4.8 Article

Two-Dimensional Biphenylene-Based Carbon Allotrope Family with High Potassium Storage Ability

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

A novel lithium decorated N-doped 4,6,8-biphenylene for reversible hydrogen storage: Insights from density functional theory

Xinhui Zhang et al.

Summary: We investigate a novel carbon biphenylene (C468) and its nitrogen-doped counterpart as potential candidates for hydrogen storage. The findings show that lithium-decorated C468 and lithium-decorated N-doped C468 can adsorb a considerable amount of hydrogen molecules, with gravimetric densities reaching 9.581 wt% and 10.588 wt%, respectively. These results provide significant insights for expanding the application scope of carbon-based and carbon-nitrogen materials and advancing hydrogen storage technologies.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Article Chemistry, Physical

Activation of metal-free porous basal plane of biphenylene through defects engineering for hydrogen evolution reaction

Mihir Ranjan Sahoo et al.

Summary: The commercial application of electrochemical water reduction for hydrogen evolution reaction (HER) is hindered by the lack of inexpensive and efficient catalysts. We propose a metal-free biphenylene nanosheet as an excellent HER electro-catalyst. The dynamical and thermal stability of the nanosheet is confirmed through calculations. The nanosheet exhibits excellent catalytic activity, and its efficiency can be further improved through doping and vacancies.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Article Physics, Applied

Abnormal strain-dependent thermal conductivity in biphenylene monolayer using machine learning interatomic potential

Guangyu Yang et al.

Summary: In this work, a surprising enhancement of thermal conductivity in a planar biphenylene network (BPN) under 5% biaxial tensile strain was explored using a Boltzmann transport equation combined with machine learning interatomic potentials. The room temperature thermal conductivity of BPN reaches about 4-5 times that of an intrinsic sample. This phenomenon can be attributed to a phonon selection rule induced by mirror symmetry. This study highlights the significant impact of the selection rule on thermal transport and enhances our understanding of thermal conductivity regulation in strained two-dimensional materials.

APPLIED PHYSICS LETTERS (2023)

Article Nanoscience & Nanotechnology

Lattice thermal conductivity of silicon monolayer in biphenylene network

Aiqing Guo et al.

Summary: Recently, a two-dimensional carbon sheet in a biphenylene network has been fabricated successfully, which promotes the study of silicon allotropes with similar structures. In this work, the lattice thermal conductivity of a silicon monolayer in a biphenylene network is investigated through first-principles calculations. It is found that the thermal conductivity is anisotropic and much lower than that of carbon sheets with a similar structure.

AIP ADVANCES (2023)

Article Chemistry, Physical

Poly-triphenylene membrane: A multifunctional two-dimensional porous carbon framework with ultra-high carrier mobilities and potassium ion storage capacity

Jiaxin Jiang et al.

Summary: A novel 2D carbon material, 2D-C18H6, composed of triphenylene molecules, was systematically investigated using density functional theory methods. The computational results demonstrate that 2D-C18H6 possesses good lattice dynamics stability, high thermal stability, and excellent gas separation ability. It is a semiconductor material with ultra-high carrier mobility and has potential applications in electronic devices, energy storage, and gas separation.

APPLIED SURFACE SCIENCE (2023)

Article Chemistry, Physical

Extraordinary negative thermal expansion of monolayer biphenylene

Qingfang Li et al.

Summary: The study successfully fabricated two-dimensional biphenylene with sp(2)-hybridized carbon atoms and found that the monolayer biphenylene exhibits negative and anisotropic in-plane thermal expansion, with the negative thermal expansion reaching up to 1000K. At 300K, the linear thermal expansion coefficient of biphenylene along the a-direction is three times that of graphene.

CARBON (2022)

Article Thermodynamics

Thermal transport in planar sp2-hybridized carbon allotropes: A comparative study of biphenylene network, pentaheptite and graphene

Penghua Ying et al.

Summary: The thermal transport properties of biphenylene network were comprehensively investigated and found to have significantly lower thermal conductivities compared to graphene and pentaheptite due to the decline in structural symmetry leading to reduced phonon group velocity and mean free path.

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER (2022)

Article Chemistry, Multidisciplinary

Unveiling the Multiradical Character of the Biphenylene Network and Its Anisotropic Charge Transport

Isaac Alcon et al.

Summary: Recent progress in on-surface synthesis and characterization of nanomaterials is enabling the creation of new carbon allotropes, such as the biphenylene network (BPN), which exhibits unusual metallic conductivity and potential device functionalities in nanoelectronics and spintronics.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Biophysics

Two-dimensional mesoporous nitrogen-rich carbon nanosheets loaded with CeO2 nanoclusters as nanozymes for the electrochemical detection of superoxide anions in HepG2 cells

Zhenxing Wang et al.

