sodium borocaptate (BSH), have their limitations and there is a need for next generation BNCT agents. Various boron compounds, including small molecules and macro/nano-vehicles, have been explored and have shown better success. This review summarizes the current knowledge of different boron compounds for BNCT application and provides a perspective for the future of BNCT in cancer treatment.

MEDICINAL RESEARCH REVIEWS (2023)

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Review Biochemistry & Molecular Biology

Towards the Application of Purely Inorganic Icosahedral Boron Clusters in Emerging Nanomedicine

Francesc Teixidor et al.

Summary: Traditionally, drugs were obtained from medicinal plants, but now more drugs are synthesized organically. Most commercial drugs today are organic compounds that can contain nitrogen, oxygen, halogens, carbon, and hydrogen. Aromatic organic compounds are important in biochemistry and have various applications in drug delivery, nanotechnology, and biomarkers. The discovery of global 3D aromaticity in boranes, carboranes, and metallabis(dicarbollides) has opened up new opportunities for their use in healthcare materials.

MOLECULES (2023)

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Article Chemistry, Multidisciplinary

Cobalt and iron bis(dicarbollide) conjugates with cholesterol: synthesis and evaluation of antiproliferative activity

K. E. Erdelyi et al.

Summary: Boron-containing conjugates of cholesterol were synthesized via copper(I)-catalyzed 1,3-dipolar [3+2] cycloaddition reactions. The antiproliferative activity of the conjugates was evaluated against various human cell lines, showing low toxicity and potential for cancer treatment.

RUSSIAN CHEMICAL BULLETIN (2023)

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Review Cell Biology

Next-Generation Boron Drugs and Rational Translational Studies Driving the Revival of BNCT

Danushka S. Seneviratne et al.

Summary: BNCT is a high-linear-energy transfer therapy that selectively delivers radiation to tumor cells while sparing normal tissues. The focus is on developing boronated compounds with high selectivity, ease of delivery, and large boron payloads. There is also interest in exploring the immunogenic potential of BNCT and utilizing it to improve outcomes in difficult-to-treat malignancies. This review covers the radiobiological and physical aspects of BNCT, traditional and next-generation boron compounds, as well as translational studies and innovative approaches for leveraging BNCT's immunogenicity.

CELLS (2023)

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Article Biology

A Combined in Silico and Structural Study Opens New Perspectives on Aliphatic Sulfonamides, a Still Poorly Investigated Class of CA Inhibitors

Emma Langella et al.

Summary: Carbonic anhydrases are enzymes involved in an important physiological reaction of converting CO2 to bicarbonate ion. They play crucial roles in various physiological and pathological processes in humans, making them potential targets for therapeutic interventions. This study investigates a class of carbonic anhydrase inhibitors, providing insights into their mechanism of action and potential for drug design.

BIOLOGY-BASEL (2023)

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Review Chemistry, Inorganic & Nuclear

Supramolecular chemistry of anionic boron clusters and its applications in biology

Jakub Cebula et al.

Summary: This article discusses the intertwining of supramolecular chemistry and biology, and the importance and potential of boron cluster chemistry in biological applications.

COORDINATION CHEMISTRY REVIEWS (2023)

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Article Instruments & Instrumentation

Metallacarboranes for proton therapy using research accelerators: a pilot study

Teresa Pinheiro et al.

Summary: The feasibility of using an external beam microprobe facility to explore the biological effects of proton irradiation in cultured cells is demonstrated. An in-air irradiation set-up was developed that allows energy tuning and estimation of flux and dose deposition. A pilot study on the effect of boron-rich metallacarboranes as radiosensitizers towards human glioblastoma cells was carried out, providing proof of concept for the enhancement effect of proton irradiation induced by the presence of boron.

EPJ TECHNIQUES AND INSTRUMENTATION (2023)

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Article Chemistry, Medicinal

Employment of chiral columns with superficially porous particles in chiral separations of cobalt bis (dicarbollide) and nido-7,8-C2B9H12(1-) derivatives

Ondrej Horacek et al.

Summary: Derivatives of nido-7,8-C2B9H12(1-) and [3,3'-Co-(1,2-C2B9H11)(2)](1-) represent stable abiotic compounds with potential applications in various research areas. However, their chirality and chiral separations have been overlooked, hindering progress in these fields. This study introduces a versatile column for faster chiral separations of these compounds, providing a valuable tool for synthetic chemists.

CHIRALITY (2023)

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Article Chemistry, Multidisciplinary

Aromaticity and Extrusion of Benzenoids Linked to [o-COSAN]-: Clar Has the Answer

Jordi Poater et al.

Summary: Benzene and pyrene can be synthetically linked to [o-COSAN](-) while maintaining their aromaticity, while naphthalene and anthracene are extruded in the same reaction. The number of Clar's pi-sextets determines whether extrusion is favorable or not. Thus, Clar provides the answer to the extrusion of attached polycyclic aromatic hydrocarbons to [o-COSAN](-).

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Nematicidal activity of naphthalimide-boron cluster conjugates

Anna Bogucka-Kocka et al.

