4.6 Article

Two proton-conductive metal-organic frameworks constructed by pyridyl imidazole dicarboxylate ligands

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Engineering, Environmental

A systematic review of metal organic frameworks materials for heavy metal removal: Synthesis, applications and mechanism

Guo Lin et al.

Summary: Worldwide rapid urbanization and development have led to the release and dispersion of anthropogenic heavy metals, posing serious threats to aquatic ecosystems and human health. Although various methods for removing heavy metal ions from aqueous solutions have been explored, there is still a need for improvement in the efficient and pertinent treatment of heavy metal pollution. Adsorption is considered the best technique for heavy metal removal, and metal-organic frameworks (MOFs) are recognized as one of the most promising emerging adsorbents with excellent adsorption properties. This review provides a comprehensive overview of MOFs synthesis techniques, functionalization methods, and adsorption mechanisms, as well as a detailed comparison of their applications in heavy metal removal, aiming to offer a strong reference for MOFs synthesis and a feasible solution for heavy metal treatment.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Chemistry, Inorganic & Nuclear

Strategies for designing metal-organic frameworks with superprotonic conductivity

Amitosh Sharma et al.

Summary: This review summarizes various key strategies implemented previously to achieve superprotonic conductivity in metal-organic frameworks (MOFs). Introducing guest molecules inside the pores of MOFs significantly enhances proton conductivity due to the resulting hydrogen bonding network. The role of proton carriers and proton-conducting media, along with MOFs' framework and functionalization, is briefly discussed to clarify the significance of applied strategies. The review concludes with remarks on the prospects for future development of MOFs as proton conductors, categorizing them in terms of strategies and conceptual approaches.

COORDINATION CHEMISTRY REVIEWS (2023)

Article Chemistry, Inorganic & Nuclear

Two Dual-Function Zr/Hf-MOFs as High-Performance Proton Conductors and Amines Impedance Sensors

Lu-Lu Kang et al.

Summary: Two highly stable 3D MOFs DUT-67(Hf) and DUT-67(Zr) were synthesized by solvothermal reaction, which have large specific surface areas and hierarchical pore structures, and can be used as high-performance amine molecular sensors. These MOFs have defects that can interact with substrates and facilitate proton transfer and amine compound identification. The proton conductivities of DUT-67(Zr) and DUT-67(Hf) under optimized conditions are significantly high, and the sensors based on these MOFs show high sensitivity to amine gases at different relative humidities.

INORGANIC CHEMISTRY (2023)

Review Chemistry, Inorganic & Nuclear

Aluminum metal-organic frameworks: From structures to applications

Weidong Fan et al.

Summary: This article systematically summarizes the construction and properties of aluminum metal-organic frameworks (MOFs), and discusses their applications in various fields. By studying the MOFs constructed by aluminum ions (Al3+), it was found that they have advantages such as low toxicity, abundant reserves, low cost, and sustainability. Aluminum MOFs have attracted much attention due to their diverse structures and functions, high physicochemical stability, and wide applications in many scientific and engineering fields.

COORDINATION CHEMISTRY REVIEWS (2023)

Review Chemistry, Analytical

MOFs composite materials for Pb2+ions detection in water: Recent trends & advances

Brij Mohan et al.

Summary: This article investigates the efficiency of metal-organic frameworks (MOFs) in detecting heavy metal ions such as Pb2+, Hg2+, and Cd2+. By optimizing conditions, MOFs composite materials and membranes can achieve ultra-sensitive detection of Pb2+ ions (LOD in pmol/L), which is their main advantage. However, the low working potential of MOFs requires the development of MOFs membrane composite materials for highly efficient detection of toxic Pb2+ ions. Therefore, this review summarizes their advantages, limitations, and future directions.

MICROCHEMICAL JOURNAL (2023)

Article Chemistry, Multidisciplinary

Novel isostructural iron-series-MOF calcined derivatives as positive and negative electrodes: A new strategy to obtain matched electrodes in a supercapacitor device

Yawen Dong et al.

Summary: Two new electrode materials derived from metal-organic frameworks (MOFs) have been developed to address the capacity gap issue in asymmetric supercapacitors (ASCs). The electrodes, Co-TAMBA-d and Fe-TAMBA-d, were prepared through a single-step sintering method and exhibited excellent electrochemical performance, surpassing that of pristine MOF materials and activated carbon. The ASCs based on these electrodes demonstrated high energy and power densities, with a capacity retention rate of about 75% after 5000 cycles. These results highlight the potential of MOF derivatives as promising electrodes for novel ASCs.