Summary: In this study, a facile method was presented to fabricate 2D mesoporous nitrogen-rich carbon nanosheets loaded with CeO2 nanoclusters for superoxide anions (O-2(center dot)) electrochemical sensor. The material exhibited a unique structure and high electrocatalytic performance, allowing for the detection of trace amounts of O-2(center dot) and potential application in biological fields.

BIOSENSORS & BIOELECTRONICS (2022)

Article Multidisciplinary Sciences

Synthesis of a monolayer fullerene network

Lingxiang Hou et al.

Summary: In this study, a single-crystal 2D carbon material, monolayer quasi-hexagonal-phase fullerene (C-60), is prepared using an interlayer bonding cleavage strategy. This material exhibits high crystallinity, good thermodynamic stability, and has a moderate bandgap. The asymmetric lattice structure of monolayer polymeric C-60 gives it notable in-plane anisotropic properties. This 2D carbon material offers an interesting platform for potential applications in 2D electronic devices.

NATURE (2022)

Article Chemistry, Physical

Electronic transport in biphenylene network monolayer: Proposals for 2D multifunctional carbon-based nanodevices

Guogang Liu et al.

Summary: This paper proposes several conceptual nanodevices based on the BPN monolayer and reveals their electronic transport properties. The study finds that the BPN monolayer has potential applications in electronic transport, gas sensors, and Schottky junction devices.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

Monolayer Fullerene Networks as Photocatalysts for Overall Water Splitting

Bo Peng

Summary: Photocatalytic water splitting is an environmentally friendly method to produce hydrogen and reduce global carbon emissions. Monolayer fullerene networks, synthesized recently, offer new material candidates for photocatalysis due to their large surface area, abundant active sites, and potential for hydrogen storage. The electronic structures of monolayer fullerene networks were investigated using density functional theory and hybrid functional calculations. It was found that these networks have suitable band gaps, appropriate band edges, and sufficient driving force for water splitting. Additionally, different phases of fullerene networks exhibit unique optical properties, making them advantageous in photocatalysis as either electron acceptors or donors.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Physical

Biphenylene: A Two-Dimensional Graphene-Based Coating with Superior Anti-Corrosion Performance

Ke Ke et al.

Summary: Metal corrosion can cause engineering accidents, so coating protection is valuable. A new two-dimensional graphene-based material called biphenylene has shown potential for metal corrosion resistance. This study investigates the anti-corrosion mechanism of biphenylene.

MATERIALS (2022)

Article Chemistry, Physical

Anisotropic electrene T′-Ca2P with electron gas magnetic coupling as anode material for Na/K ion batteries

Jiaxin Jiang et al.

Summary: There is an urgent need for high-performance rechargeable electrical storage devices as a supplement or a substitution for lithium ion batteries due to the shortage of lithium in nature. A stable 2D electrene T '-Ca2P is proposed as an anode material for Na/K ion batteries, and it exhibits suitable adsorption and anisotropic migration energy barriers for Na and K atoms.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022)

Review Green & Sustainable Science & Technology

Constructing Advanced Aqueous Zinc-Ion Batteries with 2D Carbon-Rich Materials

Zecheng Xiong et al.

Summary: This article introduces the application of 2D carbon-rich materials to overcome the drawbacks of aqueous zinc-ion batteries (AZIBs) and thoroughly discusses the advantages of various representative 2D carbon-rich materials. Additionally, it presents recent progress in utilizing 2D carbon-rich materials for AZIB cathodes, anodes, separators, and electrolytes, and summarizes the features of different 2D carbon-rich materials and future prospects for optimization and practical use of AZIBs.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2022)

Article Chemistry, Physical

Thgraphene: a novel two-dimensional carbon allotrope as a potential multifunctional material for electrochemical water splitting and potassium-ion batteries

Weiyi Wang et al.