Summary: This study demonstrates the activity of a series of 1,8-naphthalimide-carborane/metallacarborane conjugates against Rhabditis sp. The conjugates with cobaltacarborane showed high activity compared to other carborane conjugates.

CHEMICAL COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Structurally rigidified cobalt bis(dicarbollide) derivatives, a chiral platform for labelling of biomolecules and new materials

Suzan El Anwar et al.

Summary: In this study, we have reported a difunctional modification method for anionic cobalta bis(dicarbollide)(1(-)) clusters by introducing a B(8,8')-oxygen bridging unit and organic alkylazide substituents on the carbon atoms of the metallacarborane cage, which enhances their structural rigidity. These ions show good binding motifs for incorporation into organic molecules through Huisgen-Sharpless (2+3) cycloaddition reactions, and can be separated into enantiomers using chiral stationary phases. The electrochemical testing results indicate that these compounds exhibit high peaks located outside the typical signals of biomolecules.

CHEMICAL COMMUNICATIONS (2022)

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Article Biochemical Research Methods

Reversed-phase chromatography as an effective tool for the chiral separation of anionic and zwitterionic carboranes using polysaccharide-based chiral selectors

Ondrej Horacek et al.

Summary: This study explores the chiral separations of anionic cobalt bis(dicarbollide) and dicarba-7,8-nido-undecaborane derivatives using four polysaccharide-based columns under reversed-phase conditions. Compared to previously reported results in normal phase and polar-organic mode, reversed-phase separations demonstrate higher resolution, lower consumption of organic solvents, and greater flexibility during method development. Additionally, the first chiral discrimination of some hydroxyalkyl derivatives of anionic cobalt bis(dicarbollides) is reported.

JOURNAL OF CHROMATOGRAPHY A (2022)

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Article Chemistry, Physical

Counterion-Induced Aggregation of Metallacarboranes

Ziga Medos et al.

Summary: This study verifies the model of counterion-induced metallacarborane aggregation in water and introduces a novel approach that resembles the behavior of polyoxometalate nanoions. The key factors for counterion binding to the aggregates are the uneven charge distribution of cobalt bis(dicarbollide) clusters and the size compatibility between the counterion and the voids between the metallacarborane clusters. The study also shows that metallacarboranes can form larger nanostructures via a second aggregation mechanism.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

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Article Chemistry, Multidisciplinary

Synthesis and cytotoxicity of novel cholesterol-cobalt bis(dicarbollide) conjugates

Anna A. Druzina et al.

Summary: Novel cholesterol conjugates with cobalt bis(dicarbollide) were synthesized and tested for toxicity.

MENDELEEV COMMUNICATIONS (2022)

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Review Biochemistry & Molecular Biology

Boron Chemicals in Drug Discovery and Development: Synthesis and Medicinal Perspective

Bhaskar C. Das et al.

Summary: This review introduces current boron-containing drug candidates, including boron-based compounds for the treatment of different diseases. It also describes their synthesis, structure-activity relationship, and associated biological activities.

MOLECULES (2022)

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Article Biochemistry & Molecular Biology

Synthesis and Antibacterial Activity Studies of the Conjugates of Curcumin with closo-Dodecaborate and Cobalt Bis(Dicarbollide) Boron Clusters

Anna A. Druzina et al.

Summary: A series of novel conjugates of cobalt bis(dicarbollide) and closo-dodecaborate with curcumin were synthesized and tested for antibacterial activity. One of the conjugates exhibited better activity against Gram-positive microorganisms.

MOLECULES (2022)

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Article Biochemistry & Molecular Biology

Electrochemistry of Cobalta Bis(dicarbollide) Ions Substituted at Carbon Atoms with Hydrophilic Alkylhydroxy and Carboxy Groups

Lukas Fojt et al.

Summary: This study explores the effect of hydrophilic alkylhydroxy and carboxy groups on the electrochemical signals of cobalta bis(dicarbollide) ions in aqueous buffers. The results show that the location and type of substitution have minimal effect on the electrochemical response, but the intensity of the signals is dependent on concentration.

MOLECULES (2022)

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Article Multidisciplinary Sciences

Boron clusters as broadband membrane carriers

Andrea Barba-Bon et al.

Summary: This study demonstrates that globular dodecaborate clusters can function as anionic inorganic membrane carriers for a wide range of hydrophilic cargo molecules. These carriers have the potential to transport peptides, amino acids, neurotransmitters, vitamins, antibiotics, and drugs across liposomal membranes, and affect the cytosolic uptake of various small bioactive molecules.

NATURE (2022)

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Review Chemistry, Multidisciplinary

Carboxylic Acid Bioisosteres in Medicinal Chemistry: Synthesis and Properties

Kato Bredael et al.

Summary: Lead optimization involves the fine-tuning of lead compounds to improve their drug-like properties. This literature overview focuses on the use of bioisosteres to replace the carboxylic acid functionality, which is commonly associated with poor pharmacokinetic properties and toxicity. By replacing this functionality, the activity and pharmacokinetic properties of the lead compounds can be maintained or even enhanced.

JOURNAL OF CHEMISTRY (2022)

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Review Oncology

Carboranes as unique pharmacophores in antitumor medicinal chemistry

Yu Chen et al.

