期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 154, 期 -, 页码 140-148出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2022.12.075
关键词
Thermoelectric; SnSb 2 Te 4; Lattice anharmonicity; Resonant level; Band Convergence
In this work, the thermoelectric properties of polycrystalline InxSn1-xSb2(Te1-ySey)4 samples were comprehensively investigated. The introduction of indium and selenium significantly improved the Seebeck coefficient and power factor due to the combined effects of emergent resonant states and converged valence bands. Moreover, the disordered cations occupancy in SnSb2Te4 enhanced lattice anharmonicity and reduced phonon group velocity, resulting in intrinsically low lattice thermal conductivity. A record zT value of approximately 0.6 at 670 K and an average zT of approximately 0.4 between 320 and 720 K were achieved in the In0.1Sn0.9Sb2Te3.4Se0.6 sample, making it one of the highest zT values among SnSb2Te4-based materials.
As a typical (IV-VI)x(V2VI3)y compound, the tetradymite-like layered SnSb2Te4-based compounds have attracted increasing attention in the thermoelectric community owing to the intrinsically low lattice thermal conductivity. Nevertheless, the effect of cations disorder on the inherent physical characteris-tics remains puzzling, and its inferior Seebeck coefficient is the bottleneck to achieving high thermo-electric performance. In this work, the thermoelectric properties of polycrystalline InxSn1 -xSb2(Te1 -ySey)4 (0 <= x <= 0.1, 0 <= y <= 0.15) samples are comprehensively investigated. In conjunction with the calcu-lated band structure and experimental results, the Seebeck coefficient and power factor are markedly improved after the introduction of indium and selenium, which originates from the combined effects of the emergent resonant states and converged valence bands along with optimal carrier concentration. Additionally, compared with the ordered lattice structure, the disordered cations occupancy in SnSb2Te4 further strengthens lattice anharmonicity and reduces phonon group velocity verified by first-principles calculations, securing intrinsically low lattice thermal conductivity. Finally, a record zT value of similar to 0.6 at 670 K and an average zT of similar to 0.4 between 320 and 720 K are obtained in the In0.1Sn0.9Sb2Te3.4Se0.6 sam-ple, being one of the highest zT values among SnSb2Te4-based materials. This work not only demonstrates that SnSb2Te4-based compounds are promising thermoelectric candidates, but also provides guidance for the promotion of thermoelectric performance in a broad temperature range. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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