期刊
MICROCHEMICAL JOURNAL
卷 194, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.microc.2023.109312
关键词
Biogenic amine; Pillar[5]arene; Phenazine; Naphthalene diimide
In this paper, selective sensing materials for biogenic amine detection were designed and synthesized. The materials exhibited a transition from microsphere structure to supramolecular polymer gel, with fluorescence emission enhancement in the gel state. The supramolecular polymer gel material showed sensitive stimulus-response behavior and could be applied to detect food spoilage.
The development of selective sensing materials for biogenic amine detection has attracted tremendous interest because amines have high toxicity and exist widely. In this paper, phenazine-bridged pillar[5]arene monomers PA and a naphthalene diimide containing neutral guest-bearing alkyl chain binding sites NDI were designed and synthesized. They could self-assemble by host-guest interactions to form a microsphere structure in dilute solution. A series of biogenic amines can selectively quench the microsphere fluorescence. The microsphere structure transformed into the supramolecular polymer gel at relatively high concentrations. More interestingly, the supramolecular polymerization process induced fluorescence emission enhancement based on an AIE mechanism in the gel state. The supramolecular polymer gel material exhibited sensitive stimulus-response behavior owing to stimuli-induced reversible electron transfer in the presence of various amines. The gel soft material collapse could be achieved by fuming under a series of amines vapors. Besides, our results demonstrate an effective material design strategy that may be extended to fluorescence sensing of biogenic amine in solution, gel, and air and applications to detect food spoilage. It is envisaged that this important method would pave the way for overcoming the sensor's application constraints in the solution state.
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