Optimizing the synthesis process for Lithium-Ion sieve adsorbents: Effect of calcination temperature and heating rate on reaction efficiency and performance

Processing-structure-property relationships play a crucial role in tuning the performance of materials for a given application in order to attain a suitable set of optimal conditions, and it is therefore imperative to evaluate the parameters of either the synthesis, delithiation, adsorption, and desorption process. Through an orthogonal test design of the solid-state synthesis process, it was determined that a heating rate of 1 degrees C/min had consistently higher reaction efficiencies of 68.1 %, 68.6 %, and 72.3 % at the calcination temperatures of 650 degrees C, 700 degrees C, and 750 degrees C respectively compared to heating rates of 4 degrees C/min and 7 degrees C/min. Moreover, a decrease in delithiation efficiency with increase in calcination temperature (99 % at 650 degrees C, 96.1 % at 700 degrees C, and 94.2 % at 750 degrees C) at the 1 degrees C/min heating rate was observed which was attributed to an increase in the average crystallite size. Adsorption performance of the synthesis-optimized zinc-doped lithium metatitanate showed consistently high adsorption efficiency (>90 %) despite the low adsorption capacity (4.9 mg/g) which was attributed to the low initial lithium-ion concentration of the lithium chloride solution and high adsorbent dosage.

Automated summary

Processing-structure-property relationships are crucial in optimizing materials for specific applications. The thermal synthesis process showed higher reaction efficiencies at a heating rate of 1 degrees C/min compared to higher heating rates. However, delithiation efficiency decreased with increasing calcination temperature. Zinc-doped lithium metatitanate demonstrated high adsorption efficiency despite a low adsorption capacity.