Summary: Carborane is a unique carbon-boron molecular cluster that has the potential to be used as a novel pharmacophore for drug design. Its derivatives have significant applications in antitumor chemistry.

MOLECULAR THERAPY-ONCOLYTICS (2022)

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Article Chemistry, Medicinal

Cobalt Bis-Dicarbollide Enhances Antibiotics Action towards Staphylococcus epidermidis Planktonic Growth Due to Cell Envelopes Disruption

Eva Vankova et al.

Summary: COSAN.Na can enhance the action of antibiotics against Staphylococcus epidermidis and disrupt cell envelopes, making it a promising approach to overcome antibiotic resistance in Gram-positive cocci.

PHARMACEUTICALS (2022)

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Article Chemistry, Medicinal

The Boron Advantage: The Evolution and Diversification of Boron's Applications in Medicinal Chemistry

Katia Messner et al.

Summary: This review discusses the history of boron's early use in drugs and the use of boron functional groups in medicinal chemistry. It highlights critical developments from these functional groups and showcases the application of boron in prodrugs, softdrugs, and nanocarriers.

PHARMACEUTICALS (2022)

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Review Biochemistry & Molecular Biology

History of Cobaltabis(dicarbollide) in Potentiometry, No Need for Ionophores to Get an Excellent Selectivity

Anca-Iulia Stoica et al.

Summary: This work highlights the applications of the theta metallabis(dicarbollide) cluster in preparing sensors for monitoring amine-containing drugs or other nitrogen-containing molecules. The developed electrodes show Nernstian responses for target analytes, such as antibiotics, amino acids, neurotransmitters, and analgesics.

MOLECULES (2022)

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Article Biochemistry & Molecular Biology

Synthesis of Cobalt Bis(Dicarbollide)-Curcumin Conjugates for Potential Use in Boron Neutron Capture Therapy

Lyubov G. Dezhenkova et al.

Summary: Novel cobalt bis(dicarbollide)-curcumin conjugates were synthesized and found to be non-cytotoxic against tumor and normal cells. Flow cytometry analysis showed that these conjugates entered the cells in a time-dependent manner.

MOLECULES (2022)

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Article Multidisciplinary Sciences

3D and 2D aromatic units behave like oil and water in the case of benzocarborane derivatives

Jordi Poater et al.

Summary: This study investigates the possibility of 3D/2D aromatic fusions and their relationship to electronic delocalization. While 2D/2D and 3D/3D aromatic fusions have been synthesized, the ineffective overlap between the pi-MOs of planar species and the n + 1 molecular orbitals in the aromatic cage makes 3D/2D aromatic combination impossible.

NATURE COMMUNICATIONS (2022)

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Review Chemistry, Multidisciplinary

Carboranes in drug discovery, chemical biology and molecular imaging

Anita Marfavi et al.

Summary: There is a lack of structural innovation and limited molecular diversity in drug discovery and biomolecular imaging/chemical probe design. However, carboranes, especially boron clusters, offer an alternative with unique properties and unusual interactions with biological receptors, making them promising frameworks for chemical biology or medicine.

NATURE REVIEWS CHEMISTRY (2022)

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Article Chemistry, Analytical

Study of the Possibility of Deep Partitioning of the Spent Nuclear Fuel Reprocessing Raffinate According to the Scheme of a Pilot Demonstration Center by Extraction with a Mixture of CCD, PEO, and HDEHP in a Polar Solvent

D. N. Shishkin et al.

Summary: Laboratory studies have shown that using a specific extractant in the high-level waste processing can effectively separate hazardous elements, increasing storage safety and reducing storage and disposal costs. This partitioning scheme has advantages over previous schemes.

RADIOCHEMISTRY (2022)

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Article Chemistry, Analytical

Electrochemically deposited cobalt bis(dicarbollide) derivative and the detection of neuroblastoma markers on the electrode surface

Tatiana Shishkanova et al.

Summary: A cobalt bis(dicarbollide) derivative deposited onto the surface of a graphite electrode through an electrochemically oxidized o-phenylenediamine unit (pCB-oPD) is proposed for the detection of catecholamine metabolites, namely homovanillic acid (HVA) and vanillylmandelic acid (VMA). The set of electrochemical techniques makes it possible to evaluate the options of the individual and simultaneous detection of metabolites.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2022)

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Article Chemistry, Analytical

Advanced Tool for Chiral Separations of Anionic and Zwitterionic (Metalla)carboranes: Supercritical Fluid Chromatography

Ondrej Horacek et al.

Summary: The continuous expansion of research in the field of stable carboranes and their wide potential in drug design require fundamental studies on chiral separations. This study aimed to develop a straightforward method for chiral separations of racemic mixtures of anionic cluster carboranes and metallacarboranes. The results demonstrated the clear advantage of SFC over HPLC in terms of analysis time and variety of successfully separated compounds.

ANALYTICAL CHEMISTRY (2022)

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Article Chemistry, Medicinal

Metallacarborane Derivatives as Innovative Anti-Candida albicans Agents

Konrad Kubinski et al.

