4.7 Article

Modeling and experimental validation of carbon dioxide sorption on hollow fibers loaded with silica-supported poly(ethylenimine)

期刊

CHEMICAL ENGINEERING JOURNAL
卷 259, 期 -, 页码 737-751

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2014.08.023

关键词

Amine sorbents; Mass transfer kinetic studies; Poly(ethylenimine) hollow fiber; Mass transfer modeling

资金

  1. U.S. Department of Energy [DE-FE0007804]

向作者/读者索取更多资源

A mathematical model is developed for carbon dioxide adsorption on hollow fiber post infused with physically impregnated poly(ethylenimine) silica sorbent. The model includes detailed mass transfer mechanisms and is rigorously validated under different operating conditions of flue gas flow rate, number of fibers within the module, fiber length and particle size. A fundamental model formulation for the sorbent polymer diffusivity including the temperature and the sorbent concentration dependency is proposed. The proposed model formulation is based on free volume theory model of polymer diffusion and effectively predicts the experimental observations. The model is able to predict the breakthrough curves at many different operating conditions and module designs such as conditions with varied flue gas flow rate, fiber length, fiber packing fraction and support silica particle size. The concave trend in the temperature dependency of breakthrough capacity that shows a maximum around 45-60 degrees C is analyzed using the developed model. (C) 2014 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据