期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 19, 页码 14246-14254出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01915
关键词
-
In this study, a visible light-induced C-H bromination reaction was developed for the synthesis of benzyl boronic esters. This method offers high yields, mild conditions, simple operation, and good functional group tolerance. Additionally, the synthesis of halogenated geminal diborons was demonstrated.
a-Halogenated boronic esters are versatile building blocks that can be diversified into a wide variety of polyfunctionalized molecules. However, their synthetic potential has been hampered by limited preparation methods. Herein, we report a visible light-induced C-H bromination reaction of readily available benzyl boronic esters. This method features high yields, mild conditions, simple operation, and good functional group tolerance. The analogous chlorides and iodides can be accessed via Finkelstein reaction. Synthesis of halogenated geminal diborons has also been demonstrated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据