Summary: Infections caused by Candida species have become a serious public health problem globally. Traditional antifungal drugs are becoming less effective against Candida due to drug resistance. This study found that metallacarborane derivatives based on cobalt bis-dicarbollide [COSAN] are effective against Candida, even against drug-resistant strains, and show potential synergy with amphotericin B.

JOURNAL OF MEDICINAL CHEMISTRY (2022)

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Article Chemistry, Physical

How to switch from a poor PEDOT:X oxygen evolution reaction (OER) to a good one. A study on dual redox reversible PEDOT:metallacarborane

Jewel Ann Maria Xavier et al.

Summary: By intimately blending PEDOT and metallacarboranes, a dual redox reversible material is formed, which lowers the over-potential for the oxygen evolution reaction and shows promise for practical applications.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Biotechnology & Applied Microbiology

Highly Purified Conjugates of Natural Chlorin with Cobalt Bis(dicarbollide) Nanoclusters for PDT and BNCT Therapy of Cancer

Maria K. Fedotova et al.

Summary: In this study, a conjugate of chlorin e6 methyl ester with cyclen and dioxane, as well as nitrile derivatives of cobalt bis(dicarbollide), were synthesized to combine the neutron-capturing properties of boron nanoclusters and the photodynamic properties of natural chlorins. The purification conditions for compounds by HPLC were selected due to the presence of closely related impurities in natural compounds.

BIOENGINEERING-BASEL (2022)

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Article Chemistry, Multidisciplinary

Cobalt Bis(dicarbollide) Alkylsulfonamides: Potent and Highly Selective Inhibitors of Tumor Specific Carbonic Anhydrase IX

Bohumir Gruner et al.

Summary: A series of derivatives based on cobalt bis(dicarbollide)(1-) anion were reported, which can inhibit CAIX with subnanomolar inhibition constants and high selectivity. The compound with n=3 and two substituents in a rac-arrangement showed the best inhibitory properties. X-ray crystallography was used to study the interactions of these compounds with the active site of CAIX on the structural level.

CHEMPLUSCHEM (2021)

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Article Nanoscience & Nanotechnology

In Vivo Evaluation of Multifunctional Gold Nanorods for Boron Neutron Capture and Photothermal Therapies

Krishna R. Pulagam et al.

Summary: A boron-rich nanoparticle composite has been developed for potential applications in cancer therapy, utilizing both BNCT and PTT. By functionalizing gold nanorods and labeling them with Cu-64, the nanoparticles showed promising results in tumor tracking and demonstrated high biocompatibility and therapeutic efficacy in mouse models of gastrointestinal cancer.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Light-Induced On/Off Switching of the Surfactant Character of the o-Cobaltabis(dicarbollide) Anion with No Covalent Bond Alteration

Abdelazim M. A. Abdelgawwad et al.

Summary: The study demonstrates the possibility of photoinducing the rotation of cobaltabis(dicarbollide) anion molecules from the cisoid to the transoid rotamer, with potential applications in nanomedicine. Experimental results show the lack of fluorescence in [o-COSAN](-) and its derivatives in aqueous solution, suggesting promising applications in the field of nanomedicine.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Inorganic & Nuclear

Boron cluster compounds as new chemical leads for antimicrobial therapy

Krzysztof Fink et al.

Summary: Boron cluster compounds are inorganic compounds with unique structures and properties that show promising antimicrobial activity and low sensitivity to pathogen resistance mechanisms. Their derivatives are effective against both standard and multi-drug resistant strains of pathogens.

COORDINATION CHEMISTRY REVIEWS (2021)

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Editorial Material Pharmacology & Pharmacy

What are the current challenges with the application of boron clusters to drug design?

Zbigniew J. Lesnikowski

EXPERT OPINION ON DRUG DISCOVERY (2021)

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Article Chemistry, Medicinal

Effects of Linkers on the Development of Liposomal Formulation of Cholesterol Conjugated Cobalt Bis(dicarbollides)

Ravindra Dhar Dubey et al.

Summary: Boron neutron capture therapy is an important treatment for cancer patients, requiring a significant amount of boron to be selectively deposited in cancer tissues. Modifying the polyhedral boron core to be hydrophobic and incorporating it into the lipid layer can increase drug loading and encapsulation efficiency. Additional studies on linker-dependent effects and hydrophobicity are needed for further development of liposomal formulations for hydrophobic-drugs.

JOURNAL OF PHARMACEUTICAL SCIENCES (2021)

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Article Chemistry, Inorganic & Nuclear

Towards purely inorganic clusters in medicine: Biocompatible divalent cations as counterions of cobaltabis(dicarbollide) and its iodinated derivatives

Adnana Zaulet et al.

Summary: This work isolates the cobaltabis(dicarbollide) salts of biocompatible divalent cations of biological importance for potential applications in biology and materials science. The study reports the preparation of Ca2+, Mg2+ and Fe2+ salts with anionic iodinated nido-[C2B9H12](-) and cobaltabis(dicarbollide), with different coordination behaviors in solvents. The Ca2+ and Mg2+ salts form aqua ions in the presence of water, while Fe2+ and Fe3+ display different coordination behaviors in acetone.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2021)

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Review Chemistry, Medicinal

Preparing (Metalla)carboranes for Nanomedicine

Marta Gozzi et al.

