期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 16, 页码 11945-11953出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01214
关键词
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A novel protocol for the synthesis of tetrahydroquinolines and 5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinolines through gold-catalyzed N-aryl propargylamines has been developed. This strategy offers advantages such as easy access to raw materials, simple reaction conditions, good substrate compatibility, high efficiency, and excellent regioselectivity.
A novelprotocol of gold-catalyzed N-aryl propargylaminesto construct tetrahydroquinolines and 5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinolines in moderate to good yields has beendeveloped through the tandem reactions of intramolecular hydroarylationand transfer hydrogenation. The strategy has the advantages of easyaccess to raw materials, simple reaction conditions, good substratecompatibility, high efficiency, and excellent regioselectivity.
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