Neutral pH Na2SO4/ glycerol/PVA polymer hydrogel electrolyte prepared at room temperature for activated carbon supercapacitors

Neutral pH PVA/glycerol/Na2SO4 hydrogels were made by aging at room temperature, the effect of Na2SO4 concentration was evaluated, and the hydrogel with the best properties was tested as a neutral pH polymeric hydrogel electrolyte in a supercapacitor device with activated carbon electrodes. PVA/glycerol/Na2SO4 hydrogels were chemically and structurally studied using Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray diffraction. Hydrogel with 0.40 mol L-1 of Na2SO4 has the most presence of hydrogen bonds and a lesser presence of crystalline regions in its polymeric matrix. By impedance spectroscopy, the ionic conductivity of the hydrogels was calculated. Hydrogel with 0.40 mol L-1 of Na2SO4 has the highest value of ionic conductivity 17.4 mS cm(-1). This hydrogel was used as a polymer hydrogel electrolyte in a supercapacitor with Printex XE2B activated carbon electrodes by cyclic voltammetry and galvanostatic charge/ discharge cycles. The supercapacitor device with 0.40 mol L-1 Na2SO4 hydrogel reached a working potential window of 2.0 V in the cyclic voltammograms. Charge/discharge plots of the supercapacitor device with 0.40 mol L-1 Na2SO4 hydrogel exhibit a triangle behavior at different current densities. Supercapacitor device with 0.40 mol L-1 Na2SO4 hydrogel presents an equivalent series resistance of 14.7 ohms cm(-2), a specific capacitance of 54.7 F g(-1), and a specific energy of 7.6 Wh kg(-1) at 0.5 A g(-1). Obtained results were compared with a supercapacitor device with Na2SO4 1.0 mol L-1 and previously works.

Automated summary

In this study, neutral pH PVA/glycerol/Na2SO4 hydrogels were prepared by aging and the effect of Na2SO4 concentration on the properties was evaluated. The hydrogel with 0.40 mol/L Na2SO4 exhibited the best performance and was used as a polymeric hydrogel electrolyte in a supercapacitor device.