4.7 Article

Fabrication and excellent performance of amorphous FeSiBCCr/ organic-inorganic hybrid powder core

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JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 616, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.jnoncrysol.2023.122482

关键词

Phytic acid; silane (PAS); Core-shell insulating coating; Soft magnetic property; Mechanical property

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Soft magnetic composites (SMCs) are widely used in power and electronic fields for inductance components. Insulation coating is crucial for SMCs, and a novel solution called phytic acid/silane (PAS) organic-inorganic hybrid solution was developed for efficient formation of insulating coatings. FeSiBCCr@PAS powder cores with a core-shell structure were successfully prepared through chemical reaction in the modified PAS solution. The study investigated the effects of insulating coating content on the magnetic and mechanical properties of the powder cores, showing significantly improved performance.
Soft magnetic composites (SMCs) are widely used in relevant inductance components in power and electronic fields. The development of high frequency devices requires SMCs to exhibit good insulation and excellent soft magnetic properties. The insulation coating for SMCs is crucial, and it is necessary to ensure that the coating thickness is uniform and maintains excellent adhesion to the powder. In the present work, a novel and efficient solution for the formation of insulating coatings, i.e. phytic acid/silane (denoted as PAS) organic-inorganic hybrid solution, was prepared by the condensation reaction between PA and & gamma;-(2,3-epoxypropoxy) propyl trimethoxy silane. The FeSiBCCr@PAS powder with a core-shell structure has been successfully prepared through chemical reaction in a modified PAS solution. The effects of insulating coating content on the magnetic and mechanical properties of FeSiBCCr@PAS powder cores were systematically investigated. The PAS hybrid insulating coating can significantly improve the DC-bias performance and reduce the core loss. The optiomal powder core, which was prepared by using the powder coated with 3 g/L phytic acid, exhibits a minimum core loss (P50mT/1MHz) of 2979.2 mW/cm3, high effective permeability & mu;e(0.1A/m) of 33.8, and superior DC-bias(100Oe) performance of 80.8%. Present work developed an effective method to prepare high performance powder cores with good soft magnetic and mechanical properties.

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