Summary: With the use of a genetic algorithm method, a novel 2D carbon allotrope named thgraphene is predicted with relatively low energy. Thgraphene shows robust thermodynamic, dynamic, and mechanic stability, making it highly possible for experimental synthesis. It is proven to be an efficient bifunctional electrocatalyst for hydrogen and oxygen evolution reactions with low overpotentials. Moreover, thgraphene shows promise as an anode material for potassium-ion batteries due to its excellent ductility, ultra-low diffusion barrier, high theoretical specific capacity, and moderate average open-circuit voltage.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Physical

High storage capacity and small volume change of potassium-intercalation into novel vanadium oxychalcogenide monolayers V2S2O, V2Se2O and V2Te2O: An ab initio DFT investigation

Yang-Xin Yu

Summary: The new two-dimensional V(2)Ch(2)O (Ch = S, Se, and Te) monolayer electrode materials show excellent thermal, dynamical, and mechanical stabilities. The exothermic adsorption energies prevent dendrite formation, while electrode potentials decrease diffusion barriers of potassium atoms and maintain metallic characteristics during K-intercalation. The V(2)Ch(2)O monolayers are promising for PIBs with high capacities and long cycle lives.

APPLIED SURFACE SCIENCE (2021)

Article Chemistry, Physical

Is graphite nanomesh a promising anode for the Na/K-Ions batteries?

Chen Yang et al.

Summary: Based on first-principles calculations, graphite nanomesh with a hole density of 46% (GN46) is demonstrated to be a promising anode material for both NIB and KIB, with high ion storage capacities and improved diffusion properties.

CARBON (2021)

Article Chemistry, Physical

Potential anodic applications of 2D MoS2 for K-ion batteries

Javed Rehman et al.

Summary: The study investigates the electronic structure and electrochemical characteristics of monolayer MoS2 as an anodic material for potassium ion batteries. The results indicate that monolayer MoS2 holds potential for application in KIBs.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Physics, Condensed Matter

A first-principles comparative study of lithium, sodium, potassium and calcium storage in two-dimensional Mg2C

Y. Z. Chu et al.

Summary: The study indicates that 2D Mg2C shows metallic behavior and excellent electrical conductivity as an anode material for batteries, with high diffusivity for sodium and potassium ions and a high storage capacity.

JOURNAL OF PHYSICS-CONDENSED MATTER (2021)

Article Chemistry, Physical

Rational design of carbon materials as anodes for potassium-ion batteries

Yuanming Wu et al.

Summary: This review summarizes the recent advances in rational design of carbon materials for developing anodes for potassium-ion batteries, including practical issues with various carbon materials as anodes, potassium storage mechanisms, and design methods for carbon materials. The ultimate goal is to develop next-generation carbon anodes with high energy density and excellent cycling stability.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Two-Dimensional Biphenylene: A Graphene Allotrope with Superior Activity toward Electrochemical Oxygen Reduction Reaction

Tianyang Liu et al.

Summary: Two-dimensional biphenylene, a newly synthesized metal-free catalyst, shows good ORR activity due to its metallic nature and positively charged carbon atoms, especially in alkaline conditions. It also exhibits good electrochemical stability, making it a promising candidate for alkaline fuel cells.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Chemistry, Physical

Toward Large-Capacity and High-Stability Lithium Storages via Constructing Quinone-2D-MnO2-Pillared Structures

Jia-Hui Li et al.

Summary: Scientists have designed three novel quinone-2D MnO2 pillared structures, which exhibit larger theoretical capacities and superior electrochemical properties and thermal stability compared to traditional mesoporous MnO2. These findings provide new insights and prospects for developing larger and more stable lithium storage systems.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Chemistry, Multidisciplinary

A Self-Growth Strategy for Simultaneous Modulation of Interlayer Distance and Lyophilicity of Graphene Layers toward Ultrahigh Potassium Storage Performance

Xiaohua Qiao et al.

Summary: This study introduces a self-growth strategy to adjust the interlayer distance and lyophilicity of graphene layers, resulting in enhanced potassium-storage performances for carbon materials. The OM-G monolith, prepared using this strategy, exhibits outstanding electrochemical properties as a free-standing anode for PIB batteries.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Electrochemistry

Flexible structural changes of the oxocarbon salt K2C6O6 during potassium ion insertion: An in-depth first-principles study

Ruqian Lian et al.

Summary: Inorganic-organic crystal materials like K2C6O6 show great potential as electrode materials for metal ion batteries. Through first-principles calculations, it has been found that K2C6O6 exhibits flexible structures and excellent K ion storage properties, allowing for fast K ion migration and high rate capability in K ion batteries.

ELECTROCHIMICA ACTA (2021)

Article Multidisciplinary Sciences

Biphenylene network: A nonbenzenoid carbon allotrope

Qitang Fan et al.

Summary: The study introduces a new method for synthesizing a novel biphenylene network by conducting an interpolymer dehydrofluorination reaction on a surface, resulting in a metallic carbon allotrope. This method provides a new approach for synthesizing other nonbenzenoid carbon allotropes.

