4.6 Article

Elevated sintering capability and electrical conductivity of Fe2O3-doped Ce0.8Sm0.1Nd0.1O2-δ as an electrolyte in IT-SOFCs

期刊

MATERIALS CHEMISTRY AND PHYSICS
卷 309, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2023.128345

关键词

Solid oxide fuel cells; Ceria; Doping; Sinterability; Electrical conductivity

向作者/读者索取更多资源

Ce0.8Sm0.1Nd0.1O2-delta (SNDC) is a promising electrolyte material for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Fe-doping significantly improves the sintering capability and electrical conductivity of SNDC.
Ce0.8Sm0.1Nd0.1O2-delta (SNDC) is one of the most promising electrolyte materials for intermediate-temperature solid oxide fuel cells (IT-SOFCs). However, the adverse effect on the preparation of the electrolyte due to the high sintering temperature of SNDC limits the application of SNDC as an electrolyte material in IT-SOFCs. In this work, x mol % (x = 0, 0.5, 1.0, 1.5, 2.0, 2.5) Fe-doped SNDC (xFe-SNDC) powders were firstly fabricated by sol-gel synthesis, and then the corresponding bulks were prepared by cold-pressing and sintering at 1200 similar to 1400 degrees C. The effects of Fe-doping on the sintering capability and electrical conductivity of SNDC were investigated. The results showed that Fe-doping leads to significant improvements in both the relative density and the electrical conductivity of SNDC. Doping Fe reduced the sintering temperature of SNDC from 1400 degrees C to 1200 degrees C and the relative density of 0.5Fe-SNDC sintered at 1200 degrees C reached 95.85%. Moreover, 0.5Fe-SNDC possessed the maximum conductivity of 0.0674 S cm(-1) at 750 degrees C, which was attributed to the highest density and the highest conductivity of grain plus grain boundary.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据