Summary: This paper discusses the potential application of boron-based drugs in the field of nanomedicine and calls on medicinal boron chemists to bridge the gap between the chemistry laboratory and real applications in living systems to promote the development of boron cluster compounds.

CHEMMEDCHEM (2021)

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Article Biochemistry & Molecular Biology

Synthesis of Boronated Amidines by Addition of Amines to Nitrilium Derivative of Cobalt Bis(Dicarbollide)

Ekaterina Bogdanova et al.

Summary: A series of novel cobalt bis(dicarbollide) based amidines were synthesized by adding primary and secondary amines to a specific compound, leading to different isomer mixtures when reacting with primary vs. secondary amines. Crystal structures of these compounds were determined by X-ray diffraction.

MOLECULES (2021)

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Review Biochemistry & Molecular Biology

Boron clusters as breast cancer therapeutics

Neville Murphy et al.

Summary: The design of small molecule-based therapeutics has been dominated by organic components since their foundation over 100 years ago, but the incorporation of boron clusters shows potential in overcoming multidrug resistance and improving therapeutic index. These compounds offer a unique set of molecular interactions in targeted therapies and have the ability to enhance the effectiveness of many organic formulations.

JOURNAL OF INORGANIC BIOCHEMISTRY (2021)

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Review Oncology

Boron Neutron Capture Therapy: A Review of Clinical Applications

Timothy D. Malouff et al.

Summary: Boron neutron capture therapy (BNCT) is an emerging treatment modality that utilizes boron-10 to target tumors and has shown promising results in various cancer types in clinical studies.

FRONTIERS IN ONCOLOGY (2021)

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Review Biochemistry & Molecular Biology

Inhibitors of CA IX Enzyme Based on Polyhedral Boron Compounds

Michael Kugler et al.

Summary: This review discusses the recent advancements in designing inhibitors of human carbonic anhydrase IX (CA IX) using space-filling carborane and cobalt bis(dicarbollide) clusters. The inhibitors showed promising results in preclinical evaluation with low toxicity, favorable pharmacokinetics, and inhibition of tumor growth, making them potential candidates for drug development or combination therapy.

CHEMBIOCHEM (2021)

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Article Chemistry, Multidisciplinary

Rotational conformation of 8,8′-dihalogenated derivatives of cobalt bis(dicarbollide) in solution

I. B. Sivaev et al.

Summary: The study using H-1 NMR revealed that the transoid conformation of dihalogenated derivatives of cobalt bis(dicarbollide) [8,8 '-X-2-3,3 '-Co(1,2-C2B9H10)(2)](-) (X = Cl, Br, I), stabilized by intramolecular C-H... X hydrogen bonds between ligands, is maintained in solution.

RUSSIAN CHEMICAL BULLETIN (2021)

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Article Biochemistry & Molecular Biology

Synchrotron-Based Fourier-Transform Infrared Micro-Spectroscopy (SR-FTIRM) Fingerprint of the Small Anionic Molecule Cobaltabis(dicarbollide) Uptake in Glioma Stem Cells

Miquel Nuez-Martinez et al.

Summary: The research found that the anionic cobaltabis retains anti-cancer properties, demonstrating potential effectiveness in altering cell physiology and targeting glioblastoma cells.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2021)

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Article Biochemistry & Molecular Biology

Metallacarborane Derivatives Effective against Pseudomonas aeruginosa and Yersinia enterocolitica

Wieslaw Swietnicki et al.

Summary: Novel compounds based on metallacarborane cage showed antibacterial activity against Yersinia pestis substitute Yersinia enterocolitica and Pseudomonas aeruginosa, indicating a common mechanism for drug resistance in the former. The compounds had predominantly bacteriostatic effect and may serve as a starting point for novel anti-Yersinia drugs.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2021)

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Article Chemistry, Inorganic & Nuclear

Anionic polyhedral boron clusters conjugates with 7-diethylamino-4-hydroxycoumarin. Synthesis and lipophilicity determination

Alexander Serdyukov et al.

Summary: A series of water-soluble conjugates of 7-diethylamino-4-hydroxycoumarin with four different anionic polyhedral boron clusters were synthesized and tested for their ability to pass through the cell membrane. The results showed two compounds with negative lipophilicity values, while conjugates of metallacarboranes containing Co and Fe were found to be suitable for medicinal applications.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2021)

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Article Chemistry, Analytical

Mass transfer studies in a micromixer-settler: extraction of Cs and Sr with CCD-PEG-400 solvent from simulated acidic radwaste solutions

Shekhar Kumar et al.

Summary: Solvent extraction of Cs(I) and Sr(II) from a simulated radwaste acidic solution was found to be much faster in a microfluidic channel based miniature extractor compared to batch equilibration studies.

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Cyclic oxonium derivatives of cobalt and iron bis(dicarbollides) and their use in organic synthesis

Anna A. Druzina et al.

Summary: The research reviews the rapid progress in the chemistry of carboranes and other polyhedral boron compounds, particularly focusing on the ring-opening reaction of cyclic oxonium derivatives as an efficient method for the preparation of these compounds.