SMARTMAT (2023)

Review Chemistry, Inorganic & Nuclear

Proton conductive metal-organic frameworks based on main-group metals

Lu-Lu Kang et al.

Summary: This review focuses on the proton conductive properties of metal-organic frameworks based on main group metals, categorizing and evaluating their properties according to the types of main group metal elements. The review covers aspects such as preparation strategies, structural stability, proton conducting mechanisms, and structure-property relationships, aiming to guide future research in this area.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Sulfonic and phosphonic porous solids as proton conductors

Shan-Shan Liu et al.

Summary: Solid-state ordered porous materials (SSOPMs), including metal-organic frameworks (MOFs), metal-organic polyhedra (MOPs), covalent-organic frameworks (COFs), hydrogen-bonded organic frameworks (HOFs), and traditional zeolites, have attracted broad attention due to their large and tuneable pore sizes and surfaces, enabling diverse scientific and technological applications. This review focuses on recent progress of sulfonic and phosphonic SSOPMs as proton conductors, discussing their performances, proton-conducting properties, membranes, and fuel cells. General strategies in designing SSOPMs-based proton-conducting materials are summarized, along with future research perspectives.

COORDINATION CHEMISTRY REVIEWS (2022)

Article Chemistry, Inorganic & Nuclear

Superprotonic Conductivity of UiO-66 with Missing-Linker Defects in Aqua-Ammonia Vapor

Qing-Qing Liu et al.

Summary: Introducing defects into metal-organic frameworks can enhance proton conductivity, which is significant for improving the performance of proton-exchange membrane fuel cells.

INORGANIC CHEMISTRY (2022)

Article Chemistry, Physical

Enhancing proton conductivity in Zr-MOFs through tuning metal cluster connectivity

Guang-Rui Si et al.

Summary: This study introduces two stable Zr(IV)-based metal-organic frameworks, BUT-76 and BUT-77, which exhibit high proton conductivity and maintain stability over an extended period of time. By increasing the connectivity of Zr-6 clusters, the proton conductivity of the materials is significantly enhanced, as demonstrated through XRD diffraction measurements and molecular simulations.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Inorganic & Nuclear

High Water-Assisted Proton Conductivities of Two Cadmium(II) Complexes Constructed from Zwitterionic Ligands

Ya-Ru Liu et al.

Summary: Finding metal complexes with outstanding water stability and high proton conductivity is still important for the energy field. In this study, two highly proton-conductive complexes were successfully assembled using a zwitterionic organic compound. The structures and properties of the complexes were analyzed, and the proton-conductive mechanisms were compared and discussed. The study confirms the importance of zwitterionic ligands in forming organo-inorganic hybrid materials with high proton conductivity.

INORGANIC CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

Two stable phenyl acyl thiourea carboxylate-based MOFs: Syntheses, crystal structures and proton conductive properties

Li-Xia Xie et al.

Summary: In this study, two MOFs were designed and synthesized using phenyl-substituted acylthiourea-carboxylic acid ligands, characterized by single-crystal X-ray diffraction, and found to exhibit good proton conductivity under high humidity and high temperature conditions.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

Review Chemistry, Multidisciplinary

Design Rules of Hydrogen-Bonded Organic Frameworks with High Chemical and Thermal Stabilities

Xiyu Song et al.

Summary: Hydrogen-bonded organic frameworks (HOFs) are rapidly evolving into a novel and important class of porous materials with unique advantages, but their stability may be limited and require further development of chemically and thermally robust materials.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Review Materials Science, Multidisciplinary

Porous coordination polymer-based composite membranes for high-temperature polymer exchange membrane fuel cells

Guoliang Chen et al.

Summary: This review summarizes the materials and engineering strategies for designing PCP-based high-temperature proton exchange composite membranes, and discusses the remaining challenges as well as future research areas.

MATTER (2022)

Article Nanoscience & Nanotechnology

Acidic Groups Functionalized Carbon Dots Capping Channels of a Proton Conductive Metal-Organic Framework by Coordination Bonds to Improve the Water-Retention Capacity and Boost Proton Conduction

Jin Zhang et al.

Summary: This study successfully improved the water-retention capacity and proton conductivity of proton conductors by hybridizing hydrophilic carbon dots with high proton conductivity MOF-802, making CDs@MOF-802 one of the most efficient MOF proton conductors reported so far.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Mesoporous Assembly of Aluminum Molecular Rings for Iodine Capture

Shuyang Yao et al.

