期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 20, 页码 14781-14788出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01550
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An unprecedented reductive cross-coupling reaction has been developed through C-N bond cleavage, enabling the efficient synthesis of diverse alkene products.
An unprecedented reductive cross-coupling reaction of allylammonium salts with alkyl electrophiles has been established through C-N bond cleavage. A range of allylammonium bromides smoothly participated in the nickel-catalyzed zinc-mediated allyl-alkyl cross-electrophile coupling reaction with alkyl iodides, delivering structurally diverse alkene products in moderate to good yields with high linear selectivity. Preliminary mechanistic experiments are consistent with the formation of an alkyl radical from the alkyl iodide.
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