期刊
JOURNAL OF POLYMER RESEARCH
卷 30, 期 9, 页码 -出版社
SPRINGER
DOI: 10.1007/s10965-023-03727-1
关键词
PVDF; Silver-copper oxide; Polar beta phase; Dielectric properties
This article presents the synthesis and characterization of Ag-CuO/rGO nanoparticles as a filler for PVDF polymer to enhance its polar beta phase and electrical conductivity, for potential use in polymer batteries. Ag-CuO/rGO nanoparticles were prepared through hydrothermal method and incorporated into PVDF matrix using solution casting. Various techniques were employed to examine the structure, crystallinity, dielectric, and electrical properties of the PVDF/Ag-CuO/rGO nanocomposites. The results showed that the incorporation of Ag-CuO/rGO nanoparticles promoted the formation of polar beta phase of PVDF, leading to higher dielectric constant and lower dielectric loss compared to pure PVDF.
This article presents the synthesis and characterization of Ag-CuO/rGO nanoparticles, which serve as a filler for the PVDF polymer to enhance its polar beta phase and electrical conductivity for possible use in polymer batteries. The Ag-CuO/rGO nanoparticles were prepared through a straightforward hydrothermal method and incorporated into a PVDF matrix using a solution casting technique. Various techniques were employed to examine the structure, crystallinity, dielectric, and electrical properties of the PVDF/Ag-CuO/rGO nanocomposites. The results revealed that the Ag-CuO/rGO nanoparticles incorporated within the PVDF matrix, promoting the formation of the polar beta phase of PVDF. The PVDF/Ag-CuO/rGO nanocomposites displayed a higher dielectric constant and lower dielectric loss compared to pure PVDF. As the Ag-CuO/ rGO content increased, so did the electrical conductivity of the nanocomposites, reaching a value of 1.23 x10(-3) S/cm at 2.5 Wt% Ag-CuO/rGO loading. The enhanced electrical conductivity was attributed to the conductive networks formed by both the Ag-CuO/rGO nanoparticles and the polar beta phase of PVDF. These findings indicate that PVDF/Ag- CuO/rGO nanocomposites hold promise for different applications such as polymer batteries.
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