4.7 Article

Electrically tunable thermoresponsive optic switch for smart window application based on dye-doped cholesteric liquid crystal

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JOURNAL OF MOLECULAR LIQUIDS
卷 388, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.molliq.2023.122752

关键词

Black dye; Liquid-crystal devices; Texture switching; Smart window; Cholesteric liquid crystal; Optical switch

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We have demonstrated a cholesteric liquid crystal (CLC) smart window that can switch between transparent and low-transmission states reversibly based on thermo-optic effect. This smart window utilizes a thermoresponsive handedness-reversible chiral dopant in a mixture of chiral dopant, dichroic dye and nematic liquid crystal to create a thermosensitized CLC. By increasing the temperature, the device switches from a homeotropic texture to a fingerprint texture. The absorption characteristic of the dichroic dye enables the CLC to have two distinct transmission levels.
We demonstrate a cholesteric liquid crystal (CLC) smart window that functions as a reversible thermo-optic switch between a transparent state at a low temperature and a low-transmission state at a higher tempera-ture. This smart window is based on the addition of a thermoresponsive handedness-reversible chiral dopant in a mixture of a typical chiral dopant, a dichroic dye and nematic liquid crystal, yielding a thermosensitized CLC. In such a homeotropically anchored dye-doped CLC, the thickness-to-pitch ratio increases as the temperature rises, causing the device to switch from the homeotropic texture to the fingerprint texture. The absorption charac-teristic of the dichroic dye enables the homeotropic and fingerprint configurations in the dye-doped CLC to create two distinct transmission levels-the transparent and opaque optically stable states, respectively. Such a switching mechanism entails no additional electric power and, thus, is energy-saving. Moreover, the switching temperature at which the texture transition takes place can be actively increased by increasing voltage for the smart window. This allows the CLC device to be perfectly adaptable to the need of a user and, in turn, applicable to a wider variety of environments.

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