RUSSIAN CHEMICAL REVIEWS (2021)

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Article Oncology

Interaction of Adenosine, Modified Using Carborane Clusters, with Ovarian Cancer Cells: A New Anticancer Approach against Chemoresistance

Katarzyna Bednarska-Szczepaniak et al.

Summary: The study focused on designing and synthesizing adenosine conjugates with metallacarboranes containing iron, cobalt, or chromium to influence the cisplatin sensitivity of ovarian cancer cells. The iron-containing metallacarborane conjugates demonstrated the best anticancer activity, sensitizing resistant cells without inducing cross-resistance to other chemotherapy drugs. This research highlights the potential of using metallacarborane-modified adenosine to enhance the sensitivity of ovarian cancer cells to cisplatin in combination therapy.

CANCERS (2021)

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Article Chemistry, Multidisciplinary

A stand-alone cobalt bis(dicarbollide) photoredox catalyst epoxidates alkenes in water at extremely low catalyst load

Isabel Guerrero et al.

Summary: The cobalt bis(dicarbollide) complex Na[3,3'-Co(eta(5)-1,2-C2B9H11) (Na[1]) is an effective photoredox catalyst for the oxidation of alkenes to epoxides in water, exhibiting high efficiency and selectivity compared to other photosensitizers. By adjusting the catalyst loading, different product selectivity and conversion rates can be achieved in the reaction.

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Radiolabeled Cobaltabis(dicarbollide) Anion-Graphene Oxide Nanocomposites for In Vivo Bioimaging and Boron Delivery

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Neutron Activated 153Sm Sealed in Carbon Nanocapsules for in Vivo Imaging and Tumor Radiotherapy

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Electrochemistry of icosahedral cobalt bis(dicarbollide) ions and their carbon and boron substituted derivatives in aqueous phosphate buffers

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ELECTROCHIMICA ACTA (2020)

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Novel Cobalt Bis(dicarbollide) Based on Terminal Alkynes and Their Click-Reactions

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Highlights on the Binding of Cobalta-Bis-(Dicarbollide) with Glucose Units

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Synthesis of coumarins modified with cobalt bis (1,2-dicarbolide) and closo-dodecaborate boron clusters

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Metallacarborane Assemblies as Effective Antimicrobial Agents, Including a Highly Potent Anti-MRSA Agent

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Tetrazole Ring Substitution at Carbon and Boron Sites of the Cobalt Bis(dicarbollide) Ion Available via Dipolar Cycloadditions

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Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)

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Experience of Mastering, Industrial Exploitation, and Optimization of the Integrated Extraction-Precipitation Technology for Fractionation of Liquid High-Activity Wastes at Mayak Production Association

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Half- and mixed-sandwich metallacarboranes for potential applications in medicine

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High-Affinity Binding of Metallacarborane Cobalt Bis(dicarbollide) Anions to Cyclodextrins and Application to Membrane Translocation

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Metallacarborane Sulfamides: Unconventional, Specific, and Highly Selective Inhibitors of Carbonic Anhydrase IX

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Unusual resistance of cobalt bis dicarbollide phosphate and phosphorothioate bridged esters towards alkaline hydrolysis: The metallacarborane effect

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Modified Diamide and Phosphine Oxide Extracting Compounds as Membrane Components for Cross-Sensitive Chemical Sensors

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The Chaotropic Effect as an Assembly Motif in Chemistry

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Electronic Interactions between Ferrocenyl Units Facilitated by the Cobalt Bis(dicarbollide) Anion Linker: An Experimental and DFT Study

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Low-Symmetry Phthalocyanine Cobalt Bis(dicarbollide) Conjugate for Hydrogen Reduction

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Deciphering the role of the cation in anionic cobaltabisdicarbollide clusters

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Synthesis of 8-alkoxy and 8,8′-dialkoxy derivatives of cobalt bis(dicarbollide)

Marina Yu. Stogniy et al.

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Liposomal Drug Delivery Systems and Anticancer Drugs

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Synthesis of cobalt bis(8-methylthio-1,2-dicarbollide)-pentacarbonyltungsten complexes

S. V. Timofeev et al.

RUSSIAN CHEMICAL BULLETIN (2018)

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Remarkable aromaticity of cobalt bis(dicarbollide) derivatives: a NICS study

Georgia M. A. Junqueira

THEORETICAL CHEMISTRY ACCOUNTS (2018)

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Metallacarboranes on the Road to Anticancer Therapies: Cellular Uptake, DNA Interaction, and Biological Evaluation of Cobaltabisdicarbollide [COSAN]-

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DNA Modified with Boron-Metal Cluster Complexes [M(C2B9H11)(2)]Synthesis, Properties, and Applications

Agnieszka B. Olejniczak et al.

