4.7 Article

Biomimetic cellular-structured MCMB@WC composites with excellent mechanical properties

期刊

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 43, 期 11, 页码 4696-4705

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ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2023.03.062

关键词

Ceramic composites; Biomimetic structure; Sintering; Mechanical properties

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Inspired by the structures of plant cells, WC-coated MCMB powders were prepared by molten salt synthesis and then densified by spark-plasma sintering to obtain biomimetic cellular-structured MCMB@WC composites. The in-situ formed WC cytoderm significantly contributed to the densification of the composites. The composite with a WC concentration of 53 vol% exhibited the maximal bending strength and fracture toughness of 446 MPa and 4.48 MPa m1/2, respectively.
Inspired by the unique structures of plant cells, tungsten carbide (WC, cytoderm) coated mesocarbon microbeads (MCMB, cytoplasm) powders were prepared by molten salt synthesis, which were then densified by spark-plasma sintering to obtain the biomimetic cellular-structured MCMB@WC composites. The in-situ formed WC cytoderm significantly contributed to the densification of the composites. Additionally, the formation of periodically ar-ranged hard-soft architecture and perfect MCMB/WC interface bonding enhanced the mechanical properties significantly. The composite with WC concentration of 53 vol% exhibited the maximal bending strength and fracture toughness of 446 MPa and 4.48 MPa m1/2, respectively. The developed biomimetic ceramic/graphite composites with excellent mechanical properties are expected to be applied in aerospace and other industries.

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