期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 44, 期 3, 页码 1562-1569出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2023.10.054
关键词
Phase boundary; Pseudocubic; Piezoelectric; PNRs; Local inhomogeneities
In this study, solid solutions of xBi(Ni1/2Hf1/2)O-3-(1 - x)PbTiO3 (xBNH-PT) were synthesized to investigate their phase boundary behaviors and physical properties. The presence of a tetragonal-pseudocubic phase boundary and a spontaneous ferroelectric-relaxor transition at specific compositions were confirmed. The introduction of a tetragonal-pseudocubic phase boundary improved the piezoelectric properties and suppressed the spontaneous ferroelectric-relaxor transition.
In this study, we synthesized solid solutions of xBi(Ni1/2Hf1/2)O-3-(1 - x)PbTiO3 (xBNH-PT) with the aim of elucidating their phase boundary behaviors and the associated physical properties. A tetragonal (T) - pseudocubic (PC) phase boundary was confirmed at x = 0.38. For x = 0.36 and x = 0.37 with distinct tetragonal distortions, a spontaneous ferroelectric-relaxor transition was observed. The introduction of a T-PC phase boundary not only led to enhanced piezoelectric properties (d(33) = 456 pC/N, x = 0.39) but also effectively suppressed the spontaneous ferroelectric-relaxor transition. Detailed analysis revealed that the local structure of the initial state in 0.39BNH-0.61PT remained tetragonal. After poling, a long-range tetragonal phase was formed from the short-range tetragonal clusters, with the c/a value of similar to 1.01. Our observations of frequency dispersion strongly suggest the presence of local inhomogeneities, resulting in distinct poling effects on the dielectric and elastic behaviors of the material.
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