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Review
Energy & Fuels
Esmail Dabirian et al.
Summary: Global warming is a critical environmental problem caused by burning fossil fuels and releasing CO2. The use of biofuels, especially those produced with nanotechnology, such as biohydrogen and bioethanol, can improve production efficiency and contribute to a greener future.
Review
Green & Sustainable Science & Technology
Wenlei Xie et al.
Summary: Biodiesel has gained attention as a potential alternative energy source. The use of heterogeneous catalysts for biodiesel production offers a more eco-friendly and attractive process. Magnetic solid catalysts have become a recent research focus due to their easy separation and minimal mass loss. This review discusses various magnetic solid catalysts, their preparation, catalytic performances, and future development trends, with a focus on their active species, surface properties, and synergisms. The review also presents possible reaction mechanisms and influential parameters for improved catalytic performances.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Biochemistry & Molecular Biology
Guodong Zeng et al.
Summary: Plant based proteins have the potential to replace formaldehyde resin as green and sustainable materials. A new adhesive based on soybean meal-dialdehyde chitosan-amine modified halloysite nanotubes was developed, enhancing strength and toughness through covalent bonding cross-linking and nanofiller toughening. This research opens up opportunities for developing biomass composites with desirable performance.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Inorganic & Nuclear
Cun Gao et al.
Summary: Designing efficient absorbents for multi-gas adsorption and separation is critical for gas purification in chemical engineering. In this work, two isomorphic metal-organic frameworks (MOFs) with multiple cages were synthesized and demonstrated to have high selectivity and capacity for gas adsorption. The study highlights the potential of multicage engineering for multicomponent gas separation.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Physical
Runze Ma et al.
Summary: A thermodynamically controllable synthetic strategy was used to prepare different morphologies of ZIF-8 and obtain a precise control over the exposed {100} and {110} facets. This work not only revealed the growth pattern of ZIF-8, but also provided a new direction for designing and synthesizing MOFs with different morphology rationally.
Article
Chemistry, Physical
Toan Minh Pham et al.
Summary: This study presented a tungsten-modified titanium dioxide support for platinum catalyst, which showed improved catalytic activity and stability, offering a potential solution to the carbon corrosion issue in proton exchange membrane fuel cells.
APPLIED SURFACE SCIENCE
(2023)
Review
Chemistry, Inorganic & Nuclear
Xuanhe Hu et al.
Summary: Lithium-sulfur batteries are highly promising successors to lithium-ion batteries due to their high energy density, low cost, and environmental friendliness. However, their practical applications are hindered by slow sulfur redox kinetics and the polysulfide shuttle effect. The use of metal-organic frameworks (MOFs) as catalysts to improve the electrochemical performance of lithium-sulfur batteries has attracted significant research interest.
COORDINATION CHEMISTRY REVIEWS
(2023)
Review
Chemistry, Multidisciplinary
Aparna Gautam et al.
Summary: Diminishing petroleum reserves, increasing carbon emissions, and growing fuel demand necessitate the search for alternative fuels. Biodiesel, produced from oils or fats, is a promising alternative. Photocatalysis, through semiconductors' light-induced emission of electrons and holes, offers an efficient method for biodiesel synthesis. This article reviews the various types, mechanisms, and prospects of metal-based, ionic liquid, and ionic liquid-based photocatalysts. Factors affecting esterification and transesterification, reaction chemistry, and reactor modifications for different oil feedstocks are discussed. Photocatalytic transesterification and esterification using metal or ionic liquid-based photocatalysts achieve up to 95% conversion of feedstocks under mild conditions, with catalyst reusability.
ENVIRONMENTAL CHEMISTRY LETTERS
(2023)
Review
Agricultural Engineering
Yaoyao Zhang et al.
