Small gas adsorption on 2D material SnSe: a first-principles study

SnSe not only has a large surface-to-volume ratio, but also provides enough space to adsorb small-molecule gases owing to its unique wrinkled structure, so it exhibits great application prospects in gas sensing. In this study, we have comprehensively investigated the adsorption properties of H-2, N-2, CO, CO2, H2S, H2O, NH3, NO, SO2, and NO2 on SnSe by the first-principles density functional theory, and have analyzed the sensing potential of SnSe for these small gas molecules. It is found that only NO and SO2 have suitable adsorption energies, showing that they can be stably adsorbed on the SnSe substrate and easily desorbed under certain conditions. Moreover, NO adsorption introduces a magnet moment that can be differentiated from SO2 and NO2. Additionally, according to the calculation results of the statistical thermodynamics model and nonequilibrium Green's function method, SO2 possesses enormous adsorption density and larger current than NO under the same condition. Therefore, SnSe is promising for reversible SO2 sensing.

Automated summary

In this study, the adsorption properties of various small gas molecules on SnSe were investigated using first-principles density functional theory. It was found that only NO and SO2 exhibited suitable adsorption energies, indicating their potential for stable adsorption on SnSe. Additionally, NO adsorption introduced a distinguishable magnetic moment, while SO2 showed higher adsorption density and current compared to NO under the same conditions. Therefore, SnSe shows promise for reversible SO2 sensing.