Summary: This study introduces a novel supramolecular nanocage structure assembled from aluminum molecular rings, exhibiting superior iodine adsorption behavior. Single-crystal X-ray diffraction reveals the binding sites of molecular I-2 within the cages. The resulting adsorbent demonstrates a high iodine vapor saturation uptake capacity and can be recycled for further use.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

MOF Nanosheet Reconstructed Two-Dimensional Bionic Nanochannel for Protonic Field-Effect Transistors

Guo-Dong Wu et al.

Summary: By utilizing MOF chemistry, a highly oriented CuTCPP thin film with abundant two-dimensional interstitial hydrophobic nanochannels has been successfully reconstructed for bionic devices, representing a new type of active-layer material for proton transport in nanochannels. This design strategy demonstrates a powerful approach for mimicking the structure and properties of bio-systems and constructing bionic electrical devices.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Inorganic & Nuclear

Proton conductive metal sulfonate frameworks

Rui-lan Liu et al.

Summary: This review discusses the recent advances in proton conductive sulfonate-based MOFs, analyzing the relationship between structures and proton conducting properties. Perspectives on future opportunities and challenges are proposed and highlighted.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Nanoscience & Nanotechnology

Fe-Based Coordination Polymers as Battery-Type Electrodes in Semi-Solid-State Battery-Supercapacitor Hybrid Devices

Kuaibing Wang et al.

Summary: Two-dimensional Fe-based metal-organic framework (FeSC1) and one-dimensional coordination polymer (FeSC2) were synthesized through reaction among FeSO4 center dot 7H(2)O, the tripodal ligand 4,4',4 ''-s-triazine-2,4,6-triyl-tribenzoate (H(3)TATB), and flexible secondary building blocks p/m-bis((1H-imidazole-1-yl)methyl)benzene (bib). Both materials showed outstanding electrochemical performances, with charge storage mainly dominated by diffusion-controlled section through power-law equations (i proportional to v(0.5)). Long-term cycling loops also revealed partial phase transformations to more stable FeOOH.

ACS APPLIED MATERIALS & INTERFACES (2021)

Review Chemistry, Inorganic & Nuclear

Proton conductive N-heterocyclic metal-organic frameworks

Bing-Xue Han et al.

Summary: This article comprehensively summarizes the proton conductive MOFs constructed by N-heterocyclic organic ligands, highlighting their potential as promising proton conductors.

COORDINATION CHEMISTRY REVIEWS (2021)

Review Electrochemistry

Advances in metal-organic frameworks and their derivatives for diverse electrocatalytic applications

Yangdan Pan et al.

Summary: Metal-organic frameworks (MOFs) and their derived materials serve as efficient electrocatalysts in clean energy production, conversion, and storage, offering a wide range of applications due to their engineering and construction strategies, as well as versatility in function.

ELECTROCHEMISTRY COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Superprotonic Conductivity of MOFs and Other Crystalline Platforms Beyond 10-1 S cm-1

Shyam Chand Pal et al.

Summary: The proton-exchange membrane (PEM) is crucial for the performance of proton-exchange membrane fuel cells (PEMFCs). While Nafion is widely used for its high protonic conductivity, emerging crystalline materials show potential for even higher conductivity levels.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Designable Assembly of Aluminum Molecular Rings for Sequential Confinement of Iodine Molecules

Chen-Hui Liu et al.

Summary: This study presents a coordination-driven self-assembly strategy for adsorbents capable of sequentially capturing iodine molecules. The adsorbents showed high removal rates and considerable loading capacities, providing distinct pore sizes and binding sites for the iodine molecules. Crystallographic data supported the sequential confinement of iodine molecules, revealing molecular details of host-guest binding interactions at high resolution.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Covalent-Organic Frameworks (COFs) as Proton Conductors

Rupam Sahoo et al.

Summary: COFs are a promising class of solid-state proton-conducting materials with high structural tunability and excellent properties, making them versatile platforms for electrochemical devices. This review discusses the strategies, structure-function relationships, challenges, and future prospects of COFs as proton conductors in detail.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

Rational strategies for proton-conductive metal-organic frameworks

Dae-Woon Lim et al.

Summary: The article focuses on rational design strategies for highly proton-conductive MOFs in recent years, discussing the challenges and future directions for the design of proton-conductive MOFs, such as improving mobile proton concentration through pre-design strategies or post-synthetic modifications.