Summary: The scarcity of fossil fuel and increasing environmental concerns have led to a growing need for the development of environmentally friendly and sustainable energy resources. Biodiesel, produced through transesterification of oils or fats with short-chain alcohol, is considered an optimal replacement for fossil-fuel based diesel due to its reproducible and eco-friendly properties. Among various catalysts, ionic liquids have shown potential as viable substitutes for conventional catalysts in biodiesel production. This paper provides a comprehensive review of the classification, synthetic schemes, and catalytic mechanism of basic ionic liquids, which have been less explored compared to acidic ionic liquids. The utilization of basic ionic liquids as catalysts for biodiesel preparation, along with the current challenges and prospects for future use, is also discussed.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Chemistry, Inorganic & Nuclear
Abdurrashid Haruna et al.
Summary: Metal-organic frameworks (MOFs) supported with Keggin-type polyoxometalates (POMs) have been successfully developed for high-performing heterogeneous catalysts. A Keggin-type PW11Zn was encapsulated within MOF-808 using an environmentally friendly solvothermal approach. The catalyst showed excellent catalytic activity for oxidative desulfurization of dibenzothiophene (DBT) in liquid fuel oil, with a 99.4% DBT conversion and a removal capacity of 86.85%. The catalyst displayed good reusability and no significant loss in activity after eight cycles of recycling. Kinetics and thermodynamic analysis of the oxidation reaction were also conducted.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Zhiqiang Guo et al.
Summary: In this study, Mg-MOF-74 was loaded onto cellulose aerogels to form the Mg-MOF-74@CA composite, overcoming agglomeration and recovery issues. The composite showed high porosity and efficient removal of Pb(II), Cd(II), and Cu(II) from wastewater. The removal process was influenced by pH, but not by ionic strength or humic acid. The maximum adsorption capacities for Pb(II), Cd(II), and Cu(II) were 223.555, 160.033, and 74.349 mg/g, respectively. The Mg-MOF-74@CA composite has great potential in practical wastewater treatment.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Mixia Hu et al.
Summary: This study developed a light-triggered CO-releasing hybrid material based on UIO-66-NH2 nanoparticles and CORM, which was coated with FA-CS-5-FAM. The hybrid material exhibited long-time CO release, targeted cancer cells, and fluorescence imaging, showing good biocompatibility and anticancer activity.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Engineering, Environmental
Xiao-Gang Jin et al.
Summary: Optimizing the properties of nanofiltration membranes is crucial for addressing the global freshwater crisis. In this study, porous two-dimensional aluminum-metal organic framework (Al-MOF) nanosheets were utilized to modify a commercial Nylon microfiltration substrate, followed by the preparation of polyamide nanofiltration membranes through interfacial polymerization. The morphologies and separation properties of the membranes were analyzed, with the best-performing Nylon-2.5 TFC membrane demonstrating an ultrahigh permeability and high rejection of Na2SO4. This work offers insights into improving substrate properties for the development of high-performance nanofiltration membranes.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Wei Guo et al.
Summary: This study investigates the deposition of MOF films with specific exposed facets using anodic electrodeposition on different substrates. The influence of deposition parameters on the exposed facets of MOFs is studied, and it is found that precise control over supersaturation can synthesize MOF crystals with well-defined exposed facets, providing a powerful toolbox for applications requiring crystal facet control in MOF films.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Xiangyuan Zhao et al.
Summary: In this study, a new method has been proposed to uniformly anchor nickel nanoparticles on the altered MXene surface, improving the performance of electrocatalysts. Pre-vacuum treatment of Mo2TiC2Tx (oMX) removes the surface terminal groups and induces surface oxidation defects. The nucleation and growth behaviors of nickel nanoparticles on oMX are altered in the hydrothermal reaction, resulting in smaller particle size and homogeneous coverage. The oxidized surface enables a strong coupling between oMX and nickel nanoparticles through Ni-O bonding, leading to the Ni@oMX hybrid exhibiting low overpotential and high durability in the electrocatalytic hydrogen evolution reaction.
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
(2023)
Article
Engineering, Biomedical
Xueying Ge et al.