SCIENCE (2021)

Article Materials Science, Multidisciplinary

Type-II Dirac cones and electron-phonon interaction in monolayer biphenylene from first-principles calculations

Peng-Fei Liu et al.

Summary: The study reveals that metallic biphenylene sheets exhibit low-temperature weak coupling superconductivity due to an unusual combination of exceptionally large logarithmically averaged phonon frequency and moderate electron-phonon coupling. The electronic structure shows specific Fermi surface features and Dirac cones, while topological calculations indicate that monolayer biphenylene is a Z(2) topological material.

PHYSICAL REVIEW B (2021)

Review Chemistry, Multidisciplinary

Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

Ranjusha Rajagopalan et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Review Chemistry, Multidisciplinary

Sustainable Recycling Technology for Li-Ion Batteries and Beyond: Challenges and Future Prospects

Ersha Fan et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

Design of tetracene-based metallic 2D carbon materials for Na- and K-Ion batteries

Umer Younis et al.

APPLIED SURFACE SCIENCE (2020)

Article Multidisciplinary Sciences

Rational design of layered oxide materials for sodium-ion batteries

Chenglong Zhao et al.

SCIENCE (2020)

Review Chemistry, Multidisciplinary

Observation of critical magnetic behavior in 2D carbon based composites

Vineeta Shukla

NANOSCALE ADVANCES (2020)

Article Chemistry, Physical

Two-Dimensional Carbon-Based Auxetic Materials for Broad-Spectrum Metal-Ion Battery Anodes

Shuaiwei Wang et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2019)

Article Chemistry, Physical

Implicit self-consistent electrolyte model in plane-wave density-functional theory

Kiran Mathew et al.

JOURNAL OF CHEMICAL PHYSICS (2019)

Article Materials Science, Multidisciplinary

Geometric and electronic structures of a two-dimensional covalent network of sp2 and sp3 carbon atoms

Mina Maruyama et al.

DIAMOND AND RELATED MATERIALS (2018)

Article Chemistry, Physical

Potential application of 2D monolayer -GeSe as an anode material in Na/K ion batteries

You Zhou et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2018)

Article Chemistry, Multidisciplinary

High-Pressure Synthesis and Characterization of β-GeSe-A Six-Membered-Ring Semiconductor in an Uncommon Boat Conformation

Fabian O. von Rohr et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Phosphorus-Based Alloy Materials for Advanced Potassium-Ion Battery Anode

Wenchao Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Physical

Boron phosphide monolayer as a potential anode material for alkali metal-based batteries

H. R. Jiang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Nanoscience & Nanotechnology

Biphenylene and Phagraphene as Lithium Ion Battery Anode Materials

David Ferguson et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Nanoscience & Nanotechnology

Potassium-Ion Oxygen Battery Based on a High Capacity Antimony Anode

William D. McCulloch et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

Article Chemistry, Multidisciplinary

Carbon Electrodes for K-Ion Batteries

Zelang Jian et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Multidisciplinary Sciences

Penta-graphene: A new carbon allotrope

Shunhong Zhang et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2015)

Article Chemistry, Physical

Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways

Kiran Mathew et al.

JOURNAL OF CHEMICAL PHYSICS (2014)

Review Chemistry, Multidisciplinary

Graphene synthesis: relationship to applications

Rebecca S. Edwards et al.

NANOSCALE (2013)

Article Chemistry, Physical

Graphenylene: a promising anode material for lithium-ion batteries with high mobility and storage

Yang-Xin Yu

JOURNAL OF MATERIALS CHEMISTRY A (2013)

Article Chemistry, Physical

Two-Dimensional Superlattice: Modulation of Band Gaps in Graphene-Based Monolayer Carbon Superlattices

Xiaoguang Luo et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

Article Chemistry, Multidisciplinary

Architecture of graphdiyne nanoscale films

Guoxing Li et al.

CHEMICAL COMMUNICATIONS (2010)

Article Physics, Multidisciplinary

Atomically Thin MoS2: A New Direct-Gap Semiconductor

Kin Fai Mak et al.

PHYSICAL REVIEW LETTERS (2010)

Article Multidisciplinary Sciences

Measurement of the elastic properties and intrinsic strength of monolayer graphene

Changgu Lee et al.

SCIENCE (2008)

Article Multidisciplinary Sciences

Electric field effect in atomically thin carbon films

KS Novoselov et al.

SCIENCE (2004)

Article Chemistry, Physical

Hybrid functionals based on a screened Coulomb potential

J Heyd et al.

JOURNAL OF CHEMICAL PHYSICS (2003)