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New sulfur derivatives of carboranes and metallacarboranes

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Catecholamines profiles at diagnosis: Increased diagnostic sensitivity and correlation with biological and clinical features in neuroblastoma patients

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Methylsulfanyl-Stabilized Rotamers of Cobalt Bis(dicarbollide)

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Pharmacokinetics of Chlorin e6-Cobalt Bis(Dicarbollide) Conjugate in Balb/c Mice with Engrafted Carcinoma

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Naked Lithium Cation: Strongly Activated Metal Cations Facilitated by Carborane Anions

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Cobalt bis(dicarbollide) anion and its derivatives

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Disubstituted cobalt bis(1,2-dicarbollide)(-I) terminal alkynes: Synthesis, reactivity in the Sonogashira reaction and application in the synthesis of cobalt bis(1,2-dicarbollide)(-I) nucleoside conjugates

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Practical synthesis of 9-methylthio-7,8-nido-carborane [9-MeS-7,8-C2B9H11]-. Some evidences of BH•••X hydride-halogen bonds in 9-XCH2(Me)S-7,8-C2B9H11 (X = Cl, Br, I)

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Preparation, characterization, and the selective antimicrobial activity of N-alkylammonium 8-diethyleneglycol cobalt bis-dicarbollide derivatives

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Two-Step Micellization Model: The Case of Long-Chain Carboxylates in Water

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Review Biochemistry & Molecular Biology

Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches

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MOLECULES (2017)

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Rodlike Polymers Containing Nickel and Cobalt Metal Bis(dicarbollide) Anions: Synthesis and Characterization

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A Highly Potent Antibacterial Agent Targeting Methicillin-Resistant Staphylococcus aureus Based on Cobalt Bis(1,2-Dicarbollide) Alkoxy Derivative

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ORGANOMETALLICS (2017)

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Fast flip-flop of halogenated cobalt bis(dicarbollide) anion in a lipid bilayer membrane

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Ligands for f-element extraction used in the nuclear fuel cycle

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Small-Molecule Kinase-Inhibitors-Loaded Boron Cluster as Hybrid Agents for Glioma-Cell-Targeting Therapy

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CHEMISTRY-A EUROPEAN JOURNAL (2017)

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Nanomaterials for In Vivo Imaging

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Charge-Compensated Metallacarborane Building Blocks for Conjugation with Peptides

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CHEMBIOCHEM (2016)

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Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

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Challenges and Opportunities for the Application of Boron Clusters in Drug Design

Zbigniew J. Lesnikowski

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Stealth Amphiphiles: Self-Assembly of Polyhedral Boron Clusters

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LANGMUIR (2016)

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Carbon Nanomaterials for Biological Imaging and Nanomedicinal Therapy

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CHEMICAL REVIEWS (2015)

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Cyanide free contraction of disclosed 1,4-dioxane ring as a route to cobalt bis(dicarbollide) derivatives with short spacer between the boron cage and terminal functional group

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DALTON TRANSACTIONS (2015)

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Tungsten carbonyl sigma-complexes with charge-compensated nido-carboranyl thioether ligands

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DALTON TRANSACTIONS (2015)

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The Synthesis and Structural Characterization of Polycyclic Derivatives of Cobalt Bis(dicarbollide)(1-)

Bohumir Gruener et al.

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Chemistry of cobalt bis(1,2-dicarbollide) ion; the synthesis of carbon substituted alkylamino derivatives from hydroxyalkyl derivatives via methylsulfonyl or p-toluenesulfonyl esters

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Boron clusters in medicinal chemistry: perspectives and problems

Detlef Gabel

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Synthesis of 9,9′,12,12′-substituted cobalt bis(dicarbollide) derivatives

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Cobaltacarborane functionalized phthalocyanines: Synthesis, photophysical, electrochemical and spectroelectrochemical properties

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π Aromaticity and Three-Dimensional Aromaticity: Two sides of the Same Coin?

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Aqueous Self-Assembly and Cation Selectivity of Cobaltabisdicarbollide Dianionic Dumbbells

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Synthesis, characterisation and some chemistry of C- and B-substituted carboxylic acids of cobalt bis(dicarbollide)

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Surfactant behaviour of metallacarboranes. A study based on the electrolysis of water

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Electrodriven Selective Transport of Cs+ Using Chlorinated Cobalt Dicarbollide in Polymer Inclusion Membrane: A Novel Approach for Cesium Removal from Simulated Nuclear Waste Solution

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Novel alkoxy derivatives of cobalt bis(1,2-dicarbollide)

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Chlorin e6 fused with a cobalt-bis(dicarbollide) nanoparticle provides efficient boron delivery and photoinduced cytotoxicity in cancer cells

Anastasija V. Efremenko et al.

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Lyotropic Lamellar Phase Formed from Monolayered θ-Shaped Carborane-Cage Amphiphiles

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Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms

Hans J. Reich

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Selective Syntheses of Planar-Chiral Ferrocenes

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Synthesis of new charge-compensated cobalt bis(1,2-dicarbollide) derivatives

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Unfairly Forgotten Member of the Iodocarborane Family: Synthesis and Structural Characterization of 8-Iodo-1,2-dicarba-closo-dodecaborane, Its Precursors, and Derivatives

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Nitric Oxide Synthases Activation and Inhibition by Metallacarborane-Cluster-Based Isoform-Specific Affectors

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Tungsten carbonyl σ-complexes of nido-carborane thioethers

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Mild C-H activation of activated aromatics with [8,8′-μ-I-3,3′-Co(1,2-C2B9H10)2]: Just mix them

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The Zwitterion (8,8′-μ-CH2O(CH3)-(1,2-C2B9H10)2-3,3′-Co]0 as a Versatile Building Block To Introduce Cobalt Bis(Dicarbollide) Ion into Organic Molecules

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Cobalt bis(dicarbollide) versus closo-dodecaborate in boronated chlorin e6 conjugates: implications for photodynamic and boron-neutron capture therapy

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Carbaboranes as Pharmacophores: Properties, Synthesis, and Application Strategies

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Boron in Drug Discovery: Carboranes as Unique Pharmacophores in Biologically Active Compounds

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Emerging Subject for Chiral Separation Science: Cluster Boron Compounds

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Relaxed but Highly Compact Diansa Metallacyclophanes

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Solubilization and deaggregation of cobalt bis(dicarbollide) derivatives in water by biocompatible excipients

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Medical Progress: Recent Advances in Neuroblastoma.