Summary: Reducing the size of metal-organic framework (MOF) composites to the nanoscale has presented unique opportunities for enhanced properties. MOF-based nanocomposites offer limitless possibilities for biomedical applications. This review focuses on the recent development, classification, and construction methods of MOF-based nanocomposites for biomedical applications.
Review
Chemistry, Multidisciplinary
Romy Ettlinger et al.
Summary: The field of metal-organic frameworks (MOFs), particularly MOF nanoparticles, has seen significant growth in the last two decades. This tutorial review emphasizes the importance of systematic toxicity assessment and discusses the current state of in vitro and in vivo toxicity studies of MOF nanoparticles, as well as the key factors affecting their toxicity.
CHEMICAL SOCIETY REVIEWS
(2022)
Article
Chemistry, Physical
G. T. Vidyavathi et al.
Summary: Gallic acid extracted from pomegranate pericarp was successfully used as a green and effective catalyst for the synthesis of novel ligands and metal complexes. The ligands and complexes were synthesized using a simple physical grinding technique and characterized using advanced spectroscopic and analytical techniques. The interactions of the metal complexes with DNA and their photonuclease characteristics were studied through molecular docking experiments and spectroscopic techniques.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Review
Chemistry, Physical
Alexis Munyentwali et al.
Summary: This review discusses the application of bifunctional solid acid/base catalysts in sustainable biodiesel production. Compared to conventional liquid base catalysts, solid catalysts offer better environmental friendliness and cost-effectiveness, and can be produced using low-cost feedstocks.
APPLIED CATALYSIS A-GENERAL
(2022)
Review
Agricultural Engineering
Youhua Zhang et al.
Summary: Due to food shortages and increasing fuel prices, scientists are exploring alternative non-edible feedstocks, such as jojoba and Schizochytrium sp. microalgae, for sustainable biodiesel production. The use of low-cost nanocatalysts, like CaO, instead of homogeneous catalysts can reduce the cost and eliminate certain steps in the biodiesel production process. The findings highlight the potential of nano-catalysts in achieving high biodiesel yields with their unique features of high surface area, reusability, reactivity, and environmental friendliness.
BIOMASS & BIOENERGY
(2022)
Review
Thermodynamics
Joshua Iseoluwa Orege et al.
Summary: Heterogeneous catalysis provides a viable alternative for low-cost biodiesel production, and catalytic transesterification is considered the most feasible synthesis method. Nine commonly used heterogeneous catalysts have been studied, with a focus on versatile catalysts with high activity and low production cost.
ENERGY CONVERSION AND MANAGEMENT
(2022)
Review
Chemistry, Applied
Muhammad Aamir Bashir et al.
Summary: Research in biodiesel production technologies is focused on improving efficiency through the use of various catalysts and feedstocks. Emerging technologies like enzyme catalysis, batch reactors, and continuous flow reactors show promise in achieving high conversion yields.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Hoai T. B. Pham et al.
Summary: The development of 2D electrically conductive metal-organic frameworks (EC-MOFs) has expanded the applications of MOFs. This study presents a new EC-MOF with a large surface area, high electrical conductivity, and tunable particle size. The framework also utilizes functional groups to host heterometal ions, providing new opportunities for expanding the library of EC-MOFs and exploring electronic applications.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Chemistry, Inorganic & Nuclear
Naoki Ogiwara et al.
Summary: In this review, the recent advances in POM-based ionic crystals are summarized, including the design strategies, proton conductivity, and mechanisms for proton conduction.
COORDINATION CHEMISTRY REVIEWS
(2022)
Review
Chemistry, Multidisciplinary
Zhimin Wang et al.
Summary: This review summarizes the recent advances of mixed-transition-metal-substituted polyoxometalates (Mixed TMSPs), highlighting their wide potential applications in multiple research areas.
SCIENCE CHINA-CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Ming-Liang Gao et al.
