期刊
LIQUID CRYSTALS
卷 -, 期 -, 页码 -出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/02678292.2023.2252388
关键词
Oxazoline derivatives; smectics; TGB phases; ferroelectric phase
We have designed new chiral mesogens, OXm/n, derived from natural L-serine amino acid with an oxazoline chiral motif. Our focus was on evaluating the synthesis accessibility and preserving the optical purity of these compounds, which was determined by chiral high-performance liquid chromatography. We characterized the mesomorphic properties of the materials and confirmed the phase identification through X-ray scattering studies. Comparisons were made between the conformationally rigid oxazoline chiral moieties in the derivatives OXm/n and the structurally similar smectogens, ZLm/n, with a flexible (S)-lactate chiral unit to investigate the effect of rigidity on the mesomorphic properties.
We have designed new chiral mesogens, OXm/n, containing an oxazoline chiral motif derived from natural L-serine amino acid. Our effort was concentrated on the evaluation of the synthetic accessibility of these new compounds and preserving their optical purity, which was determined using chiral high-performance liquid chromatography. We established materials mesomorphic properties and confirmed the phase identification by X-ray scattering studies. Depending on the ratio between the terminal alkyl chain lengths, the studied materials exhibited various smectic mesophases. The derivatives OXm/n with conformationally rigid oxazoline chiral moiety were compared with the structurally similar smectogens, ZLm/n, having a flexible (S)-lactate chiral unit, in order to investigate the effect of rigidisation of the chiral unit on the mesomorphic properties.
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