4.5 Article

Supercapacitor with highly efficient rare earth metal conjugated transition metal chalcogenide photoactive electrode In:SnO2/Nd2S3:Ni9S8:Co9S8

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DOI: 10.1016/j.mseb.2023.116544

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Ternary metal sulphide; Photo-electrochemical cell; Specific capacitance; Transient chronoamperometry; Electrical impedance spectrometry

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This study uses a simple single source precursor technique to produce distinctly shaped Nd2S3:Ni9S8:Co9S8. The material's crystal, optical, morphological and elemental investigation was performed. The transparent photoactive electrode In:SnO2/Nd2S3:Ni9S8:Co9S8 exhibited an unsurpassed specific capacity of 946 Fg-1 in the presence of light. It has great potential for practical application in renewable energy systems.
The implementation of nanostructure designs that optimize the benefits of all constituent elements and facilitate interfacial interactions between them represents a promising approach for enhancing electrochemical efficiency. This study uses a simple single source precursor technique to produce distinctly shaped Nd2S3:Ni9S8:Co9S8. The material's crystal, optical, morphological and elemental investigation was performed. The optical band gap of 3.5 eV was identified through UV-visible analysis. Furthermore, X-ray photoelectron spectroscopy and energy dispersive X-ray analysis confirmed the presence of Nd, Ni, Co, as well as S in the composite. Significant functional groups were investigated through FTIR. Electrical investigations involving multiple techniques were performed in a photoelectrochemical cell. Ascribing to the transparent photoactive electrode In:SnO2/Nd2S3: Ni9S8:Co9S8 the results presented an unsurpassed specific capacity of 946 Fg-1 in the presence of light. In each experiment, it was demonstrated that the electrode's photocurrent density was greater when it was exposed to light. This study has successfully introduced a highly valuable photoelectrode that exhibits great potential for practical application in the realm of renewable energy systems.

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