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Polyhedral Boranes for Medical Applications: Current Status and Perspectives

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First example of the formation of a Si-C bond from an intramolecular Si-H•••H-C diyhydrogen interaction in a metallacarborane: A theoretical study

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Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste

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A Simple and Rapid Method for Measurement of 10B-para-Boronophenylalanine in the Blood for Boron Neutron Capture Therapy Using Fluorescence Spectrophotometry

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Synthesis and Spectroelectrochemistry of N-Cobaltacarborane Porphyrin Conjugates

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Controlled direct synthesis of C-Mono- and C-disubstituted derivatives of [3,3 '-Co(1,2-C(2)B(9)H(11))(2)](-) with organosilane groups: Theoretical calculations compared with experimental results

Emilio Jose Juarez-Perez et al.

CHEMISTRY-A EUROPEAN JOURNAL (2008)

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Chemical Ligation: A Versatile Method for Nucleoside Modification with Boron Clusters

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Cyclic oxonium derivatives of polyhedral boron hydrides and their synthetic applications

Andrey A. Semioshkin et al.

DALTON TRANSACTIONS (2008)

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Inorganic polyhedral metallacarborane inhibitors of HIV protease:: A new approach to overcoming antiviral resistance

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Boron detection from blood samples by ICP-AES and ICP-MS during boron neutron capture therapy

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Airway epithelial control of Pseudomonas aeruginosa infection in cystic fibrosis

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Synthesis, aggregation and cellular investigations of porphyrin-cobaltacarborane conjugates

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CHEMISTRY-A EUROPEAN JOURNAL (2007)

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Review Chemistry, Multidisciplinary

Chemistry of the carba-closo-dodecaborate(-) anion, CB11H12-

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CHEMICAL REVIEWS (2006)

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Review Chemistry, Inorganic & Nuclear

Computational studies of structures and properties of metallaboranes.: 2.: Transition-metal dicarbollide complexes

M Bühl et al.

ORGANOMETALLICS (2006)

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Article Chemistry, Multidisciplinary

Molecular assembly of metallacarboranes in water:: Light scattering and microscopy study

P Matejícek et al.

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Article Chemistry, Multidisciplinary

Highly stable neutral and positively charged dicarbollide sandwich complexes

R Núñez et al.

CHEMISTRY-A EUROPEAN JOURNAL (2005)

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Review Chemistry, Multidisciplinary

Computational study of structures and properties of metallaboranes:: Cobalt bis(dicarbollide)

M Bühl et al.

CHEMISTRY-A EUROPEAN JOURNAL (2005)

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Review Chemistry, Inorganic & Nuclear

Cage C-H•••X interactions in solid-state structures of icosahedral carboranes

MA Fox et al.

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Article Chemistry, Multidisciplinary

Synthesis and coordinating ability of an anionic cobaltabisdicarbollide ligand geometrically analogous to BINAP

I Rojo et al.

CHEMISTRY-A EUROPEAN JOURNAL (2004)

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Review Medical Laboratory Technology

Measurement of catecholamines and their metabolites

RT Peaston et al.

ANNALS OF CLINICAL BIOCHEMISTRY (2004)

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Article Chemistry, Inorganic & Nuclear

Syntheses of the B(8)-hydroxy- and B(8,8′)-dihydroxy-derivatives of the bis(1,2-dicarbollido)-3-colbalt(1-)ate ion by its reductive acetoxylation and hydroxylation:: molecular structure of [8,8′-μ-CH3C(O)2(1,2-C2B9H10)2-3-Co]0 zwitterion determined by X-ray diffraction analysis

J Plesek et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2002)

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Article Chemistry, Multidisciplinary

Development and testing of a cobalt dicarbollide based solvent extraction process for the separation of cesium and strontium from acidic tank waste

RS Herbst et al.

SEPARATION SCIENCE AND TECHNOLOGY (2002)

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Article Chemistry, Inorganic & Nuclear

Substituent effect on the carborane coupling reaction: synthesis and crystal structure of 1-phenyl-2-[2,3-benzobicyclo(3,3,0)-1-oxo-4-oxa-7-aza-8-yl]-1,2-dicarba-closo-dodecaborane(12)

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INORGANIC CHEMISTRY COMMUNICATIONS (2001)

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Article Chemistry, Multidisciplinary

Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)(+) and anionic carboranes with host cyclotriveratrylene

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CHEMICAL COMMUNICATIONS (2001)

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