Viscosity experiments of slag-spinel suspensions: The effect of volume fraction, particle size, and shear rate

Heterogeneous slag viscosity measurements have a wide variety of parameters, such as particle size, shape, solid volume fraction, and shear rate, which affect the final measured viscosity. Often, some of these parameters are neglected or predicted via models, since it is experimentally difficult to determine them during high-temperature slag viscosity measurements. In this work, a viscosity apparatus was used, which allows quenching of the sample after measurement. This way, all relevant parameters could be experimentally determined. The viscosities of three datasets were studied with various spinel sizes: small (13 mu m), medium (34 mu m), and large particles (76 mu m). Within each dataset, the composition of the liquid slag matrix was kept constant to uniquely measure the effect of solids. Shear thinning, i.e., a decreasing viscosity with increasing shear rate, was observed for all samples, even at a low vol. % of 1.8. Moreover, stronger shear thinning was observed at a higher vol. % and for smaller spinel particles. On the basis of these results, the phenomenon of shear thinning was discussed and mainly attributed to the particle-particle orientation in the suspension. The obtained viscosity values were used to optimize a Krieger-Dougherty equation, which describes the viscosity increase caused by the presence of a certain vol. % of spinel particles, with a certain size and at a specific shear rate.

Automated summary

Heterogeneous slag viscosity measurements are affected by various parameters, such as particle size, shape, solid volume fraction, and shear rate. This study used a viscosity apparatus to experimentally determine all relevant parameters by quenching the sample after measurement. The results showed that the size and volume fraction of spinel particles have an impact on viscosity, and shear thinning is more pronounced at higher shear rates. These findings contribute to the optimization of an equation describing the viscosity increase caused by spinel particles.