4.7 Article

Palladium-Catalyzed E-Selective Oxidative Amination of Aromatic Amine with 3-Butenoic Acid

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JOURNAL OF ORGANIC CHEMISTRY
卷 88, 期 21, 页码 15350-15357

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AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01843

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A palladium-catalyzed oxidative amination of inactive olefins with an aromatic amine using a copper acetate oxidant was developed, yielding corresponding secondary and tertiary enamines in moderate to good yields. This new procedure outlines an efficient approach for the construction of enamine skeletons.
A palladium-catalyzed oxidative amination of inactive olefins with an aromatic amine was developed using a copper acetate oxidant to yield corresponding secondary and tertiary enamines in moderate to good yields. This new procedure outlines an efficient approach for the construction of enamine skeletons.

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