Summary: The exposed facets of supported catalysts are crucial in catalysis, but they are usually ignored. This study demonstrates that crystal facet engineering of supports can modulate the microenvironment and electronic state of supported metal nanoparticles, leading to enhanced catalysis.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Physical
Iqra Riaz et al.
Summary: This article provides a review of various catalysts used in biodiesel production, with a focus on naturally derived heterogeneous catalysts. It explores the use of different heterogeneous catalysts as alternatives to homogeneous catalysts for the esterification and transesterification of nonedible and low-cost biomasses. The article also analyzes the impact and long-term performance of biodiesel in various applications, and reports advancements in catalysts and processes to facilitate further development in biodiesel production.
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING
(2022)
Review
Nanoscience & Nanotechnology
Shixian Wang et al.
Summary: This article discusses the synthesis strategies and application areas of nanoscale/microscale metal-organic frameworks (nano/microscale MOFs). By utilizing specific synthesis methods, the shape and size of the crystal can be regulated for optimal performance in energy storage, catalysis, and biomedical applications. Additionally, the challenges and prospects of nanoscale/microscale MOF materials in advanced energy storage and conversion applications are summarized.
Review
Chemistry, Multidisciplinary
Heng Zhang et al.
Summary: This review systematically examines the application of organic-inorganic hybrid porous coordination polymers (OIHPCPs) in biodiesel production. The study comprehensively evaluates the factors influencing the transesterification/esterification reactions of liquid biomass catalyzed by OIHPCPs, including catalyst dosage, type and molar ratio of alcohol, reaction temperature and time, water and fatty acids content of the substrate. The review also discusses the plausible reaction mechanisms and future perspectives for OIHPCP applications in biodiesel production.
Review
Chemistry, Inorganic & Nuclear
Ketan Maru et al.
Summary: The insertion of molecular metal oxides, such as polyoxometalates (POMs), into metal-organic frameworks (MOFs) has provided new research opportunities, particularly in the field of catalysis. POM/MOF composites exhibit strong acidity, oxygen-rich surface, and redox capacity due to the characteristics of POMs, as well as large surface area, highly organized structures, tunable pore size, and shape due to MOFs. These hybrid materials have gained significant attention and have potential applications in various fields including organic catalysis, sorption and separation, proton conduction, magnetism, lithium-ion batteries, supercapacitors, electrochemistry, medicine, and bio-fuel. The exceptional properties of POMOFs make them promising catalysts for simple organic transformations with high capacity and selectivity.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Tong Wang et al.
Summary: A viologen-functionalized metal-organic framework (MOF), MIL-125-RV2+, was obtained by modifying MIL-125-NH2 with viologen molecules. MIL-125-RV2+ is the first viologen-based MOF used for photocatalytic CO2 reduction reaction (CO2RR), exhibiting excellent photocatalytic activity and high selectivity for HCOO-.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Wei Yang et al.
Summary: Different crystal facets in metal and metal oxide nanocrystals often exhibit varied catalytic performances, whereas this phenomenon is rarely seen in metal-organic frameworks. A nickel metal-organic layer with rich (100) crystal facets demonstrates significantly higher photocatalytic CO2-to-CO activity compared to the one with rich (010) crystal facets and its bulky counterpart, due to synergistic catalysis on the surface enabling more favorable energetics in CO2 reduction.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Thermodynamics
Xiaoling Ma et al.
Summary: Biodiesel is a green and renewable energy source, and the use of heterogeneous catalysts like metal organic frameworks (MOFs) in its production process is gaining attention due to the difficulties of recovery and reuse associated with traditional homogeneous catalysts. The unique structure and advantages of MOFs make them a promising candidate for catalyzing biodiesel production.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Article
Green & Sustainable Science & Technology
Wenlei Xie et al.
Summary: Efficient and reusable catalysts are desired for improved biodiesel production, and a solid catalyst was successfully developed by incorporating ZIF-8 MOF into Fe3O4 nanoparticles and encapsulating a vanadium-substituted heteropolyacid. The catalyst showed good magnetic responsiveness and achieved simultaneous transesterification of soybean oil and esterification of free fatty acids, with high conversion rates and good reusability.
