期刊
JOURNAL OF POWER SOURCES
卷 574, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2023.233140
关键词
Silicon anode; Li-ion; DFT; NMR; Binder; Polyacrylic acid
In this study, the effect of slurry pH on the lithiation mechanism of silicon nanoparticle anodes in lithium-ion batteries was investigated using a combination of NMR, DFT, and electrochemical cycling. The results showed that the lithiation mechanisms varied depending on the pH. An acidic slurry promoted the lithiation of silicon nanoparticles, while a basic slurry oxidized the nanoparticles to form a SiO/SiO2 shell that needed to be cracked before Si lithiation. The reaction of Li+ and SiO/SiO2 to form lithium silicates was the dominant process in a basic slurry, resulting in greater capacity loss compared to an acidic slurry.
In this work we have investigated the effect of slurry pH on the lithiation mechanism of silicon nanoparticle (SiNP) anodes in lithium-ion batteries. To this end, we have used a combination of lithium (7Li) and silicon (29Si) magic angle spinning nuclear magnetic resonance (MAS NMR), density functional theory (DFT), and electrochemical charge-discharge cycling. The NMR results show that different lithiation mechanisms are present depending on the pH. An acidic slurry facilitates the lithiation of SiNP, whereas a basic slurry oxidises the SiNP to form a shell of SiO/SiO2, which must be cracked before Si lithiation becomes relevant. In a basic slurry, the leading process during the first cycle is the reaction of Li+ and SiO/SiO2 to form lithium silicates. Consequently, this intermediate step leads to a greater capacity loss in the basic media than in the acidic one.
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