4.6 Article

Tunable white-light emission and afterglow of Eu3+doped Gd2Zr2O7 phosphors

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MATERIALS LETTERS
卷 347, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.matlet.2023.134598

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Luminescence; Phosphors; Eu; WLED

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Undoped and Eu-doped Gd2Zr2O7 phosphors with different concentrations were prepared using the solid-state reaction method. The emission color of Gd2Zr2O7:Eu3+ phosphors can be tuned over a broad range by varying the Eu3+ concentration under 256 nm excitation wavelength. The synthesized phosphors were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL) spectroscopy. The PL spectra showed the 5D0 -> 7FJ (J = 1, 2, and 3) transition of Eu3+ and described the afterglow properties of these phosphors, which may be suitable for white-LED (WLED) development.
The undoped and Eu-doped Gd2Zr2O7 phosphors with different concentrations were prepared by the conven-tional solid-state reaction method. By varying the Eu3+ concentration, under the 256 nm excitation wavelength, the emission colour of the Gd2Zr2O7:Eu3+ phosphors can be tuned over a broad region. The synthesized phos-phors were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and photo-luminescence (PL) spectroscopy. The PL spectra show the 5D0 -> 7FJ (J = 1, 2 and 3) transition of Eu3+ and describe the afterglow properties of these phosphors which may be applicable for the development of white-LED (WLED).

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