Article
Chemistry, Applied
Pavletta Shestakova et al.
Summary: The study introduces a novel POM-functionalized hybrid catalyst immobilized on mesoporous silica, with in situ generation of active Bronsted acid sites and Lewis acidity from the metal center during synthesis. These catalysts exhibit higher catalytic activity, recyclability, and leaching resistance compared to common POM-based catalysts.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Article
Chemistry, Physical
Hong-Yu Zhang et al.
Summary: A new strategy for constructing covalently linked MOF-COF hybrid materials by post-synthetic modification of metal nodes has been developed in this work, leading to enhanced efficiency of photocatalytic hydrogen evolution.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Review
Chemistry, Multidisciplinary
P. Mialane et al.
Summary: In recent years, there has been a significant interest in the heterogenisation of molecular catalysts, with Metal-Organic Frameworks (MOFs) serving as a platform for immobilizing the catalysts. This review thoroughly discusses the preparation methods, analytical tools, and applications of Cat@MOF composites in catalysis.
CHEMICAL SOCIETY REVIEWS
(2021)
Review
Chemistry, Multidisciplinary
Jiawei Zhong et al.
Summary: Efficient utilization of biomass is crucial in green and sustainable chemistry, with POMs and POM-metal composites playing a significant role in catalytic reactions due to their high reactivity. This review highlights recent advances in biomass conversion over POMs and POM-metal composites, including acid catalysis and chemical oxidation, and discusses the future prospects of biomass valorisation using POM-based catalysts.
Review
Nanoscience & Nanotechnology
Cassandra T. Buru et al.
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Chemistry, Multidisciplinary
Hang Li et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Energy & Fuels
Pengpeng Wei et al.
Review
Nanoscience & Nanotechnology
Wentao Xu et al.
NATURE REVIEWS MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Luis A. Gallego-Villada et al.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Qiuyun Zhang et al.
Article
Chemistry, Physical
Yukwon Jeon et al.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2019)
Article
Chemistry, Multidisciplinary
Yanfen Zhang et al.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2019)
Article
Chemistry, Multidisciplinary
Checkers R. Marshall et al.
Article
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Kanagaraj Madasamy et al.
NEW JOURNAL OF CHEMISTRY
(2019)
Article
Chemistry, Multidisciplinary
Latif Ullah et al.
SCIENCE CHINA-CHEMISTRY
(2018)
Review
Chemistry, Inorganic & Nuclear
Nazmul Abedin Khan et al.
COORDINATION CHEMISTRY REVIEWS
(2018)
Article
Chemistry, Multidisciplinary
Shu-Mei Liu et al.
ADVANCED MATERIALS INTERFACES
(2018)
Review
Chemistry, Multidisciplinary
Liyu Chen et al.
CHEMICAL SOCIETY REVIEWS
(2017)
Review
Chemistry, Multidisciplinary
Yuan-Biao Huang et al.
CHEMICAL SOCIETY REVIEWS
(2017)
Article
Chemistry, Inorganic & Nuclear
Ruowen Liang et al.
DALTON TRANSACTIONS
(2015)
Article
Chemistry, Physical
Hui Wan et al.
Review
Chemistry, Multidisciplinary
Dong-Ying Du et al.
CHEMICAL SOCIETY REVIEWS
(2014)
Article
Chemistry, Multidisciplinary
Youn-Sang Bae et al.
Software Review
Chemistry, Multidisciplinary
Oleg V. Dolomanov et al.
JOURNAL OF APPLIED CRYSTALLOGRAPHY
(2009)
Article
Chemistry, Multidisciplinary
Wenxin Niu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2009)
Article
Chemistry, Multidisciplinary
Farid Nouar et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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Chemistry, Physical
OY Khyzhun
JOURNAL OF ALLOYS AND COMPOUNDS
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