CHEMICAL SOCIETY REVIEWS (2021)

Review Chemistry, Inorganic & Nuclear

Proton conductive carboxylate-based metal-organic frameworks

Xiao-Xin Xie et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Article Nanoscience & Nanotechnology

Dual-Functional Proton-Conducting and pH-Sensing Polymer Membrane Benefiting from a Eu-MOF

Sheng-Zheng Huang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Multidisciplinary

Flexible Porous Organic Polymer Membranes for Protonic Field-Effect Transistors

Hong Zhong et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Multidisciplinary

Proton Transport in Metal-Organic Frameworks

Dae-Woon Lim et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Multidisciplinary

High protonic conduction in two metal-organic frameworks containing high-density carboxylic groups

Yin Qin et al.

NEW JOURNAL OF CHEMISTRY (2020)

Review Chemistry, Inorganic & Nuclear

Proton conductive metal phosphonate frameworks

Song-Song Bao et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Article Chemistry, Multidisciplinary

Proton transfer in hydrogen-bonded degenerate systems of water and ammonia in metal-organic frameworks

Dae-Woon Lim et al.

CHEMICAL SCIENCE (2019)

Article Nanoscience & Nanotechnology

Open-Framework Chalcogenide Showing Both Intrinsic Anhydrous and Water-Assisted High Proton Conductivity

Hong-Bin Luo et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Polycarboxylate-Templated Coordination Polymers: Role of Templates for Superprotonic Conductivities of up to 10-1 S cm-1

Syed Meheboob Elahi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

A Highly Stable Two-Dimensional Copper(II) Organic Framework for Proton Conduction and Ammonia Impedance Sensing

Zhibing Sun et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Chemistry, Inorganic & Nuclear

A Water-Stable Proton-Conductive Barium(II)-Organic Framework for Ammonia Sensing at High Humidity

Kaimeng Guo et al.

INORGANIC CHEMISTRY (2018)

Article Chemistry, Inorganic & Nuclear

An ultra-stable porous coordination polymer for water-mediated proton conduction

Man Zhu et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Achieving Superprotonic Conduction in Metal-Organic Frameworks through Iterative Design Advances

SiRim Kim et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Inorganic & Nuclear

Channel-Assisted Proton Conduction Behavior in Hydroxyl-Rich Lanthanide-Based Magnetic Metal-Organic Frameworks

Soumava Biswas et al.

INORGANIC CHEMISTRY (2017)

Article Chemistry, Physical

3D hollow porous carbon microspheres derived from Mn-MOFs and their electrochemical behavior for sodium storage

Guoqiang Zou et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Chemistry, Physical

Synergistic Conductivity Effect in a Proton Sources-Coupled Metal Organic Framework

Xiao-Min Li et al.

ACS ENERGY LETTERS (2017)

Review Chemistry, Inorganic & Nuclear

Proton-conductive metal-organic frameworks: Recent advances and perspectives

Ai-Lin Li et al.

COORDINATION CHEMISTRY REVIEWS (2017)

Article Chemistry, Multidisciplinary

Conductive Metal-Organic Framework Nanowire Array Electrodes for High-Performance Solid-State Supercapacitors

Wen-Hua Li et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Review Chemistry, Inorganic & Nuclear

Ionic metal-organic frameworks (iMOFs): Design principles and applications

Avishek Karmakar et al.

COORDINATION CHEMISTRY REVIEWS (2016)

Review Chemistry, Inorganic & Nuclear

Ionic liquid transported into metal-organic frameworks

Kazuyuki Fujie et al.

COORDINATION CHEMISTRY REVIEWS (2016)

Editorial Material Multidisciplinary Sciences

Proton Conduction with Metal-Organic Frameworks

George K. H. Shimizu et al.

SCIENCE (2013)

Software Review Chemistry, Multidisciplinary

EDMA: a computer program for topological analysis of discrete electron densities

Lukas Palatinus et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2012)

Article Chemistry, Multidisciplinary

Wide Control of Proton Conductivity in Porous Coordination Polymers

Akihito Shigematsu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Physical

New proton conducting materials for technical applications: What can we learn from solid state NMR studies?

Robert Graf

SOLID STATE NUCLEAR MAGNETIC RESONANCE (2011)

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

Article Chemistry, Multidisciplinary

Symmetry determination following structure solution in P1

L. Palatinus et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2008)

Article Chemistry, Multidisciplinary

SUPERFLIP -: a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions

Lukas Palatinus et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2007)